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nNa = \(\dfrac{6,9}{23}\) =0,3 mol
2Na + 2H2O ->2 NaOH + H2
0,3mol ->0,3mol->0,15mol
=>mNaOH = 0,3 . 40 = 12g
=> mdd = 6,9 + 50 - 0,15.2 = 56,6 g
=> C% = \(\dfrac{12}{56,6}\).100% = 21,2%
mNaOH = \(\dfrac{4\times200}{100}=8\left(g\right)\)
=> nNaOH = \(\dfrac{8}{40}=0,2\left(mol\right)\)
Pt: 2NaOH + H2SO4 --> Na2SO4 + 2H2O
....0,2 mol--> 0,1 mol---> 0,1 mol
C% dd H2SO4 đã dùng = \(\dfrac{0,1\times98}{51}.100\%=19,216\%\)
mNa2SO4 = 0,1 . 142 = 14,2 (g)
mdd sau pứ = mdd NaOH + mdd H2SO4 = 200 + 51 = 251 (g)
C% dd Na2SO4 = \(\dfrac{14,2}{251}.100\%=5,657\%\)
Lần sau đăng 2-3 bài 1 lần thôi nha
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1. \(n_{AgNO_3}=1.0,02=0,02\left(mol\right)\)
\(n_{HCl}=0,15.0,5=0,075\left(mol\right)\)
Pt: \(AgNO_3+HCl\rightarrow AgCl+HNO_3\)
0,02mol 0,075mol \(\rightarrow0,02mol\)
Lập tỉ số: \(n_{AgNO_3}:n_{HCl}=0,02< 0,075\)
\(\Rightarrow AgNO_3\) hết; HCl dư
\(n_{HCl\left(dư\right)}=0,075-0,02=0,055\left(mol\right)\)
\(\Sigma_{V\left(spu\right)}=0,02+0,15=0,17\left(l\right)\)
\(C_{M_{HCl}}=\dfrac{0,055}{0,17}=0,32M\)
\(C_{M_{HNO_3}}=\dfrac{0,02}{0,17}=0,12M\)
\(m_{AgNO_3}=D.V=1,1.20=22\left(g\right)\)
\(m_{HCl}=D.V=1,05.150=157,5\left(g\right)\)
\(m_{AgCl}=0,02.143,5=2,87\left(g\right)\)
\(\Sigma_{m_{\left(spu\right)}}=22+157,5-2,87=176,63\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{0,055.36,5.100}{176,63}=1,13\%\)
\(C\%_{HNO_3}=\dfrac{0,02.63.100}{176,63}=0,71\%\)
3.Pt: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
40 73 95
a \(\rightarrow\) \(\dfrac{73}{40}a\) \(\rightarrow\) \(\dfrac{95}{40}a\)
Ta có : \(\dfrac{95}{40}a=a+55\)
\(\Rightarrow a=40\)
\(m_{ct}=\dfrac{m.3,65}{100}\)(1)
\(m_{HCl}=\dfrac{73}{40}.40=73\left(g\right)\)(2)
(1)(2)\(\Rightarrow\dfrac{m.3,65}{100}=73\)
\(\Rightarrow m=2000\)
\(C\%_{MgCl_2}=\dfrac{a+55}{a+m}.100=\dfrac{40+55}{40+2000}.100=4,65\%\)
\(m_{Na2SO4}=355.\frac{10}{100}=35,5\left(g\right)\)
\(\rightarrow n_{Na2SO4}=\frac{35,5}{142}=0,25\left(mol\right)\)
PTHH: Na2SO4 + BaCl2 → BaSO4 ↓ + 2NaCl
_______0,25_______0,25___0,25________0,5 (mol)
BTKL: m dd sau pư = m dd Na2SO4 + m dd BaCl2 – mBaSO4
= 355 + 200 – 0,25.233 = 496,75 (g)
Dung dịch sau phản ứng chỉ chứa 0,5 mol NaCl
\(C\%_{NaCl}=\frac{0,5.58.5}{496,75}.100\%=5,89\%\)
a) mBaCl2 = \(\dfrac{20.208}{100}=41,6\) (g)
=> nBaCl2 \(\dfrac{41,6}{208}=0,2\) mol
nFe2(SO4)3 \(\dfrac{20}{400}=0,05\) mol
Pt: 3BaCl2 + Fe2(SO4)3 --> 3BaSO4 + 2FeCl3
0,15 mol---> 0,05 mol------> 0,15 mol-> 0,1 mol
Xét tỉ lệ mol giữa BaCl2 và Fe2(SO4)3:
\(\dfrac{0,2}{3}>\dfrac{0,05}{1}\)
Vậy BaCl2 dư
mFeCl3 = 0,1 . 162,5 = 16,25 (g)
mBaCl2 dư = (0,2 - 0,15) . 208 = 10,4 (g)
mBaSO4 = 0,15 . 233 = 34,95 (g)
mdd sau pứ = mdd BaCl2 + mFe2(SO4)3 - mBaSO4
....................= 208 + 20 - 34,95 = 193,05 (g)
C% dd FeCl3 = \(\dfrac{16,25}{193,05}.100\%=8,42\%\)
C% dd BaCl2 dư = \(\dfrac{10,4}{193,05}.100\%=5,4\%\)
b) Pt: FeCl3 + 3NaOH --> Fe(OH)3 + 3NaCl
........0,1 mol---------------> 0,1 mol
..........2Fe(OH)3 --to--> Fe2O3 + 3H2O
..........0,1 mol----------> 0,05 mol
mFe2O3 = 0,05 . 160 = 8 (g)
mik từng yêu cầu bạn : nên đăng từng câu một ( đây là lần thứ 3)
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Theo bài ra ta có :
\(\dfrac{V_A}{V_B}=\dfrac{3}{5}\Rightarrow\dfrac{V_A}{3}=\dfrac{V_B}{5}=V\left(l\right)\)
=> \(V_A=3V\left(l\right)\) , \(V_B=5V\left(l\right)\)
Ta có CM(A) = 2CM(B) hay \(\dfrac{n_A}{V_A}=\dfrac{2n_B}{V_B}\) \(\Leftrightarrow\dfrac{n_A}{3V}=\dfrac{2n_B}{5V}\)=> 5V.nA= 6V.nB <=>\(\dfrac{n_A}{n_B}=\dfrac{6}{5}=1,2\Rightarrow n_A=1,2n_B\)
CM(dung dịch sau khi trộn) = \(\dfrac{n_A+n_B}{V_A+V_B}\)= \(\dfrac{2,2n_B}{8V}\)= 3(M)
<=>0,275\(\dfrac{n_B}{V}=3\left(M\right)\)
<=>\(0,275.5.\dfrac{n_B}{5V}=3\left(M\right)\Leftrightarrow1,375.C_{M\left(B\right)}=3\left(M\right)\)
<=> CM(B) \(\approx2,182\) (M) =>CM(A) = 4,364(M)
1)
nBaCl2=\(\frac{\text{150.10%.1,04}}{208}\)=0,075 mol
nH2SO4= \(\frac{\text{50.20%.1,225}}{98}\)=0,125 mol
PTHH:
BaCl2+ H2SO4→ BaSO4+ 2HCl
0,075___0,075____0,075___0,15
mdd sau pư= 150.1,04+50.1,225- 0,075.233= 199,75 g
C%HCl=\(\frac{\text{0,15.36,5}}{199,75.100\%}\)=2,74%
C% H2SO4 dư= \(\frac{\text{(0,125- 0,075).98}}{199,75}\)=2,45%
2)
nBa=\(\frac{\text{10,275}}{137}\)=0,075 mol
nH2So4 dư= 0,125- 0,075= 0,05 mol
PTHH:
Ba + H2SO4 → BaSO4+ H2
0,025__0,025___ 0,025
Ba + 2HCl → BaCl2+ H2
0,0375_0,075__0,0375
Ba + 2H2O→ Ba(OH)2 + H2
0,0125 0,0125
mdd sau pư= \(\frac{\text{199,75}}{2}\)+ 10,275- 0,025.233- 0,025.2=104,275g
C%Bacl2= \(\frac{\text{0,0375.208}}{104,275.100\%}\)=7,48%
C% Ba(OH)2= \(\frac{\text{0,0125.171}}{104,275.100\%}\)=2,05%
Ta có: \(m_{BaCl_2}=200.5,2\%=10,4\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\)
\(m_{H_2SO_4}=58,8.20\%=11,76\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{11,76}{98}=0,12\left(mol\right)\)
PT: \(BaCl_2+H_2SO_4\rightarrow BaSO_{4\downarrow}+2HCl\)
Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{0,12}{1}\), ta được H2SO4 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\n_{HCl}=2n_{BaCl_2}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ nH2SO4 (dư) = 0,12 - 0,05 = 0,07 (mol)
Ta có: m dd sau pư = m dd BaCl2 + m dd H2SO4 - mBaSO4 = 200 + 58,8 - 0,05.233 = 247,15 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,07.98}{247,15}.100\%\approx2,78\%\\C\%_{HCl}=\dfrac{0,1.36,5}{247,15}.100\%\approx1,48\%\end{matrix}\right.\)
Bạn tham khảo nhé!