trung hòa 200ml dung dịch h2so4 1m bằng dung dịch naoh 1m. Tính nồng độ mol các chất có trong dung dịch thu được sau phản ứng
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a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)
\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)
0,2.............0,1
Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư
Dung dịch D gồm NaNO3 và NaOH dư
\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)
\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)
\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
Ion trong dung dịch D : Na+ , NO3-, OH-
\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)
\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)
\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)
b)Trong dung dịch D chỉ có NaOH dư phản ứng
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
0,1................0,05
=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)
a) \(n_{NaOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,15.2=0,3\left(mol\right)\)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,2 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ NaOH hết, H2SO4 dư
\(m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
b) Vdd sau pứ = 0,2 + 0,15 = 0,35 (l)
\(C_{M_{ddNa_2SO_4}}=\dfrac{0,1}{0,35}=\dfrac{2}{7}\approx0,2857M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,35}=\dfrac{4}{7}\approx0,57M\)
\(n_{CuO}=\dfrac{8}{80}=0.1\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.1...........0.1.........0.1\)
\(n_{NaOH}=0.24\cdot0.5=0.12\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.12..........0.06\)
\(n_{H_2SO_4}=0.1+0.06=0.16\left(mol\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.16}{1}=0.16\left(l\right)\)
\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.06}{0.16}=0.375\left(M\right)\)
\(C_{M_{CuSO_4}}=\dfrac{0.1}{0.16}=0.625\left(M\right)\)
\(n_{H_2SO_4}=0,4\cdot1=0,4mol\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
0,8 0,4
\(V_{NaOH}=\dfrac{0,8}{0,5}=1,6l\)
\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)
\(n_{H_2SO_4}=0.3\cdot0.5=0.15\left(mol\right)\)
\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.1..........0.05...............0.05\)
Dung dịch D : 0.05 (mol) K2SO4 , 0.1 (mol) H2SO4
\(\left[K^+\right]=\dfrac{0.05\cdot2}{0.1+0.3}=0.25\left(M\right)\)
\(\left[H^+\right]=\dfrac{0.1\cdot2}{0.1+0.3}=0.5\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.1}{0.1+0.3}=0.375\left(M\right)\)
\(2NaOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)
\(0.2..................0.1\)
\(V_{dd_{NaOH}}=\dfrac{0.2}{1}=0.2\left(l\right)\)
\(a,H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=1.0,4=0,4\left(mol\right)\\ n_{NaOH}=0,4.2=0,8\left(mol\right)\\ b,V_{ddNaOH}=\dfrac{0,8}{0,5}=1,6\left(l\right)\\ c,n_{Na_2SO_4}=n_{H_2SO_4}=0,4\left(mol\right)\\ V_{ddNa_2SO_4}=0,4+1,6=2\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,4}{2}=0,2\left(M\right)\)
`C1:`
`2NaOH+H_2 SO_4 ->Na_2 SO_4 +2H_2 O`
`n_[H_2 SO_4]=0,2.1=0,2(mol)`
`n_[NaOH]=[200.10]/[100.40]=0,5(mol)`
Ta có: `[0,2]/1 < [0,5]/2=>NaOH` dư, `H_2 SO_4` hết.
`=>` Quỳ tím chuyển xanh.
`C2:`
`SO_3 +H_2 O->H_2 SO_4`
`0,2` `0,2` `(mol)`
`n_[SO_3]=16/80=0,2(mol)`
`C_[M_[H_2 SO_4]]=[0,2]/[0,25]=0,8(M)`
Có: \(n_{NaOH}=0,2.1=0,2\left(mol\right)\)
PT: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
______0,2_____0,1_______0,1 (mol)
a, \(V_{ddH_2SO_4}=\dfrac{0,1}{2}=0,05\left(l\right)\)
b, \(C_{M_{Na_2SO_4}}=\dfrac{0,1}{0,2+0,05}=0,4M\)
Bạn tham khảo nhé!
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
PT: \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
Theo PT: \(n_{Na_2SO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{H_2SO_4}=0,4\left(mol\right)\)
\(\Rightarrow V_{ddNaOH}=\dfrac{0,4}{1}=0,4\left(l\right)\)
\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,2}{0,2+0,4}=\dfrac{1}{3}\left(M\right)\)