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Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
Gọi số mol O2, CO2 là a, b
Có: \(\overline{M}=\dfrac{32a+44b}{a+b}=19,5.2=39\)
=> \(a=\dfrac{5}{7}b\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{\dfrac{5}{7}b}{\dfrac{5}{7}b+b}.100\%=41,67\%\\\%V_{CO_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{\dfrac{5}{7}b+b}.100\%=58,33\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=34,188\%\\\%m_{CO_2}=\dfrac{44b}{32a+44b}.100\%=65,812\%\end{matrix}\right.\)
thay a = \(\dfrac{5}{7}b\) thôi bn :)
\(\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=\dfrac{32.\dfrac{5}{7}b}{32.\dfrac{5}{7}b+44b}.100\%=34,188\%\)
Giả sử các khí được đo ở điều kiện sao cho 1 mol khí chiếm thể tích 1 lít
Gọi số mol CH4, C2H6 là a, b (mol)
=> \(a+b=\dfrac{25}{1}=25\left(mol\right)\) (1)
\(n_{O_2}=\dfrac{95}{1}=95\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a---->2a---------->a
2C2H6 + 7O2 --to--> 4CO2 + 6H2O
b------>3,5b-------->2b
=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=95-2a-3,5b\left(mol\right)\\n_{CO_2}=a+2b\left(mol\right)\end{matrix}\right.\)
=> \(95-a-1,5b=\dfrac{60}{1}=60\)
=> a + 1,5b = 35 (2)
(1)(2) => a = 5; b = 20
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{5}{25}.100\%=20\%\\\%V_{C_2H_6}=\dfrac{20}{25}.100\%=80\%\end{matrix}\right.\)
\(\overline{M}_A=\dfrac{5.16+20.30}{5+20}=27,2\left(g/mol\right)\)
\(\overline{M}_B=20,5.2=41\left(g/mol\right)\)
=> \(d_{A/B}=\dfrac{27,2}{41}\approx0,663\)
a)
Gọi $n_{CO} = a ; n_{NO} = b$
Ta có :
$28a + 30b = (a + b). $\dfrac{103}{14}.4$
$\Rightarrow \dfrac{10}{7}a = \dfrac{4}{7}b$
$\Rightarrow \dfrac{a}{b} = \dfrac{2}{5}(1)$
b)
$28a + 30b = 20,6(2)$
Từ (1)(2) suy ra a = 0,2 ;b = 0,5
$n_{O_2} = 0,5(mol)$
2CO + O2 \(\xrightarrow{t^o}\) 2CO2
0,2..........0,1............0,2........(mol)
2NO + O2 \(\xrightarrow{t^o}\) 2NO2
0,5.........0,25...........0,5............(mol)
Sau phản ứng, B gồm :
CO2 : 0,2 mol
NO2 : 0,5 mol
O2 dư : 0,5 - 0,25 - 0,1 = 0,15(mol)
$n_{hh} = 0,2 + 0,5 + 0,15 = 0,85\ mol$
$\%n_{CO_2} = \dfrac{0,2}{0,85}.100\% = 23,53\%$
$\%n_{NO_2} = \dfrac{0,5}{0,85} .100\% = 58,82\%$
$\%n_{O_2\ dư} = 17,65\%$
Bảo toàn khối lượng : $m_B = m_A + m_{O_2} = 20,6 + 0,5.32 = 36,6(gam)$
$M_B = \dfrac{36,6}{0,85} = 43,06(g/mol)$
$d_{B/He} = \dfrac{43,06}{4} = 10,765$
a) \(M_A=\dfrac{103}{14}.4=\dfrac{206}{7}\)
Lập sơ đồ đường chéo :
=> \(\dfrac{n_{CO}}{n_{NO}}=\dfrac{30-\dfrac{206}{7}}{\dfrac{206}{7}-28}=\dfrac{2}{5}\)
b)Gọi x, y lần lượt là số mol CO, NO
=> \(\left\{{}\begin{matrix}28x+30y=20,6\\\dfrac{x}{y}=\dfrac{2}{5}\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,2\\y=0,5\end{matrix}\right.\)
\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
2CO + O2 → 2CO2
0,2---->0,1---->0,2
2NO + O2 → 2NO2
0,5---->0,25--->0,5
=> Hỗn hợp khí B gồm : \(\left\{{}\begin{matrix}O_{2\left(dư\right)}=0,5-\left(0,1+0,25\right)=0,15\left(mol\right)\\n_{CO_2}=0,2\left(mol\right)\\n_{NO_2}=0,5\left(mol\right)\end{matrix}\right.\)
=> \(M_B=\dfrac{0,15.32+0,2.44+0,5.46}{0,15+0,2+0,5}=\dfrac{732}{17}\)
dB/He= \(\dfrac{732}{17}:4=\dfrac{183}{17}\approx10,77\)
a)
Dựa vào màu sắc:
+ NO: Chất khí không màu
+ NO2: Chất khí màu nâu
b)
Gọi số mol NO2, O2 là a, b (mol)
\(M=\dfrac{46a+32b}{a+b}=17,75.2=35,5\left(g/mol\right)\)
=> 10,5a = 3,5b
=> 3a = b
\(\left\{{}\begin{matrix}\%V_{NO_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{O_2}=100\%-25\%=75\%\end{matrix}\right.\)
ta có \(d_{A\O_2 }=0.25\Rightarrow M_A=0.25\times32=8\)
a, Dùng đường chéo ta có
\(\Rightarrow\dfrac{n_{H_2}}{n_{O_2}}=\dfrac{24}{6}=4\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{H_2}=\dfrac{4}{5}\times100=80\%\\\%V_{O_2}=\dfrac{1}{5}\times100=20\%\end{matrix}\right.\)
b.\(V_A=\dfrac{11.2}{22.4}=0.5\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0.4\left(mol\right)\\V_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
PTHH: \(2H_2+O_2\rightarrow2H_2O\)
Trước pu 0.4 0.1
Pu 0.2 0.1
Sau pu 0.2 0 0.2
\(\Rightarrow m_{H_2O}=0.2\times18=3,6\left(g\right)\)
\(\dfrac{4}{5}\)ở đâu ra