Hòa tan 2,7 g Al cần dùng vừa đủ m gam dd H2SO4 9,8%. Sau p/ứ thu đc dd X và khí H2.Tính nồng độ % muối có trong dd X.
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.2.....................0.2..........0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng }}=4.8+250-0.2\cdot2=254.4\left(g\right)\)
\(m_{MgCl_2}=0.2\cdot95=19\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{19}{254.4}\cdot100\%=7.47\%\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
____0,2____0,4______0,2____0,2 (mol)
b, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, Ta có: m dd sau pư = mMg + m dd HCl - mH2 = 4,8 + 250 - 0,2.2 = 254,4 (g)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,2.95}{254,4}.100\%\approx7,47\%\)
Bạn tham khảo nhé!
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
\(a)n_{H_2}=\dfrac{7,437}{24,79}=0,3mol\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
\(\%m_{Al}=\dfrac{0,2.27}{15,6}\cdot100=34,62\%\\ \%m_{Al_2O_3}=100-34,62=65,38\%\\ b)n_{Al_2O_3}=\dfrac{\left(15,6-0,2.27\right)}{102}=0,1mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,15 0,05 0,15
\(m_{ddH_2SO_4}=\dfrac{\left(0,3+0,15\right).98}{9,8}\cdot100=450g\)
c) \(C_{\%Al_2\left(SO_4\right)_3}=\dfrac{\left(0,1+0,05\right)342}{15,6+450-0,3.2}\cdot100=11\%\)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
BTNT, có: \(n_{SO_4}=n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\)
Mà: m muối = mKL + mSO4
⇒ m = mKL = 93,6 - 0,6.96 = 36 (g)
Bạn tham khảo nhé!
\(n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
\(0.05.......0.05......0.05...........0.05\)
\(m_{Zn}=0.05\cdot65=3.25\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.05}{0.2}=0.25\left(M\right)\)
\(m_{ZnSO_4}=0.05\cdot161=8.05\left(g\right)\)
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
B1:
2NaOH+H2SO4\(\rightarrow\)Na2SO4+2H2O
nNaOH=\(\frac{4}{40}=0.1\)mol
=>nH2SO4=\(\frac{1}{2}\)nNaOH=0.05 mol
=>CM=\(\frac{n_{H2SO42}}{V}\)=\(\frac{0.05}{200}\)=2,5.10-4 (M)
B2:
Mg+\(\frac{1}{2}\)O2\(\underrightarrow{t^0}\)MgO (1)
MgO+2HCl\(\rightarrow\)MgCl2+H2O (2)
nMg(1)=\(\frac{0,36}{24}=0,015mol\)
=>nMgO(1)=0,015=nMgO(2)
nHCl(2)=2nMgO(2)=0,03mol
=>CM(HCl)=\(\frac{n_{HCl}}{V}=\frac{0,03}{100}=3.10^{-4}M\)
$n_{HCl} = 0,8.0,5 = 0,4(mol) ; n_{H_2SO_4} = 0,6(mol) ;n_{H_2} = 0,2(mol)$
$n_{H(trong\ axit)} = 0,4 + 0,6.2 = 1,6(mol)$
Bảo toàn H : $n_{H_2O} = \dfrac{n_{H(trong\ axit)} - 2n_{H_2} }{2} = 0,6(mol)$
Bảo toàn khối lượng :
$m = 88,7 + 0,6.18 + 0,2.2 - 0,4.36,5 - 0,6.98 = 26,5(gam)$
Gọi \(n_{H_2}=5a\left(mol\right)\) \(\Rightarrow n_{CO_2}=11a\left(mol\right)\)
\(\Rightarrow5a+11a=\dfrac{3,584}{22,4}\) \(\Rightarrow a=0,01\) \(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,05\left(mol\right)\\n_{CO_2}=0,11\left(mol\right)\end{matrix}\right.\) \(\Rightarrow m_{khí}=0,05\cdot2+0,11\cdot44=4,94\left(g\right)\)
Ta có: \(n_{HCl}=\dfrac{188\cdot1,25\cdot7,3\%}{36,5}=0,47\left(mol\right)\) \(\Rightarrow m_{HCl}=0,47\cdot36,5=17,155\left(g\right)\)
Bảo toàn Hidro: \(n_{H_2O}=\dfrac{1}{2}n_{HCl}=0,235\left(mol\right)\) \(\Rightarrow m_{H_2O}=0,235\cdot18=4,23\left(g\right)\)
Bảo toàn khối lượng: \(m_{NaCl}=m_{hhX}+m_{HCl}-m_{khí}-m_{H_2O}=27,945\left(g\right)\)
Mặt khác: \(m_{ddHCl}=188\cdot1,25=235\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.pư\right)}=m_{hhX}+m_{ddHCl}-m_{khí}=250,02\left(g\right)\)
\(\Rightarrow C\%_{NaCl}=\dfrac{27,945}{250,02}\cdot100\%\approx11,18\%\)