1. Tính nồng độ mol/l của các ion có trong các dd sau: a) Ba(OH)2 0,2M b) 150 ml dd có hòa tan 6,39 g Al(NO3)3. c) (*) Dd HNO3 20% (khối lượng riêng D = 1,054 g/ml). d) (*) H2SO4 3,92 % ( D = 1,025g/ml) e) (*) Hòa tan 12,5 g CuSO4.5H2O vào một lượng nước vừa đủ thành 200 ml dd. f) Trộn 200 ml dd chứa 7,3 g HCl và 9,8 g H2SO4. g) Trộn lẫn 100 ml dd NaOH 0,3M với 150 ml dd NaOH 0,6M
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\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)
\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)
\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)
\(n_{NaOH}=0,02.2=0,04\left(mol\right)\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ a.n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,04}{2}=0,02\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,02}{0,08}=0,25\left(M\right)\\ b.\left[Na^+\right]=\dfrac{0,02.2}{0,02+0,08}=0,4\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,02+0,08}=0,2\left(M\right)\)
a) Ta có: \(n_{Al\left(NO_3\right)_3}=\dfrac{4,26}{213}=0,02\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al^+}=0,02\left(mol\right)\\n_{NO_3^-}=0,06\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Al^+\right]=\dfrac{0,02}{0,1}=0,2\left(M\right)\\\left[NO_3^-\right]=\dfrac{0,06}{0,1}=0,6\left(M\right)\end{matrix}\right.\)
b) Ta có: \(\left[Na^+\right]=0,1+0,02\cdot2+0,3=0,304\left(M\right)\)
c) Bạn xem lại đề !!
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
\(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
Theo PT : \(n_{HCl}=2n_{Ba\left(OH\right)_2}=2.\dfrac{400.1,2.17,1\%}{171}=0,96\left(mol\right)\)
=> \(V_{HCl}=\dfrac{0,96.36,5}{3,65\%.1,05}=914,29\left(ml\right)\)
\(m_{Ba\left(OH\right)_2}=400\cdot1.2\cdot17.1\%=82.08\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{82.08}{171}=0.48\left(mol\right)\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.48..............0.96\)
\(m_{HCl}=0.96\cdot36.5=35.04\left(g\right)\)
\(m_{dd_{HCl}}=\dfrac{35.04}{3.65\%}=960\left(g\right)\)
\(V_{dd_{HCl}}=\dfrac{960}{1.05}=1008\left(ml\right)\)