Cho 37, 8 gam Na2SO3 phản ứng với 200 gam dung dịch axit H2SO4 19, 6%. Tính:
1, Thể tích khí sinh ra ở đktc.
2, Nồng độ phần trăm dung dịch thu được sau phản ứng.
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a) $n_{Na_2SO_3} = \dfrac{37,8}{126} = 0,3(mol)$
$n_{H_2SO_4} = \dfrac{200.19,6\%}{98} = 0,4(mol)$
$Na_2SO_3 + H_2SO_4 \to Na_2SO_4 + SO_2 + H_2O$
Ta thấy $n_{Na_2SO_3} : 1 < n_{H_2SO_4} :1$ nên $H_2SO_4$ dư
$n_{SO_2} = n_{Na_2SO_3} = 0,3(mol) \Rightarrow V_{SO_2} = 0,3.22,4 = 6,72(lít)$
b) $m_{dd\ sau\ pư} = 37,8 +200 - 0,3.64 = 218,6(gam)$
$n_{Na_2SO_4} = n_{H_2SO_4\ pư} = 0,3(mol) \Rightarrow n_{H_2SO_4\ dư} = 0,4 - 0,3 = 0,1(mol)$
$C\%_{Na_2SO_4} = \dfrac{0,3.142}{218,6}.100\% = 19,49\%$
$C\%_{H_2SO_4} = \dfrac{0,1.98}{218,6}.100\% = 4,48\%$
$n_{Na_2O} = \dfrac{9,3}{62} = 0,15(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,15.2 = 0,3(mol)$
$C_{M_{NaOH}} = \dfrac{0,3}{0,4} = 0,75M$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CO_2} = n_{CaCO_3} = \dfrac{15}{100} = 0,15(mol)$
$n_{NaOH} = \dfrac{80.12,5\%}{40} = 0,25(mol)$
Ta thấy \(1< \dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,25}{0,15}=1,67< 2\) nên X gồm $Na_2CO_3(a\ mol);NaHCO_3( b\ mol)$
$2NaOH + CO_2 \to Na_2CO_3 + H_2O$
$NaOH + CO_2 \to NaHCO_3$
Ta có : $2a + b = 0,25$ và $a + b = 0,15$
Suy ra : a = 0,1 ; b = 0,05
$m_{dd\ X} = m_{CO_2} + m_{dd\ NaOH} = 86,6(gam)$
$C\%_{Na_2CO_3} = \dfrac{0,1.106}{86,6}.100\% = 12,24\%$
$C\%_{NaHCO_3} = \dfrac{0,05.84}{86,6}.100\% = 4,85\%$
a)
Mg + 2HCl ---> MgCl2 + H2 (1)
MgO + 2HCl ---> MgCl2 + H2O (2)
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo (1): \(n_{Mg}=n_{H_2}=0,15\left(mol\right)\)
=> \(\left\{{}\begin{matrix}m_{Mg}=0,15.24=3,6\left(g\right)\\m_{MgO}=10-3,6=6,4\left(g\right)\end{matrix}\right.\)
c) \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{3,6}{10}.100\%=36\%\\\%m_{MgO}=100\%-36\%=64\%\end{matrix}\right.\)
d) \(n_{MgO}=\dfrac{6,4}{40}=0,16\left(mol\right)\)
Theo (1), (2): \(n_{HCl}=2n_{Mg}+2n_{MgO}=0,62\left(mol\right)\)
=> \(C_{M\left(HCl\right)}=\dfrac{0,62}{0,2}=3,1M\)
e) Theo (1), (2): \(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,31\left(mol\right)\)
=> mmuối = 0,31.95 = 29,45 (g)
f) \(C_{M\left(MgCl_2\right)}=\dfrac{0,31}{0,2}=1,55M\)
1)
$Fe + 2HCl \to FeCl_2 + H_2$
$CuO + 2HCl \to CuCl_2 + H_2O$
Theo PTHH, $n_{Fe} = n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol)$
$\%m_{Fe} = \dfrac{0,25.56}{30}.100\% = 46,67\%$
$\%m_{CuO} = 100\% - 46,67\% = 53,33\%$
2)
$n_{CuO} = \dfrac{30 - 0,25.56}{80} = 0,2(mol)$
Ta có : $n_{HCl} =2n_{Fe} + 2n_{CuO} = 0,9(mol)$
$\Rightarrow V_{dd\ HCl} =\dfrac{0,9}{1,6} = 0,5625(lít)$
1) \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,25<-0,5<------0,25<----0,25
=> \(\left\{{}\begin{matrix}m_{Fe}=0,25.56=14\left(g\right)\\n_{CuO}=30-14=16\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{14}{30}.100\%=46,67\%\\\%m_{CuO}=100\%-46,67\%=53,33\%\end{matrix}\right.\)
2) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PTHH: CuO + 2HCl ---> CuCl2 + H2O
0,2----->0,4
=> \(V_{ddHCl}=\dfrac{0,4+0,5}{1,6}=0,5625M\)
1)
$Fe + 2HCl \to FeCl_2 + H_2$
$CuO + 2HCl \to CuCl_2 + H_2O$
Theo PTHH, $n_{Fe} = n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol)$
$\%m_{Fe} = \dfrac{0,25.56}{30}.100\% = 46,67\%$
$\%m_{CuO} = 100\% - 46,67\% = 53,33\%$
2)
$n_{CuO} = \dfrac{30 - 0,25.56}{80} = 0,2(mol)$
Ta có : $n_{HCl} =2n_{Fe} + 2n_{CuO} = 0,9(mol)$
$\Rightarrow V_{dd\ HCl} =\dfrac{0,9}{1,6} = 0,5625(lít)$
Gọi nFe = x ; nCuO = y (mol)
Phương trình : Fe + 2HCl --> FeCl2 + H2
x -> 2x -> x
CuO + 2HCl ---> CuCl2 + H2O
Lại có \(x=n_{H_2}=\dfrac{V}{22,4}=\dfrac{5,6}{22,4}=0,25\)(mol)
=> \(m_{Fe}=n.M=0,25.56=14\left(g\right)\)
=> \(m_{Cu}=30-14=16\left(g\right)\)
=> \(\%Fe=46,7\%;\%Cu=53,3\%\)
b) \(V_{Hcl}=\dfrac{n}{C_M}=\dfrac{0,5}{1,6}=\dfrac{5}{16}\left(l\right)\)
a. \(n_{H_2}=\dfrac{6.72}{22,4}=0,3\left(mol\right)\)
PTHH : Mg + 2HCl -> MgCl2 + H2
PTHH : Fe + 2HCl -> FeCl2 + H2
Gọi \(n_{Mg}=a\left(mol\right);n_{Fe}=b\left(mol\right)\)
\(\Rightarrow24a+56b=10,4\left(g\right)\left(1\right)\)
\(\Rightarrow a+b=0,3\left(mol\right)\left(2\right)\)
Từ \(\left(1\right)\left(2\right)\Rightarrow a=0,2\left(mol\right),b=0,1\left(mol\right)\)
\(\%m_{Mg}=\dfrac{0,2.24}{10,4}=46,1\%\)
\(\%m_{Fe}=100\%-46,1\%=53,9\%\)
b. \(n_{hh}=0,1+0,2=0,3\left(mol\right)\)
Theo PT : \(n_{HCl}=2n_{hh}=0,6\left(mol\right)\)
\(C\%_{HCl}=\dfrac{0,6.36,5}{300}.100=7,3\%\)
c. Theo PT : \(n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\)
\(n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,2.95}{10,4+300-0,6}=6,13\%\\C\%_{FeCl_2}=\dfrac{0,1.127}{10,4+300-0,6}=4,09\%\end{matrix}\right.\)
1) $n_{Na_2SO_3} = \dfrac{37,8}{126} = 0,3(mol)$
$n_{H_2SO_4} = \dfrac{200.19,6\%}{98} = 0,4(mol)$
$Na_2SO_3 + H_2SO_4 \to Na_2SO_4 + SO_2 + H_2O$
Ta thấy $n_{Na_2SO_3} : 1 < n_{H_2SO_4} : 1$ nên $H_2SO_4$ dư
$n_{SO_2} = n_{Na_2SO_3} = 0,3(mol)$
$V_{SO_2} = 0,3.22,4 = 6,72(lít)$
2) Sau phản ứng, $m_{dd} = 37,8 + 200 - 0,3.64 = 218,6(gam)$
$n_{H_2SO_4\ pư} = n_{Na_2SO_3} = 0,3(mol) \Rightarrow n_{H_2SO_4\ dư} = 0,4 - 0,3 = 0,1(mol)$
$C\%_{H_2SO_4\ dư} = \dfrac{0,1.98}{218,6}.100\% = 4,48\%$
$C\%_{Na_2SO_4} = \dfrac{0,3.142}{218,6}.100\% = 19,49\%$