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a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
Fe+2HCl->FeCl2+H2
x-------------------------x mol
Zn+2HCl->ZnCl2+H2
y-------------------------y mol
=>Ta có hệ :\(\left\{{}\begin{matrix}56x+65y=14,9\\x+y=0,25\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\)
=>%m Fe=\(\dfrac{0,15.56}{14,9}.100=56,375\%\)
=>VHCl=\(\dfrac{0,15.2+0,1.2}{2}=0,25l=250ml\)
`a)`
`Zn+2HCl->ZnCl_2+H_2`
`ZnO+2HCl->ZnCl_2+H_2O`
`b)`
Theo PT: `n_{Zn}=n_{H_2}={2,24}/{22,4}=0,1(mol)`
`->m_{Zn}=0,1.65=6,5(g)`
`->m_{ZnO}=14,6-6,5=8,1(g)`
Theo gt ta có: $n_{Zn}=0,06(mol)$
$Zn+2HCl\rightarrow ZnCl_2+H_2$
a, Ta có: $n_{HCl}=0,12(mol)\Rightarrow m_{ddHCl}=30(g)$
b, Ta có: $n_{H_2}=0,06(mol)\Rightarrow V_{H_2}=1,344(l)$
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a. PTHH: \(Mg+2HCl--->MgCl_2+H_2\)
Theo PT: \(n_{Mg}=n_{H_2}=0,2\left(mol\right)\)
=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)
Theo PT: \(n_{HCl}=2.n_{Mg}=2.0,2=0,4\left(mol\right)\)
=> \(m_{HCl}=0,4.36.5=14,6\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{14,6}{200}.100\%=7,3\%\)
b. Ta có: \(m_{dd_{MgCl_2}}=4,8+200=204,8\left(g\right)\)
Theo PT: \(n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\)
=> \(m_{MgCl_2}=0,2.95=19\left(g\right)\)
=> \(C_{\%_{MgCl_2}}=\dfrac{19}{204,8}.100\%=9,28\%\)
a) Gọi số mol Zn, Fe là a, b (mol)
=> 65a + 56b = 8,56 (1)
\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
a--->2a-------->a----->a
Fe + 2HCl --> FeCl2 + H2
b----->2b------->b------>b
=> a + b = 0,14 (2)
(1)(2) => a = 0,08; b = 0,06
=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)
b)
nKOH = 0,2.0,1 = 0,02 (mol)
PTHH: KOH + HCl --> KCl + H2O
0,02-->0,02
=> nHCl = 0,02 + 2a + 2b = 0,3 (mol)
=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)
c) m = 0,08.136 + 0,06.127 = 18,5(g)
1) \(n_{HCl}=\dfrac{80.14,6\%}{36,5}=0,32\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,16<-0,32--->0,16--->0,16
a = 0,16.65 = 10,4 (g)
2) V = 0,16.22,4 = 3,584 (l)
3) mdd sau pư = 10,4 + 80 - 0,16.2 = 90,08 (g)
\(C\%_{ZnCl_2}=\dfrac{0,16.136}{90,08}.100\%=24,156\%\)