Cho 10 gam CACO3 tác dụng với 200ml dd H2SO4 Tính nồng độ mol dd axit phản ứng Tính thể tích khí hiđro (đkc) Tính khối lượng muối tạo thành
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\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
(mol).......0,3........0,6.........0,3.......0,3
a) \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b) \(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c) \(200ml=0,2l\)
\(C_{M_{HCl}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
d) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ban đầu: 0,2......0,3
Phản ứng: 0,2....0,2.....0,2.....0,2
Dư:.....................0,1
Lập tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\left(0,2< 0,3\right)\)
\(\Rightarrow H_2\) dư
a) \(n_{Fe}=\dfrac{1,12}{56}=0,02\left(mol\right)\)
PTHH: Fe + 2HCl -->FeCl2 + H2
_____0,02->0,04--->0,02--->0,02
=> VH2 = 0,02.22,4 = 0,448(l)
b) mFeCl2 = 0,02.127 = 2,54(g)
c) \(C_{M\left(HCl\right)}=\dfrac{0,04}{0,2}=0,2M\)
Fe + 2HCl → FeCl2 + H2
1 2 1 1
0,02 0,04 0,02 0,02
nFe=\(\dfrac{1,12}{56}\)= 0,02(mol)
a). nH2=\(\dfrac{0,02.1}{1}\)= 0,02(mol)
→VH2= n . 22,4 = 0,02 . 22,4 = 0,448(l)
b). nFeCl2= \(\dfrac{0,02.1}{1}\)= 0,02(mol)
→mFeCl2= n . M = 0,02 . 127 = 2,54(g)
c). 200ml = 0,2l
nHCl= \(\dfrac{0,02.2}{1}\)=0,04(mol)
→CM= \(\dfrac{n}{V}\)= \(\dfrac{0,04}{0,2}\)= 0,2M
\(a,n_{HCl}=0,2.0,75=0,15\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15-->0,075-->0,075
\(\rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\\ b,m_{FeCl_2}=0,075.127=9,525\left(g\right)\)
a)
$n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
Theo PTHH:
$n_{H_2SO_4} = n_{H_2} = \dfrac{3}{2}n_{Al} = 0,3(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,3}{2} = 0,15(lít)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,1(mol)$
$C_{M_{Al_2(SO_4)_3}} = \dfrac{0,1}{0,15} = 0,67M$
b)
$V_{H_2} = 0,3.22,4 = 6,72(lít)$
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
_____0,2-->0,6----->0,2---->0,3
=> \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,2}=3M\)
b) VH2 = 0,3.24,79 = 7,437 (l)
c) \(C_{M\left(AlCl_3\right)}=\dfrac{0,2}{0,2}=1M\)
a) \(n_{CO_2}=\dfrac{0,4958}{24,79}=0,02\left(mol\right);n_{HCl}=0,6.1=0,6\left(mol\right)\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
0,02<------0,04<----0,02<-----0,02
\(\Rightarrow n_{HCl\left(p\text{ư}\right)}< n_{HCl\left(b\text{đ}\right)}\left(0,04< 0,6\right)\Rightarrow HCl\) dư, \(CaCO_3\) tan hết
\(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,02.100=2\left(g\right)\\m_{CaSO_4}=5-2=3\left(g\right)\end{matrix}\right.\)
b) dd sau phản ứng có: \(\left\{{}\begin{matrix}n_{HCl\left(d\text{ư}\right)}=0,6-0,04=0,56\left(mol\right)\\n_{CaCl_2}=0,02\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M\left(HCl\left(d\text{ư}\right)\right)}=\dfrac{0,56}{0,6}=\dfrac{14}{15}M\\C_{M\left(CaCl_2\right)}=\dfrac{0,02}{0,6}=\dfrac{1}{30}M\end{matrix}\right.\)
\(n_{CaCO_3}=\dfrac{10}{100}=0.1\left(mol\right)\)
\(CaCO_3+H_2SO_4\rightarrow CaSO_4+CO_2+H_2O\)
\(0.1..........0.1................0.1...........0.1\)
\(C_{M_{H_2SO_4}}=\dfrac{0.1}{0.2}=0.5\left(M\right)\)
\(V_{CO_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{CaSO_4}=0.1\cdot136=13.6\left(g\right)\)