Cho 50ml dd H2SO4 2M tác dụng vừa đủ với dd NaOH 20% a) Tính khối lượng dd của dd NaOH: 20% b) Tính khối lượng của muối sau phản ứng
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\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
\(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)
c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)
\(n_{CuO}=\dfrac{1.6}{80}=0.02\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.02.......0.02.................0.02\)
\(m_{H_2SO_4}=0.02\cdot98=1.96\left(g\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{1.96}{20\%}=9.8\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng }}=1.6+9.8=11.4\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.02\cdot160}{11.4}=28.07\%\)
Ta có: \(n_{NaOH}=0,1.0,5=0,05\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{CH_3COONa}=n_{NaOH}=0,05\left(mol\right)\)
a, \(C_{M_{CH_3COOH}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
b, \(m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
a)
\(n_{Alanin} = \dfrac{8,9}{89} = 0,1(mol)\\ n_{HCl} = 0,2(mol) \)
\(CH_3-CH(NH_2)-COOH + HCl \to CH_3-CH(NH_3Cl)-COOH\)
_______0,1_______________0,1____________0,1_____________(mol)
Suy ra :
\(m_{muối} = 0,1.122,5 =12,25(gam)\)
b)
\(n_{HCl\ dư} = 0,2 - 0,1 = 0,1(mol)\)
\(HCl + NaOH \to NaCl + H_2O\)
0,1____________0,1___________(mol)
\(CH_3-CH(NH_3Cl)COOH + 2NaOH \to CH_3-CH(NH_2)-COONa + NaCl + 2H_2O\)
________0,1___________________________________0,1_____________0,1_________(mol)
Vậy muối gồm :
\(CH_3-CH(NH_2)-COONa : 0,1\ mol\\ NaCl : 0,1 + 0,1 = 0,2(mol)\\ \Rightarrow m_{muối} = 0,1.111 + 0,2.58,5 = 22,8(gam)\)
nH2SO4= 2.0,05=0,1(mol)
PTHH: 2 NaOH + H2SO4 -> Na2SO4 + 2 H2O
a) nNaOH= 0,1.2=0,2(mol) => mNaOH=0,2.40=8(g)
=>mddNaOH= 8/20%= 40(g)
b) nNa2SO4=nH2SO4=0,1(mol)
=> mNa2SO4=142.0,1=14,2(g)