nhiệt phân hoàn toàn m gam kali clorat KCIO3 thu được kali clorua KCI và khí oxi . Xác định giá trị của m khi có 6,72 lít O2 thoát ra (đktc)
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\(n_{Fe}=\dfrac{16,8}{56}=0,3(mol)\\ a,2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\\ 3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2(mol)\\ \Rightarrow V_{O_2}=0,2.22,4=4,48(l)\\ n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{15}(mol)\\ \Rightarrow m_{KClO_3}=\dfrac{2}{15}.122,5\approx 16,33(g)\)
a) \(2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\)
b)
\(n_{KClO_3} = \dfrac{36,75}{122,5} = 0,3(mol)\)
Theo PTHH :
\(n_{KCl} = n_{KClO_3} = 0,3(mol)\\ \Rightarrow m_{KCl} = 0,3.74,5 = 22,35(gam)\\ \Rightarrow m_{O_2} = m_{KClO_3} - m_{KCl} = 14,4(gam)\)
c)
Bảo toàn khối lượng :
\(m_{O_2} = 25 - 15,4 = 9,6(gam)\\ \Rightarrow n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{KClO_3} = 0,2.122,5 = 24,5(gam)\\ \%m_{tạp\ chất}= \dfrac{25-24,5}{25}.100\% = 2\%\)
\(a.\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(b.\)
\(n_{KClO_3}=\dfrac{36.75}{122.5}=0.3\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}\cdot0.3=0.45\left(mol\right)\)
\(m_{O_2}=0.45\cdot32=14.4\left(g\right)\)
\(m_{KCl}=0.3\cdot74.5=22.35\left(g\right)\)
\(c.\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(a.............a\)
\(m_{Cr}=m_{KCl}+m_{tc}=25-122.5a+74.5a=15.4\left(g\right)\)
\(\Rightarrow a=0.2\)
\(m_{O_2}=\dfrac{3}{2}\cdot0.2\cdot32=9.6\left(g\right)\)
\(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)
\(m_{tc}=25-24.5=0.5\left(g\right)\)
\(\%m_{Tc}=\dfrac{0.5}{25}\cdot100\%-2\%\)
2KClO3-to\xt->2KCl+3O2
0,1------------------0,1
n KClO3=\(\dfrac{12,25}{122,5}\)=0,1 mol
=>m KCl=0,1.74,5=7,45g
H=\(\dfrac{6,8}{7,45}.100\)=91,275%
b)
2KClO3-to\xt->2KCl+3O2
0,2-------------------------0,3 mol
n O2=\(\dfrac{6,72}{22,4}\)=0,3 mol
H=85%
=>m KClO3=0,2.122,5.\(\dfrac{100}{85}\)=28,82g
c)
2KClO3-to\xt->2KCl+3O2
0,2------------------------0,3
n KClO3=\(\dfrac{24,5}{122,5}\)=0,2 mol
H=80%
=>m O2=0,3.32.\(\dfrac{80}{100}\)=10,4g
a) 2KClO3 --to--> 2KCl + 3O2
b) \(n_{KClO_3}=\dfrac{36,75}{122,5}=0,3\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,3----------------->0,45
=> V = 0,45.22,4 = 10,08 (l)
nKClO3 = 36,75 : 122,5 = 0,3 (mol)
pthh : 2KClO3 -t--> 2KCl + 3O2
0,3----------------------->0,45 (mol)
=> V= VO2 = 0,45 . 22,4 = 10,08 (L)
a,b,
\(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\)
PTHH: 2KClO3 --to, MnO2--> 2KCl + 3O2
0,1-------------------->0,1------->0,15
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=0,15.22,4=3,36\left(l\right)\\m_{KCl}=74,5.0,1=7,45\left(g\right)\end{matrix}\right.\)
c, PTHH: 3Fe + 2O2 --to--> Fe3O4
0,225<-0,15------->0,075
=> mFe3O4 = 0,075.232 = 17,4 (g)
a)PTHH:2KClO\(_3\)➞\(^{t^o}\)2KCl+3O\(_2\)
b) n\(_{KClO_3}\)=\(\dfrac{m_{KClO_3}}{M_{KClO_3}}\)=\(\dfrac{12,15}{122,5}\)\(\approx\)0,1(m)
PTHH : 2KClO\(_3\) ➞\(^{t^o}\) 2KCl + 3O\(_2\)
tỉ lệ : 2 2 3
số mol : 0,1 0,1 0,15
V\(_{O_2}\)=n\(_{O_2}\).22,4=0,15.22,4=3,36(l)
c)PTHH : 2Zn + O\(_2\) -> 2ZnO
tỉ lệ : 2 1 2
số mol :0,3 0,15 0,3
m\(_{Zn}\)=n\(_{Zn}\).M\(_{Zn}\)=0,3.65=19,5(g)
\(a,2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2\\ n_{KMnO_4}=\dfrac{395}{158}=2,5(mol)\\ \Rightarrow n_{O_2}=1,25(mol)\\ \Rightarrow V_{O_2}=1,25.22,4=28(l)\\ \Rightarrow V_{O_2(tt)}=28.85\%=23,8(l)\)
\(b,n_{O_2}=\dfrac{67,2}{22,4}=3(mol)\\ 2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2\\ \Rightarrow n_{KMnO_4}=6(mol)\\ \Rightarrow m_{KMnO_4}=6.158=948(g)\\ \Rightarrow m_{KMnO_4(tt)}=\dfrac{948}{80\%}=1185(g)\)
a.\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{12,25}{122,5}=0,1mol\)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)
2 2 3 ( mol )
0,1 0,15
\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)
b.\(V_{kk}=V_{O_2}.5=3,36.5=16,8l\)
c.\(n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{28}{56}=0,5mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
3 2 1 ( mol )
0,5 > 0,15 ( mol )
0,225 0,15 ( mol )
\(m_{Fe\left(du\right)}=n_{Fe\left(du\right)}.M_{Fe}=\left(0,5-0,225\right).56=15,4g\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{67,2}{22,4}=3\left(mol\right)\\ Theo.PTHH:n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.3=2\left(mol\right)\\ m_{KClO_3}=n.M=2.122,5=245\left(g\right)\)