Đốt cháy 33,6g sắt trong bình chứa . Trong bình chứa 12,395 l khí O2 (đktc) tạo thành m g Fe3O4.
a) Tính giá trị m nhỏ
b) dùng 5,4198.1023 Phân tử H2 để khử oxide. tính khối lượng kim loại thu được.
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nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a.\(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{19,5}{65}=0,3mol\)
\(2Zn+O_2\rightarrow\left(t^o\right)2ZnO\)
0,3 0,15 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
0,1 0,15 ( mol )
\(m_{KClO_3}=n_{KClO_3}.M_{KClO_3}=0,1.122,5=12,25g\)
a) PTHH: 2Zn + O2 → 2ZnO
2 1 2
0,3 0,15 0,3
nZn = \(\dfrac{m}{M}\) = \(\dfrac{19,5}{65}\) = 0,3 (mol)
mO2 = n.M = 0,15 . 16 = 2,4 (g)
VO2 = m . 22,4 = 2,4 . 22,4 = 53,76 (l)
b) 2KClO3 → 2KCl + 3O2 ↑
0,1 0,1 0,15
mKClO3 = n . M = 0,1 . 122,5 = 12,25 (g)
nFe = 16,8 : 56 = 0,3 (mol)
pthh :3 Fe + 2O2 -t--> Fe3O4
0,3--------------> 0,1 (mol)
=> mFe3O4 =0,1 . 232 = 23,2(G)
nH2 = 44,8 : 22,4 = 2 (g)
pthh : Fe3O4 + H2 -t--> Fe + H2O
LTL : 0,1 / 1 < 2 /1
=> H2 du
nH2 (pu) = nFe3O4 = 0,1 (mol)
=> nH2 (d) = 2-0,1 = 1,9 (mol)
mH2 (d) = 1,9 . 2 = 3,8 (g)
a) \(n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
0,6--->0,4------->0,2 (mol)
=> \(m_{Fe_3O_4}=0,2.232=46,4\left(g\right)\)
b) \(V_{O_2\left(\text{đ}kc\right)}=0,4.24,79=9,916\left(l\right)\)
c) PTHH: \(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\)
\(\dfrac{4}{15}\)<-------------------0,4 (mol)
=> \(m_{KClO_3}=\dfrac{4}{15}.122,5=\dfrac{98}{3}\left(g\right)\)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
a, Ta có: \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{2}n_{O_2}=0,075\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,075.232=17,4\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}KMnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
Bạn tham khảo nhé!
a. \(n_{Fe}=\dfrac{11.2}{56}=0,2\left(mol\right)\)
PTHH : 3Fe + 2O2 ---to---> Fe3O4
0,2 \(\dfrac{0.4}{3}\)
b. \(V_{O_2}=\dfrac{0.4}{3}.22,4=\dfrac{8.96}{3}\left(l\right)\)
c. PTHH : 2KClO3 -> 2KCl + 3O2
\(\dfrac{0.8}{3}\) \(\dfrac{0.4}{3}\)
\(m_{KClO_3}=\dfrac{0.8}{3}.122,5=\dfrac{98}{3}\left(g\right)\)
a, Ta có: \(n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
\(n_{O_2}=\dfrac{12,395}{24,79}=0,5\left(mol\right)\)
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Xét tỉ lệ: \(\dfrac{0,6}{3}< \dfrac{0,5}{2}\), ta được O2 dư.
Theo PT: \(n_{Fe_3O_3}=\dfrac{1}{3}n_{Fe}=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,2.232=46,4\left(g\right)\)
b, \(n_{H_2}=\dfrac{5,4198.10^{23}}{6,022.10^{23}}=0,9\left(mol\right)\)
PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,9}{4}\), ta được H2 dư.
Theo PT: \(n_{Fe}=3n_{Fe_3O_4}=0,6\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,6.56=33,6\left(g\right)\)