hòa tan hoàn toàn hỗn hợp gồm4,6 gam na và 6,2 g na2o vào 100 g nước thu đc dd A . tính nồng độ % của A
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Ta có \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(m_{NaOH}=100.16\%=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Theo PT: \(n_{Na}=2n_{H_2}=0,2\left(mol\right)\)
\(n_{NaOH}=n_{Na}+2n_{Na_2O}\Rightarrow n_{Na_2O}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na}=\dfrac{0,2.23}{0,2.23+0,1.62}.100\%\approx42,6\%\\\%m_{Na_2O}\approx57,4\%\end{matrix}\right.\)
\(n_{CuSO_4}=\dfrac{50}{250}=0.2\left(mol\right)\)
\(n_{FeSO_4}=\dfrac{27.8}{278}=0.1\left(mol\right)\)
\(C_{M_{CuSO_4}}=C_{M_{FeSO_4}}=\dfrac{0.1}{0.1964}=0.5\left(M\right)\)
\(m_{dd_A}=50+27.8+196.4=274.2\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.1\cdot160}{274.2}\cdot100\%=6.47\%\)
\(C\%_{FeSO_4}=\dfrac{0.1\cdot152}{274.2}\cdot100\%=5.54\%\)
\(n_{CuSO_4.5H_2O}=\dfrac{50}{250}=0,2\left(mol\right)\)
=> \(m_{CuSO_4}=0,2.160=32\left(g\right)\)
\(m_{H_2O}=0,2.5.18=18\left(g\right)\)
\(n_{FeSO_4.7H_2O}=\dfrac{27,8}{278}=0,1\left(mol\right)\)=> \(m_{FeSO_4}=0,1.152=15,2\left(g\right)\)
\(m_{H_2O}=0,1.7.18=12,6\left(g\right)\)
\(m_{dd}=196,4+50+27,8=274,2\left(g\right)\)
\(V_{dd}=\dfrac{196,4+18+12,6}{1000}=0,227\left(l\right)\)
=> \(CM_{CuSO_4}=\dfrac{0,2}{0,227}=0,72M\)
\(C\%_{CuSO_4}=\dfrac{32}{274,2}.100=11,67\%\)
\(CM_{FeSO_4}=\dfrac{0,1}{0,227}=0,44M\)
\(C\%_{CuSO_4}=\dfrac{15,2}{274,2}.100=5,54\%\)
A) có 2 pthh
Na2o + h2o ----> 2Naoh
2Na +2 h2o ------> 2naoh + h2
N khí. H2 = 0,56/22,4 =0,025 (mol)
Gọi x và y lần lượt là số mol của bà và na2o
Viết lại pt
2Na +2 h2o----> 2 naoh + h2
X mol. X/2 moll
Na2o + h2o-----> 2naoh
Xin lỗi bài này có gif đó sai sai xin bí tay
a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(a,n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,1 0,1 0,2
\(C_{M\left(A\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(m_{H_2} = 8,5 + 50 - 58,4 = 0,1(gam)\\ n_{H_2} = \dfrac{0,1}{2} = 0,05(mol)\\ 2Na + 2H_2O \to 2NaOH + H_2\\ Na_2O + H_2O \to 2NaOH\\ n_{Na} = 2n_{H_2} = 0,05.2 = 0,1(mol)\\ \Rightarrow n_{Na_2O} = \dfrac{8,5-0,1.23}{62}=0,1(mol)\\ n_{NaOH} = 2n_{Na_2O} + n_{Na} = 0,3(mol)\\ C\%_{NaOH} = \dfrac{0,3.40}{58,4}.100\% = 20,55\%\)
Coi X gồm Na, Ba và O.
Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{20,52}{171}=0,12\left(mol\right)\)
BTNT Ba, có: nBa = nBa(OH)2 = 0,12 (mol)
Gọi: \(\left\{{}\begin{matrix}n_{Na}=x\left(mol\right)\\n_O=y\left(mol\right)\end{matrix}\right.\) ⇒ 23x + 16y = 21,9 - 0,12.137 (1)
Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
BT e, có: nNa + 2nBa = 2nO + 2nH2 ⇒ x + 0,12.2 = 2y + 0,05.2 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,14\left(mol\right)\\y=0,14\left(mol\right)\end{matrix}\right.\)
BTNT Na, có: nNaOH = nNa = 0,14 (mol)
⇒ m = mNaOH = 0,14.40 = 5,6 (g)
\(n_{Na}=\dfrac{13,8}{23}=0,6\left(mol\right)\\ pthh:Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
0,6 0,6 0,3
\(V_{H_2}=0,3.22,4=6,72\left(l\right)\\ c,m_{\text{dd}}=13,8+286,8-\left(0,3.2\right)=300\left(g\right)\\ C\%=\dfrac{0,6.40}{300}.100\%=8\%\)
\(n_{Na}\) = \(\dfrac{13,8}{23}\) = 0,6 mol
Theo PTHH:
a) \(2Na+2H_2O\underrightarrow{t^o}2NaOH+H_2\)
2 2 2 1 (mol)
0,6 \(\rightarrow\) 0,6 \(\rightarrow\) 0,6 \(\rightarrow\) 0,3 (mol)
b) \(V_{H_2}\) = 0,3.22,4 = 6,72l
c) \(m_{dd}\) = 13,8 + 286,8 - 0,3.2 = 300g
\(C\%\) = \(\dfrac{0,6.40}{300}\).100% = 8%
Gọi \(n_{H_2}=5a\left(mol\right)\) \(\Rightarrow n_{CO_2}=11a\left(mol\right)\)
\(\Rightarrow5a+11a=\dfrac{3,584}{22,4}\) \(\Rightarrow a=0,01\) \(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,05\left(mol\right)\\n_{CO_2}=0,11\left(mol\right)\end{matrix}\right.\) \(\Rightarrow m_{khí}=0,05\cdot2+0,11\cdot44=4,94\left(g\right)\)
Ta có: \(n_{HCl}=\dfrac{188\cdot1,25\cdot7,3\%}{36,5}=0,47\left(mol\right)\) \(\Rightarrow m_{HCl}=0,47\cdot36,5=17,155\left(g\right)\)
Bảo toàn Hidro: \(n_{H_2O}=\dfrac{1}{2}n_{HCl}=0,235\left(mol\right)\) \(\Rightarrow m_{H_2O}=0,235\cdot18=4,23\left(g\right)\)
Bảo toàn khối lượng: \(m_{NaCl}=m_{hhX}+m_{HCl}-m_{khí}-m_{H_2O}=27,945\left(g\right)\)
Mặt khác: \(m_{ddHCl}=188\cdot1,25=235\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.pư\right)}=m_{hhX}+m_{ddHCl}-m_{khí}=250,02\left(g\right)\)
\(\Rightarrow C\%_{NaCl}=\dfrac{27,945}{250,02}\cdot100\%\approx11,18\%\)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}+2n_{Na_2O}=\dfrac{4,6}{23}+2\cdot\dfrac{6,2}{62}=0,3\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3\cdot40=12\left(g\right)\\m_{H_2}=0,05\cdot2=0,1\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na}+m_{Na_2O}+m_{H_2O}-m_{H_2}=110,7\left(g\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{12}{110,7}\cdot100\%\approx10,84\%\)
Theo gt ta có: $n_{Na}=0,2(mol);n_{Na_2O}=0,1(mol)$
$2Na+2H_2O\rightarrow 2NaOH+H_2$
$Na_2O+H_2O\rightarrow 2NaOH$
Ta có: $n_{NaOH}=0,4(mol);n_{H_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{dd}=110,6(g)$
$\Rightarrow \%C_{NaOH}=14,46\%$