P (Z = 15): 1s22s22p63s23p3 Þ P có 5 electron hóa trị cần thêm 3 electron để đạt octet.

H (Z = 1): 1s1 H có 1 electron hóa trị cần thêm 1 electron để đạt octet.

Khi hình thành liên kết, P góp chung 3 electron với 3 electron của 3 H ⇒ Trong PH₃, xung quanh P có 8 electron giống khí hiếm Ar còn 3 H đều có 2 electron giống khí hiếm He

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