Phân hủy hoàn toàn 43,4g HgO ở nhiệt đọ cao thu được Hg và O2. Tính khối lượng Hg thu được.
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2HgO -t--> 2Hg + O2
0,15-------------->0,75 (mol)
=> mO2 = 0,75 . 32 = 24 (g)
nCaCO3 = \(\dfrac{15}{100}=0,15\left(mol\right)\)
PTHH: CaCO3 -> CaO + CO2
PT: 1 1 1 (mol)
ĐB: 0,15 0,15 0,15 (mol)
mCaO = 0,15.56 = 8,4 (g)
VCO2 = 0,15.22,4 = 3,36(l)
nHgO=2,17/217=0,01(mol)
nO2=0,112/22,4=0,005(mol)
PTHH: 2 Hg + O2 -to-> 2 HgO
Ta có: 0,01/2 = 0,005
=>P.ứ xảy ra hết.
=> nHg=nHgO=0,01(mol)
=>mHg=0,01.201=2,01(g)
2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
a)
\(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\) (1)
\(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\) (2)
\(n_{KCl}=\dfrac{0,894}{74,5}=0,012\left(mol\right);m_B=\dfrac{0,894}{8,132\%}=11\left(g\right)\)
Gọi \(n_{O_2\left(sinh.ra\right)}=a\left(mol\right)\Rightarrow n_{kk}=3a\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{N_2}=3a.80\%=2,4a\left(mol\right)\\n_{O_2}=a+\left(3a-2,4a\right)=1,6a\left(mol\right)\end{matrix}\right.\)
\(n_C=\dfrac{0,528}{12}=0,044\left(mol\right)\)
\(C+O_2\xrightarrow[]{t^o}CO_2\) (3)
Vì hỗn hợp D gồm 3 khí và O2 chiếm 17,083%
\(\Rightarrow D:CO_2,O_{2\left(d\text{ư}\right)},N_2\)
BTNT C: \(n_{CO_2}=n_C=0,044\left(mol\right)\)
BTNT O: \(n_{O_2\left(d\text{ư}\right)}=n_{O_2\left(b\text{đ}\right)}-n_{CO_2}=1,6a-0,044\left(mol\right)\)
\(\Rightarrow\%V_{O_2}=\%n_{O_2}=\dfrac{1,6a-0,044}{1,6a-0,044+0,044+2,4a}.100\%=17,083\%\)
\(\Leftrightarrow a=0,048\left(mol\right)\left(TM\right)\)
ĐLBTKL: \(m_A=m_B+m_{O_2}=11+0,048.32=12,536\left(g\right)\)
Theo PT (2): \(n_{KClO_3}=n_{KCl}=0,012\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{KClO_3}=\dfrac{0,012.122,5}{12,536}.100\%=11,63\%\\\%m_{KMnO_4}=100\%-11,63\%=88,37\%\end{matrix}\right.\)
b) Theo PT (2): \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4\left(p\text{ư}\right)}+\dfrac{3}{2}n_{KClO_3}\)
\(\Rightarrow n_{KMnO_4\left(p\text{ư}\right)}=2.\left(0,048-\dfrac{3}{2}.0,012\right)=0,06\left(mol\right)\)
\(n_{KMnO_4\left(b\text{đ}\right)}=\dfrac{12,536-0,012.122,5}{158}=0,07\left(mol\right)\)
\(\Rightarrow n_{KMnO_4\left(d\text{ư}\right)}=0,07-0,06=0,01\left(mol\right)\)
\(n_{KCl}=\dfrac{74,5}{74,5}+0,012=1,012\left(mol\right)\)
Theo PT (1): \(n_{K_2MnO_4}=n_{MnO_2}=\dfrac{1}{2}.n_{KMnO_4\left(p\text{ư}\right)}=0,03\left(mol\right)\)
PTHH:
\(2KMnO_4+10KCl+8H_2SO_4\rightarrow6K_2SO_4+2MnSO_4+5Cl_2+8H_2O\) (4)
\(K_2MnO_4+4KCl+4H_2SO_4\rightarrow3K_2SO_4+MnSO_4+2Cl_2+4H_2O\) (5)
\(MnO_2+2KCl+2H_2SO_4\rightarrow MnSO_4+K_2SO_4+Cl_2+2H_2O\) (6)
\(2KCl+H_2SO_4\xrightarrow[]{t^o}K_2SO_4+2HCl\) (7)
Theo PT (4), (5), (6): \(n_{KCl\left(p\text{ư}\right)}=5n_{KMnO_4\left(d\text{ư}\right)}+4n_{K_2MnO_4}+2n_{MnO_2}=0,23\left(mol\right)< 1,012\left(mol\right)=n_{KCl\left(b\text{đ}\right)}\)
`=> KCl` dư
Theo PT (4), (5), (6): \(n_{Cl_2}=\dfrac{1}{2}.n_{KCl\left(p\text{ư}\right)}=0,115\left(mol\right)\)
\(\Rightarrow V_{kh\text{í}}=V_{Cl_2}=0,115.22,4=2,576\left(l\right)\)
Bài 1:
\(PTHH:2HgO\underrightarrow{Phân.hủy}2Hg+O_2\\ á,Theo.PTHH:n_{O_2}=\dfrac{1}{2}.n_{HgO}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\\ V_{O_2\left(đktc\right)}=n.22,4=0,05.22,4=1,12\left(l\right)\)
\(b,n_{HgO}=\dfrac{m}{M}=\dfrac{43,4}{217}=0,2\left(mol\right)\\ Theo.PTHH:n_{Hg}=n_{HgO}=0,2\left(mol\right)\\ m_{Hg}=n.M=0,2.201=40,2\left(g\right)\)
\(c,n_{Hg}=\dfrac{m}{M}=\dfrac{14,07}{201}=0,07\left(mol\right)\\ Theo.PTHH:n_{HgO}=n_{Hg}=0,07\left(mol\right)\\ m_{HgO}=n.M=0,07.217=15,19\left(g\right)\)
Câu 2:
\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Theo.PTHH:n_{Zn}=n_{H_2}=0,3\left(mol\right)\\ m_{Zn}=n.M=0,3.65=19,5\left(g\right)\\ b,Theo.PTHH:n_{HCl}=2.n_{Zn}=2.0,3=0,6\left(mol\right)\\ m_{HCl}=n.M=0,6.36,5=21,9\left(g\right)\)
a, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Ta có: \(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)
Theo PT: \(n_{K_2MnO_4}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{K_2MnO_4}=0,1.197=19,7\left(g\right)\)
b, Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,1.24,79=2,479\left(l\right)\)
c, PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{1}{2}n_{O_2}=0,05\left(mol\right)\\n_{H_2O}=n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow V_{CO_2}=0,05.24,79=1,2395\left(l\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
a) 2HgO → 2Hg +O\(_2\)
b) Theo PT ta có: n\(_{O_2}\)=\(\dfrac{1}{2}\)nHgO=\(\dfrac{1}{2}\).0,1=0,05(mol)⇒m\(_{O_2}\)=0,05.32=1,6(g)
c)nHgO=\(\dfrac{43,4}{217}\)=0,2(mol)
Theo Pt ta có:nHg=nHgO=0,2(mol)⇒mHg=0,2.201=40,2(g)
a, PTHH:2HgO--->2Hg+O2
b, Theo pt: nO2=\(\dfrac{1}{2}.nHgO=\dfrac{1}{2}.0,1=0,05\) mol
=> mO2= 0,05.32= 1,6 (g)
c, nHgO=\(\dfrac{43,4}{217}=0,2\) mol
Theo pt: nHg=nHgO=0,2 mol
=> mHg= 0,2.201= 40,2 (g)
\(n_{HgO}=\dfrac{43,4}{217}=0,2mol\)
2HgO \(\underrightarrow{t^o}\) 2Hg + O2
0,2 0,2 ( mol )
\(m_{Hg}=0,2.201=40,2g\)