Đốt cháy hoàn toàn một hỗn hợp khí gồm CO và H2 cần dùng 9,6g khí oxi. Khí sinh ra có 8,8g CO2
a. Viết các PTHH xảy ra
b. Tính thành phần % của hỗn hợp khí ban đầu theo số mol và theo khối lượng
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a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
nO2 = 9.6/32 = 0.3 (mol)
nCO2 = 8.8/44 = 0.2 (mol)
CO + 1/2O2 -to-> CO2
0.2_____0.1______0.2
H2 + 1/2O2 -to-> H2O
0.4__0.3-0.1
%CO = 0.2*28/(0.2*28 + 0.4*2) * 100% = 87.5%
Chúc bạn học tốt !!!
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\(n_{CO_2}=\dfrac{8.8}{44}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{9.6}{32}=0.3\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^0}2CO_2\)
\(0.2.......0.1.......0.2\)
\(2H_2+O_2\underrightarrow{t^0}2H_2O\)
\(0.4......0.3-0.1\)
\(\%m_{CO}=\dfrac{0.2\cdot28}{0.2\cdot28+0.4\cdot2}\cdot100\%=87.5\%\)
\(\%m_{H_2}=100-87.5=12.5\%\)
a)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2(1)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O(2) \)
b)
\(n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\)
Theo PTHH :
\(n_{CO} = n_{CO_2} = 0,2(mol)\\ n_{O_2(1)} = \dfrac{1}{2}n_{CO_2} = 0,1(mol)\\ n_{H_2} = 2n_{O_2(2)} = 2(0,3-0,1) = 0,4(mol)\)
Vậy :
\(\%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\% = 87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
n CO2 = 0,2 mol
n O2 = 0,3 mol
2 CO + O2 -> 2 CO2
............0,1........0,2
2 H2 + O2 -> 2 H2O
.......0,3-0,1.....0,4
=> % tự tính nha
\(n_{O_2}=\dfrac{89.6}{22.4}=4\left(mol\right)\)
\(n_{H_2O}=3a\left(mol\right)\)
\(n_{CO_2}=a\left(mol\right)\)
\(2H_2+O_2\underrightarrow{^{^{t^0}}}2H_2O\)
\(2CO+O_2\underrightarrow{^{^{t^0}}}2CO_2\)
\(n_{O_2}=1.5a+0.5a=4\left(mol\right)\)
\(\Leftrightarrow a=2\)
\(n_{H_2}=3\left(mol\right),n_{CO}=1\left(mol\right)\)
\(\%V_{H_2}=\dfrac{3}{4}\cdot100\%=75\%\)
\(\%V_{CO}=25\%\)
\(\%m_{H_2}=\dfrac{3\cdot2}{3\cdot2+1\cdot28}\cdot100\%=17.64\%\)
\(\%m_{CO}=100-17.64=82.36\%\)
PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(2H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=n_{CO}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow n_{O_2\left(1\right)}=0,1\left(mol\right)\\\Sigma n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{O_2\left(2\right)}=0,2\left(mol\right)\) \(\Rightarrow n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow\%V_{H_2}=\dfrac{0,4}{0,4+0,2}\cdot100\%\approx66,67\%\)
\(\Rightarrow\%V_{CO}=33,33\%\)
\(2CO + O_2 \xrightarrow{t^o} 2CO_2\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2} = \dfrac{n_{CO} + n_{H_2}}{2}=\dfrac{0,2+n_{H_2}}{2} = \dfrac{9,6}{32} = 0,3(mol)\\ \Rightarrow n_{H_2} = 0,4(mol)\\ \%V_{CO} = \dfrac{0,2}{0,2 + 0,4}.100\% = 33,33\%\\ \%V_{H_2} = 100\% - 33,33\% = 66,67\%\\ \%m_{CO} = \dfrac{0,2.28}{0,2.28+0,4.2}.100\%=87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
nCO2 = 8.8/44 = 0.2 (mol)
nO2 = 9.6/32 = 0.3 (mol)
2CO + O2 -to-> 2CO2
0.2____0.1______0.2
2H2 + O2 -to-> 2H2O
0.4___0.3-0.1
%CO = 0.2*28 / ( 0.2*28 + 0.4*2) * 100% = 87.5%
%H2 = 12.5%
=> D
\(2CO + O_2\xrightarrow{t^o} 2CO_2(1)\\ n_{CO} = n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)\\ n_{O_2(1)} = \dfrac{n_{CO_2}}{2} = 0,1(mol)\\ 2H_2 +O_2 \xrightarrow{t^o} 2H_2O(2)\\ n_{H_2} = 2n_{O_2(2)} = 2.(\dfrac{9,6}{32}-0,1) = 0,4(mol)\\ \Rightarrow \%m_{CO} = \dfrac{0,2.28}{0,2.28 + 0,4.2}.100\% = 87,5\%\\ \%m_{H_2} = 100\% - 87,5\% = 12,5\%\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
2CO + O2 --to--> 2CO2
0,2<---0,1<--------0,2
2H2 + O2 --to--> 2H2O
0,4<--0,2<-------0,2
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\\%V_{H_2}=100\%-33,33\%=66,67\%\end{matrix}\right.\)
\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,3<--0,15<------0,3
2H2 + O2 --to--> 2H2O
0,1<--0,05
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\%n_{CO}=\dfrac{0,3}{0,3+0,1}.100\%=75\%\\\%V_{H_2}=100\%-75\%=25\%\end{matrix}\right.\)
$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)$
\(2CO+O_2\xrightarrow[]{t^o}2CO_2\)
0,2 0,1 0,2 (mol)
$n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)$
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,4 0,2 0,2 (mol)
\(\%m_{CO}=\dfrac{0,2.44}{0,2.44+0,4.2}.100\%=91,67\%\\ \%m_{H_2}=100\%-91,67\%=8,33\%\)
\(\%n_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\ \%n_{H_2}=100\%-33,33\%=66,67\%\)