cho 100ml dd KOH 1M phản ứng với 200ml dd H2SO4 nồng độ 2M a) hỏi sau phản ứng chất nào dư, dư bao nhiêu b) tính nồng độ mol của dd sau phản ứng
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Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,1}{2}\), ta được Fe dư.
a, Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\)
⇒ VH2 = 0,05.22,4 = 1,12 (l)
b, Sau pư, Fe dư.
Theo PT: \(n_{Fe\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\Rightarrow n_{Fe\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)
⇒ mFe (dư) = 0,05.56 = 2,8 (g)
c, Theo PT: nFeCl2 = nFe (pư) = 0,05 (mol)
\(\Rightarrow C_{M_{FeCl_2}}=\dfrac{0,05}{0,1}=0,5M\)
Bạn tham khảo nhé!
\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)
\(n_{HCl}=0.1\cdot1=0.1\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(\dfrac{n_{Fe}}{1}=0.1>\dfrac{n_{HCl}}{2}=\dfrac{0.1}{2}=0.05\)
\(\Rightarrow Fedư\)
\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)
\(m_{Fe\left(dư\right)}=\left(0.1-0.05\right)\cdot56=2.8\left(g\right)\)
\(C_{M_{FeCl_2}}=\dfrac{0.05}{0.1}=0.5\left(M\right)\)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(n_{KOH}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{K_2SO_4}=0,05\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\C_{M_{K_2SO_4}}=\dfrac{0,05}{0,2+0,1}\approx0,17\left(M\right)\end{matrix}\right.\)
Bài 1 :
200ml = 0,2l
100ml = 0,1l
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\)
a) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,1 0,05 0,05
b) \(n_{H2SO4}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(C_{M_{ddH2SO4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
c) \(n_{K2SO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{ddspu}=0,2+0,1=0,3\left(l\right)\)
\(C_{M_{K2SO4}}=\dfrac{0,05}{0,3}=\dfrac{1}{6}\left(M\right)\)
Chúc bạn học tốt
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
a, Ta có: \(n_{KOH}=0,15.2=0,3\left(mol\right)\)
PT: \(KOH+HCl\rightarrow KCl+H_2O\)
Theo PT: \(n_{HCl\left(pư\right)}=n_{KOH}=0,3\left(mol\right)\)
Mà: HCl dư 15%
\(\Rightarrow n_{HCl}=0,3+0,3.15\%=0,345\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,345}{1,5}=0,23\left(l\right)\)
b, Theo PT: \(n_{KCl}=n_{KOH}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{KCl}}=\dfrac{0,3}{0,15+0,23}\approx0,789\left(M\right)\)
\(C_{M_{HCl\left(dư\right)}}=\dfrac{0,3.15\%}{0,15+0,23}\approx0,118\left(M\right)\)
PT: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
a, Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\). ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
b, Ta có: \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
c, \(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Bạn tham khảo nhé!
\(n_{KOH}=0,2.0,2=0,04(mol); n_{H_3PO_4}=0,15.0,15=0,0225(mol)\\ \Rightarrow \dfrac{n_{KOH}}{n_{H_3PO_4}}=\dfrac{0,04}{0,0225} \Rightarrow 1<\dfrac{n_{KOH}}{n_{H_3PO_4}}<2\)
\(\Rightarrow \) Tạo 2 muối \(K_2HPO_4,KH_2PO_4\)
Đặt \(\begin{cases} n_{KH_2PO_4}=x(mol)\\ n_{K_2HPO_4}=y(mol) \end{cases}\)
Bảo toàn K: \(x+2y=0,04(1)\)
Bảo toàn P: \(x+y=0,0225(2)\)
\((1)(2)\Rightarrow \begin{cases} x=0,005(mol)\\ y=0,0175(mol) \end{cases}\\ \Rightarrow \begin{cases} C_{M_{KH_2PO_4}}=\dfrac{0,005}{0,2+0,15}\approx 0,014M\\ C_{M_{K_2HPO_4}}=\dfrac{0,0175}{0,2+0,15}=0,05M \end{cases}\)