hòa tan 19,5 gam Zn vào dung dịch HCL 20 %
a, viết pthh , tính khối lượng muối thu đc
b, tính nồng độ % muối
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a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a)
Khối lượng của dung dịch:
\(m_{dd}=m_{ct}+m_{dm}=20+180=200\left(g\right)\)
Nồng độ phần trăm của dung dịch:
\(C\%=\dfrac{m_{ct}}{m_{dd}}.100\%=\dfrac{20}{200}.100\%=10\%\)
b) đề sai nha bạn
PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
a_____2a_______a_______a (mol)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b_____6b_______2b_______3b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}40a+102b=18,2\\2a+6b=\dfrac{182,5\cdot20\%}{36,5}=1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgO}=\dfrac{0,2\cdot40}{18,2}\cdot100\%\approx43,96\%\\\%m_{Al_2O_3}=56,04\%\end{matrix}\right.\)
Theo PTHH: \(n_{MgCl_2}=0,2\left(mol\right)=n_{AlCl_3}\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,2\cdot95=19\left(g\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{19}{18,2+182,5}\cdot100\%\approx9,47\%\\C\%_{AlCl_3}=\dfrac{26,7}{182,5+18,2}\cdot100\%\approx13,3\%\end{matrix}\right.\)
a) mHCl=182,5. 20%=36,5(g) -> nHCl=1(mol)
Đặt nMgO=a(mol); nAl2O3=b(mol)
PTHH: MgO +2 HCl -> MgCl2 + H2O
a__________2a______a(mol)
Al2O3 + 6 HCl -> 2 AlCl3 + 3 H2O
b_______6b______2b(mol)
b) Ta có hpt:
\(\left\{{}\begin{matrix}40a+102b=18,2\\2a+6b=1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mMgO=0,2.40=8(g)
=>%mMgO=(8/18,2).100=43,956%
=> %mAl2O3= 56,044%
c) m(muối)= mAlCl3 + mMgCl2= 133,5.2b+ 95.a= 133,5.0,1.2+95.0,2= 45,7(g)
d) mAlCl3= 26,7(g) ; mMgCl2 = 19(g)
mddsau= 18,2+ 182,5= 200,7(g)
=>C%ddAlCl3=(26,7/200,7).100=13,303%
C%ddMgCl2=(19/200,7).100=9,467%
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(a.PTHH:Zn+H_2SO_4--->ZnSO_4+H_2\uparrow\)
b. Theo PT: \(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
\(\Rightarrow m_{dd_{H_2SO_4}}=49\left(g\right)\)
\(n_{Na_2O}=\dfrac{6.2}{62}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{91.25\cdot10\%}{36.5}=0.25\left(mol\right)\)
\(Na_2O+2HCl\rightarrow2NaCl+H_2O\)
\(TC:\dfrac{0.1}{1}< \dfrac{0.25}{2}\Rightarrow HCldư\)
\(m_{NaCl}=0.1\cdot2\cdot58.5=11.7\left(g\right)\)
\(m_{dd}=6.2+91.25=97.45\left(g\right)\)
\(C\%_{NaCl}=\dfrac{11.7}{97.45}\cdot100\%=12\%\)
\(C\%_{HCl\left(dư\right)}=\dfrac{\left(0.25-0.2\right)\cdot36.5}{97.45}\cdot100\%=1.87\%\)
nNa2O=0,1(mol)
PTHH: Na2O + H2O -> 2 NaOH
-> nNaOH=0,2(mol)
nHCl=9,125(mol)->nHCl=0,25(mol)
PTHH: NaOH + HCl -> NaCl + H2O
Vì 0,25/1 > 0,2/1
=> NaOH hết, HCl dư, tính theo nNaOH
-> nNaCl=nHCl(p.ứ)=nNaOH=0,2(mol)
=>mNaCl=58,5.0,2= 11,7(g)
mHCl(dư)=0,05.36,5= 1,825(g)
mddsau=0,2.40+ 91,25= 99,25(g)
=>C%ddHCl(dư)=(1,825/99,25).100=1,839%
C%ddNaCl=(11,7/99,25).100=11,788%
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\(n_{HCl}=1\cdot0,2=0,2\left(mol\right)\\ PTHH:MgO+2HCl\rightarrow MgCl_2+H_2O\\ a,n_{MgO}=\dfrac{1}{2}n_{HCl}=0,1\left(mol\right)\\ \Rightarrow m=m_{MgO}=0,1\cdot40=4\left(g\right)\\ b,n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{MgCl_2}=0,1\cdot95=9,5\left(g\right)\\ c,m_{CT_{HCl}}=0,2\cdot36,5=7,3\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{7,3}{250}\cdot100\%=2,92\%\)
\(n_{H_2O}=n_{MgO}=0,1\left(mol\right)\\ \Rightarrow m_{H_2O}=0,1\cdot18=1,8\left(g\right)\\ \Rightarrow m_{dd_{MgCl_2}}=4+250-1,8=252,2\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{252,2}\cdot100\%\approx3,77\%\)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{ZnCl_2}=0,3\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ZnCl_2}=0,3\cdot136=40,8\left(g\right)\\m_{ddHCl}=\dfrac{0,6\cdot36,5}{20\%}=109,5\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{19,5+109,5-0,6}\cdot100\%\approx37,78\%\)