\(n_{NaOH}=0,15.0,6=0,09\left(mol\right)\\ n_{H_2SO_4}=0,05.0,15=0,0075\left(mol\right)\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ Vì:\dfrac{0,09}{2}>\dfrac{0,0075}{2}\Rightarrow NaOHdư\\ n_{NaOH\left(dư\right)}=0,09-2.0,0075=0,075\left(mol\right)\\ \left[OH^-\right]=\left[NaOH\right]=\dfrac{0,075}{0,15+0,05}=0,375\left(M\right)\\ \Rightarrow C\)

\(n_{NaOH}=0,1.0,2=0,02\left(mol\right)\\ n_{HCl}=0,3.0,1=0,03\left(mol\right)\\ NaOH+HCl\rightarrow NaCl+H_2O\\ Vì:\dfrac{0,02}{1}< \dfrac{0,03}{1}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,03-0,02=0,01\left(mol\right)\\ \left[H^+\right]=\left[HCl_{dư}\right]=\dfrac{0,01}{0,1+0,1}=0,05\left(M\right)\\ \Rightarrow D\)

\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)

\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)

\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)

PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

\(n_{H_2SO_4}=C_M.V=0,2.0,5=0,1\left(mol\right)\)

\(n_{NaOH}=2n_{H_2SO_4}=0,2\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{n}{V}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

\(n_{H_2SO_4}=0,2.0,5=0,1\left(mol\right)\)

PTHH: 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O

Mol:     0,2                0,1

\(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

$C_6H_5C_2H_5 + Br_2 \xrightarrow{t^o,Fe} Br-C_6H_4-C_2H_5(1-brom-4-etylbenzen) + HBr$

\(n_{HCl}=Cm.V=1.0,1=1mol\)

\(n_{H_2SO_4}=Cm.V=0,5.0,1=0,05mol\)

Thể thích của dd D là 200ml = 0,2l

\([H^+]=\frac{n_{HCl}+2.n_{H_2SO_4}}{V}=\frac{0,1+0,1}{0,2}=1M\)

\([Cl^-]=\frac{n_{HCl}}{V}=\frac{0,1}{0,2}=0,5M\)

\([SO_4^{2-}]=\frac{n_{H_2SO_4}}{V}=\frac{0,05}{0,2}=0,25M\)

Khi cho dd D vào \(Ba\left(OH\right)_2\) chỉ có \(H_2SO_4\) tác dụng, tạo kết tủa

\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)

\(0,05....\rightarrow0,05mol\)

\(\rightarrow m_{BaSO_4}=n.M=0,05.233=11,65g\)

Bảo toàn nguyên tố ta có

\(n_{H_2}=n_{H_2SO_4}=\dfrac{6,72}{22,4}=0.3\) (mol)

Sau khi cô cạn dd ta được : ion kim loại : 11,3g và SO₄^2- 0.3 mol

⇒ m = 30.5 g

Hình như sai rồi đó ạ

 Muốn hợp tác giúp đỡ nhau thì liên hệ Fb:Quang Tâm(Sun).