Cho 5,6 lít khí O2 ở đktc tác dụng với 3,1 gam P
a. Oxi hay photpho chất nào dư và dư bao nhiêu g
b. Tính khối lượng sản phẩm
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PTHH: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
a) Ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)
\(\Rightarrow n_{P_2O_5}=0,05\left(mol\right)\) \(\Rightarrow m_{P_2O_5}=0,05\cdot142=7,1\left(g\right)\)
b) Ta có: \(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{4}< \dfrac{0,25}{5}\) \(\Rightarrow\) Photpho p/ứ hết, Oxi còn dư
\(\Rightarrow n_{O_2\left(dư\right)}=0,25-0,125=0,125\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,125\cdot32=4\left(g\right)\)
\(a) n_P = \dfrac{3,1}{31} = 0,1(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_{P_2O_5} = \dfrac{1}{2}n_P = 0,05(mol)\\ m_{P_2O_5} = 0,05.142 = 7,1(gam)\\ b) n_{O_2} = \dfrac{5,6}{22,4} = 0,25(mol)\\ \dfrac{n_P}{4} = 0,025<\dfrac{n_{O_2}}{5} = 0,05 \to O_2\ dư\\ n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,125(mol) \Rightarrow m_{O_2\ dư} = (0,25 - 0,125).32 = 4(gam)\)
a, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
b, \(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{4}< \dfrac{0,4}{5}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\Rightarrow n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(\Rightarrow m_{O_2\left(dư\right)}=0,15.32=4,8\left(g\right)\)
c, Theo PT: \(n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
d, \(m_{P_2O_5}=14,2.80\%=11,36\left(g\right)\)
a. \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH : 2Mg + O2 -> 2MgO
0,2 0,1 0,2
Xét tỉ lệ : \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) => Mg đủ , O2 dư
\(m_{O_2\left(dư\right)}=\left(0,3-0,1\right).32=6,4\left(g\right)\)
b) \(m_{MgO}=0,2.40=8\left(g\right)\)
nP = 6.2/31 = 0.2 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
4P + 5O2 -to-> 2P2O5
0.2___0.25_____0.1
mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g)
mP2O5 = 0.1*142 = 14.2 (g)
Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)
PTHH:
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
ta có:
\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)
=> \(O_2\) dư
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 ----------->2
0.2---------->0.1=nP2O5
=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)
a)
\(n_P = \dfrac{6,2}{31} = 0,2(mol) ; n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\)
Ta thấy :
\(\dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\) nên O2 dư.
\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\)
b)
\(n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)$\\ m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right);n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\\ Vì:\dfrac{0,4}{4}>\dfrac{0,2}{5}\Rightarrow P.dư\\ n_{P\left(dư\right)}=0,4-\dfrac{5}{4}.0,2=0,15\left(mol\right)\\ m_{P\left(Dư\right)}=0,15.31=4,65\left(g\right)\)
PTHH: \(4P+5O_2\xrightarrow[]{t^o}2P_2O_5\)
\(n_P=\dfrac{12,4}{31}=0,4\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Ta có: \(\dfrac{n_P}{4}=\dfrac{0,4}{4}\)
\(\dfrac{n_{O_2}}{5}=\dfrac{0,2}{5}\)
\(\Rightarrow\dfrac{n_P}{4}>\dfrac{n_{O_2}}{5}\)
Vậy phốt pho dư
\(n_{P\text{Pứ}}=\dfrac{0,4.4}{5}=0,32\left(mol\right)\)
\(n_{Pdư}=n_P-n_{PPứ}=0,4-0,32=0,08\left(mol\right)\)
Khối lượng phốt pho dư:
\(m_{Pdư}=n_{Pdư}.M_P=0,08.31=2,48g\)
nP=\(\dfrac{62}{31}\)=0,2(mol)
nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)
PTHH:4P+5O2to→2P2O5
tpứ: 0,2 0,35
pứ: 0,2 0,25 0,1
spứ: 0 0,1 0,1
a)chất còn dư là oxi
mO2dư=0,1.32=3,2(g)
b)mP2O5=n.M=0,1.142=14,2(g)
\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)
PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,25}{1}\), ta được O2 dư.
Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{Mg}=0,1\left(mol\right)\)
\(\Rightarrow n_{O_2\left(dư\right)}=0,25-0,1=0,15\left(mol\right)\)
Bạn tham khảo nhé!
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
Ta có: \(\left\{{}\begin{matrix}n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,25}{1}\) \(\Rightarrow\) Magie p/ứ hết, Oxi còn dư
\(\Rightarrow n_{O_2\left(dư\right)}=0,25-0,1=0,15\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{24,79}=\dfrac{5,6}{24,79}\approx0,23\left(mol\right)\\ n_P=\dfrac{m}{M}=\dfrac{3,1}{31}=0,1\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 5 2
0,1 0,125 0,05
a. Tỉ lệ: \(\dfrac{0,1}{4}< \dfrac{0,12}{5}\Rightarrow O_2\) dư và dư \(0,025-0,024=0,001\left(mol\right)\\ m_{O_2}=n.M=0,001.\left(16.2\right)=0,032\left(g\right)\)
b. \(m_{P_2O_5}=n.M=0,05.\left(31.2+16.5\right)=7,1\left(g\right).\)