Cho 5,4g Aluminum tác dụng với dung dịch H2SO4 (2M) a. Tính thể tích khí hydrogen tạo thành ở điều kiện chuẩn và khối lượng muối tạo thành. b. Tính thể tích dung dịch H2SO4 (2M) đã dùng.
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a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
Bài 2 :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH :
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(b,V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)
\(c,C_{M\left(Fe_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\)
Bài 3 :
\(n_{Mg}=\dfrac{4.8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2O\)
0,2 0,2 0,2 0,2
\(m_{MgSO_4}=0,2.120=24\left(g\right)\)
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(c,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(d,C_{M\left(MgSO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 4 :
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH :
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
0,3 0,45 0,15 0,45
\(V_{H_2}=0,45.24,79=11,1555\left(l\right)\)
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\)
\(C\%_{H_2SO_4}=\dfrac{44,1}{300}.100\%=14,7\%\)
\(m_{Al_2\left(SO_4\right)_3}=0,15.342=51,3\left(g\right)\)
\(m_{dd}=8,1+300-\left(0,45.2\right)=307,2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{51,3}{307,2}.100\%\approx16,7\%\)
Bài 5 :
\(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,4}{0,2}=2\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
1:
a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
______0,2------>0,2------------------->0,2_____(mol)
=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b) \(V_{ddH_2SO_4}=\dfrac{0,2}{1}=0,2\left(l\right)\)
2:
a)
\(n_{HCl}=2.0,2=0,4\left(mol\right)\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
______0,2<------0,4------------------>0,2______(mol)
=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)
b) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(4.a/n_{Al}=\dfrac{5,4}{27}=0,2mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(V_{H_2}=0,3.24,79=7,437l\\ b/C_{\%H_2SO_4}=\dfrac{0,3.98}{150}\cdot100=19,6\%\\ c/m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2g\)
\(5.a/n_{MgO}=\dfrac{4}{40}=0,1mol\\ MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,1 0,2 0,1 0,1
\(C_{\%HCl}=\dfrac{0,2.36,5}{200}\cdot100=3,65\%\\ b/C_{\%MgCl_2}=\dfrac{0,1.95}{200+4}\cdot100=4,66\%\\ c/NaOH+HCl\rightarrow NaCl+H_2O\\ n_{NaOH}=n_{HCl}=0,2mol\\ V_{NaOH}=\dfrac{0,2}{1}=0,2l=200ml\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right);n_{HCl}=2.0,1=0,2\left(mol\right)\\ m_{ZnCl_2}=136.0,1=13,6\left(g\right)\\ c,V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(lít\right)\)
\(a,n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,01--->0,02---->0,01---->0,01
\(V_{H_2}=0,01.22,4=0,224\left(l\right)\\ b,m_{ZnCl_2}=0,01.136=1,36\left(g\right)\\ V_{ddHCl}=\dfrac{0,02}{2}=0,01\left(l\right)\)
a, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.24,79=7,437\left(l\right)\)
\(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\Rightarrow m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\)
b, \(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)