Cho 150g dung dịch H2SO4 9,8% tác dụng vừa đủ với dung dịch Na2CO3 10,6%. Tính khối lượng dung dịch Na2CO3 đã dùng và tính nồng độ % của dung dịch muối sau phản ứng
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\(m_{H_2SO_4}=150.9,8\%=14,7\left(g\right)\\ n_{H_2SO_4}=\dfrac{14,7}{98}=0,3\left(mol\right)\\ PTHH:H_2SO_4+Na_2CO_3\rightarrow Na_2SO_4+CO_2\uparrow+H_2O\\ Mol:0,3\rightarrow0,3\rightarrow0,3\rightarrow0,3\)
\(m_{Na_2CO_3}=0,3.106=31,8\left(g\right)\\ m_{ddNa_2CO_3}=\dfrac{31,8}{10,6\%}=300\left(g\right)\\ m_{Na_2SO_4}=0,3.142=42,6\left(g\right)\\ m_{CO_2}=0,3.44=13,2\left(g\right)\\ m_{dd}=150+300-13,2=436,8\left(g\right)\\ C\%_{Na_2SO_4}=\dfrac{42,6}{436,8}=9,75\%\)
mH2SO4 =mdd H2SO4.C% : 100% = 400.9,8% :100% = 39,2 (g)
=> nH2SO4 = mH2SO4 : MH2SO4 = 39,2: 98 = 0,4 (mol)
PTHH: H2SO4 + Na2CO3 ---> Na2SO4 + CO2 + H2O
0,4 ---->0,4 -----------> 0,4 -------> 0,4 (mol)
a) Theo PTHH: nNa2CO3 = nH2SO4 = 0,4 (mol)
=> mNa2CO3 = nNa2CO3. MNa2CO3 = 0,4.106 = 42,4 (g)
=> mdd Na2CO3 = mNa2CO3. 100% : C% = 42,4.100% : 10% = 424 (g)
b) Theo PTHH: nCO2 = nH2SO4 = 0,4 (mol)
=> VCO2(đktc) = 0,4.22,4 = 8,96 (lít)
c) Theo PTHH: nNa2SO4 = nH2SO4 = 0,4 (mol)
=> mNa2SO4 = nNa2SO4. MNa2SO4 = 0,4.142 = 56,8 (g)
mdd A = mdd H2SO4 + mdd Na2CO3 = 400 + 424 = 824 (g)
dd A chứa Na2SO4
=> C% Na2SO4 = (mNa2SO4 : mddA).100% = (56,8 : 824).100% = 6,89%
\(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+CO_2+H_2O\)
\(0.5..............0.5...............0.5\)
\(m_{Na_2CO_3}=0.5\cdot106=53\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.5}{0.25}=2\left(M\right)\)
a)
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1--------->0,2------------->0,2------------>0,1
=> mCH3COOH = 0,2.60 = 12 (g)
\(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
b) \(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{0,2.80}{100}=0,16\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
0,16------------------------------------->0,16
=> \(m_{CH_3COOC_2H_5}=0,16.88=14,08\left(g\right)\)
\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
0,6 0,3 0,6 0,3
=> VCO2 = 0,3.22,4 = 6,72 (l)
\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)
=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)
mCO2 = 0,3.44 = 13,2 (g)
\(m_{dd}=150+150-13,2=286,8\left(g\right)\)
\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
Bài 10:
PTHH: \(Na_2CO_3+BaCl_2\rightarrow2NaCl+BaCO_3\downarrow\)
a) Ta có: \(n_{Na_2CO_3}=\dfrac{200\cdot10,6\%}{106}=0,2\left(mol\right)=n_{BaCO_3}\)
\(\Rightarrow m_{BaCO_3}=0,2\cdot197=39,4\left(g\right)\)
b) Theo PTHH: \(n_{BaCl_2}=n_{BaCO_3}=0,2mol\)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2\cdot208}{120}\cdot100\%\approx34,67\%\)
c) Theo PTHH: \(n_{NaCl}=2n_{BaCl_2}=0,4mol\) \(\Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
Mặt khác: \(m_{dd}=m_{ddNa_2CO_3}+m_{ddBaCl_2}-m_{BaCO_3}=280,6\left(g\right)\)
\(\Rightarrow C\%_{NaCl}=\dfrac{23,4}{280,6}\cdot100\%\approx8,34\%\)
a, \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{CO_2}=0,08\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,08}{0,2}=0,4\left(M\right)\)
c, \(n_{Na_2CO_3}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na_2CO_3}=\dfrac{0,04.106}{10}.100\%=42,4\%\\\%m_{NaCl}=57,6\%\end{matrix}\right.\)
\(n_{H_2SO_4}=\dfrac{150.9,8\%}{98}=0,15\left(mol\right)\\ H_2SO_4+Na_2CO_3\rightarrow Na_2SO_4+H_2O+CO_2\\ n_{Na_2CO_3}=n_{H_2SO_4}=0,15\left(mol\right)\\ \Rightarrow m_{ddNa_2CO_3}=\dfrac{0,15.106}{10,6\%}=150\left(g\right)\\ n_{CO_2}=n_{H_2SO_4}=0,15\left(mol\right)\\ m_{ddsaupu}=150+150-0,15.44=293,4\left(g\right)\\ n_{Na_2SO_4}=n_{H_2SO_4}=0,15\left(mol\right)\\ C\%_{Na_2SO_4}=\dfrac{0,15.142}{293,4}.100=7,26\%\)
chị ơi cho em hỏi tại sao lại 150* 9,8% lại chia cho 98 ạ