Cho 20 lit hỗn hợp khí methane và ethylen đi qua bình đựng dd brom 0,2 M thu được
37,6 gam dibromoethane
a. Viết PTHH?
b. Tính thể tích mỗi khí trong hỗn hợp?
c. Tính thành phần trăm theo thể tích mỗi khí trong hỗn hợp?
d. Tính thể tích dd brom cần dùng? Br = 80, C=12, H=1.
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a) \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,2<---0,2<------0,2
b) \(\left\{{}\begin{matrix}V_{C_2H_4}=0,2.24,79=4,958\left(l\right)\\V_{CH_4}=20-4,958=15,042\left(l\right)\end{matrix}\right.\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,958}{20}.100\%=24,79\%\\\%V_{CH_4}=100\%-24,79\%=75,21\%\end{matrix}\right.\)
d) \(V_{\text{dd}Br_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
\(n_{C_2H_4}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-4,48=15,52\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,48}{20}.100\%=22,4\%\\\%V_{CH_4}=77,6\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{1,88}{188}=0,01\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow V_{C_2H_4}=0,01.22,4=0,224\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-0,224=19,776\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,224}{20}.100\%=1,12\%\\\%V_{CH_4}=98,88\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow C_{M_{Br_2}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\)
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<--0,05
=> \(V_{C_2H_4}=0,05.22,4=1,12\left(l\right)\)
=> \(V_{CH_4}=4,48-1,12=3,36\left(l\right)\)
b) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{1,12}{4,48}.100\%=25\%\\\%V_{CH_4}=\dfrac{3,36}{4,48}.100\%=75\%\end{matrix}\right.\)
a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
a) \(n_{CH_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
=> \(\%V_{CH_4}=\dfrac{3,36}{11,2}.100\%=30\%\)
=> \(\%V_{C_2H_4}=100\%-30\%=70\%\)
b) \(n_{C_2H_4}=\dfrac{11,2.70\%}{22,4}=0,35\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,15-->0,3
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,35-->1,05
=> nO2 = 0,3 + 1,05 = 1,35 (mol)
=> VO2 = 1,35.22,4 = 30,24 (l)