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\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right);n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,25}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{Fe\left(p.ứ\right)}=n_{H_2SO_4}=0,25\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,4-0,25=0,15\left(g\right)\\ m_{Fe\left(dư\right)}=0,14.56=8,4\left(g\right)\)
a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\) => Zn hết, HCl dư
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2--->0,4-------------->0,2
=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b) \(n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)
=> \(m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)
nZn = 19.5/65 = 0.3 (mol)
Zn + H2SO4 => ZnSO4 + H2
0.3........................0.3.........0.3
VH2 = 0.3*22.4 = 6.72 (l)
mZnSO4 = 0.3*161 = 48.3 (g)
nCuO = 16/80 = 0.2 (mol)
CuO + H2 -to-> Cu + H2O
0.2........0.2
=> H2 dư
mH2 (dư) = ( 0.3 - 0.2 ) * 2 = 0.2 (g)
nZn=0,3(mol)
a) PTHH: Zn + H2SO4 -> ZnSO4+ H2
0,3___________________0,3____0,3(mol)
mZnSO4=161.0,3=48,3(g)
b) V(H2,đktc)=0,3.22,4=6,72(l)
c) nCuO=16/80=0,2(mol)
PTHH: CuO + H2 -to-> Cu + H2O
vì: 0,3/1 > 0,2/1
=> H2 dư, CuO hết, tính theo nCuO
=> n(H2,dư)=0,3-0,2=0,1(mol)
=> mH2(dư)=0,1.2=0,2(g)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,5 0 0
0,2 0,4 0,2 0,2
0 0,1 0,2 0,2
Sau phản ứng, axit HCl còn dư và dư \(m=0,1\cdot36,5=3,65g\)
\(m_{ZnCl_2}=0,2\cdot136=27,2g\)
\(V_{H_2}=0,2\cdot22,4=4,48l\)
nFe=11,2/56=0,2 mol
nH2SO4=24,5/98=0,25
PTPƯ: Fe + H2SO4 ---> FeSO4 + H2
0,2 mol ----> 0,2 mol --------------------> 0,2 mol
Ta có Fe:H2SO4=0,2/1<0,25/1 (nên H2SO4 dư)
a, mH2SO4=(0,25-0,2).98=4,9 g
b, VH2=0,2.22,4=4,48 l
PTHH: \(Fe+H_2SO_{4\left(l\right)}\rightarrow FeSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Sắt còn dư, Axit p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,25\left(mol\right)\\n_{Fe\left(dư\right)}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\\m_{Fe\left(dư\right)}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)
a) \(Pt:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)
\(n_{H_2SO_4}=\dfrac{24,5}{98}=0,25mol\)
Lập tỉ lệ
\(n_{Fe}:n_{H_2SO_4}=\dfrac{0,4}{1}:\dfrac{0,25}{1}=0,4:0,25\)
Do 0,4>0,25
=> Fe dư
Theo pt: \(n_{H_2}=n_{H_2SO_4}=0,25mol\)
=> \(V_{H_2}=0,25.22,4=5,6lít\)
b) Fe là chất dư sau phản ứng
\(n_{Fe}dư=0,4-0,25=0,15mol\)
\(m_{Fe}dư=0,15.56=8,4g\)
\(a) Fe + H_2SO_4 \to FeSO_4 + H_2\\ n_{Fe} = \dfrac{22,4}{56} = 0,4 > n_{H_2SO_4} = \dfrac{24,5}{98} = 0,25(mol) \to Fe\ dư\\ n_{H_2} = n_{H_2SO_4} = 0,25(mol)\\ V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) n_{Fe\ pư} = n_{H_2SO_4} = 0,25(mol)\\ \Rightarrow m_{Fe\ dư} = 22,4 - 0,25.56 = 8,4(gam)\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right);n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,6}{2}\Rightarrow Zn.dư\\ n_{H_2}=n_{Zn\left(p.ứ\right)}=\dfrac{0,6}{2}=0,3\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,n_{Zn\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{Zn\left(dư\right)}=0,1.65=6,5\left(g\right)\)
`n_(Zn)=m/M=(26)/65=0,4(mol)`
`n_(HCl)=m/M=(21,9)/36,5=0,6(mol)`
`PTHH:Zn+2HCl->ZnCl_2 +H_2`
tỉ lệ: 1 ; 2 : 1 : 1
n(mol) 0,3<----0,6---->0,3----->0,3
\(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\left(\dfrac{0,4}{1}>\dfrac{0,6}{2}\right)\)
`=>` `Zn` dư, `HCl` hết, tính theo `HCl`
`V_(H_2)=n*22,4=0,3*22,4=6,72(l)`
`n_(Zn(dư))=0,4-0,3=0,1(mol)`
`m_(Zn(dư))=n*M=0,1*65=6,5(g)`
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) \(\Rightarrow\) Zn p/ứ hết, H2SO4 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4\left(dư\right)}=0,1\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2SO_4}=0,1\cdot98=9,8\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Thanks