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a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
a) PTHH: C + O2 -to-> CO2
x_____________x_____x(mol)
S+ O2 -to-> SO2
y__y________y(mol)
b) Ta có:
\(\left\{{}\begin{matrix}12x+32y=5,6\\32x+32y=9,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
mC=0,2.12=2,4(g)
mS=0,1.32=3,2(g)
c)
\(\%mC=\dfrac{2,4}{5,6}.100\approx42,857\%\\ \rightarrow\%mS\approx100\%-42,857\%\approx57,143\%\)
d)
\(\%nCO2=\dfrac{x}{x+y}.100\%=\dfrac{0,2}{0,2+0,1}.100\approx66,667\%\\ \rightarrow\%nSO2=\dfrac{y}{x+y}.100\%=\dfrac{0,1}{0,2+0,1}.100\approx33,333\%\)
a)nO2=m/M=9,6/32=0,3 (mol)
C + O2 ->t° CO2
1:1:1
x/12 :(x/12) :x/12 mol
S + O2->t° SO2
1:1:1
5,6-x/32: (5,6-x/32): 5,6-x/32 mol
gọi x là số gam của cacbon
nC=m/M=x/12(mol)
nS=5,6-x/12 (mol)
b)ta có phương trinh
5,6-x/32+x/12=0,3
<=>3(5,6-x)/96 + 8x/96= 28,8/96
->3(5,6-x)+8x=28,8
<=> 16,8 -3x+8x=28,8
<=>-3x+8x=12
<=>5x=12
<=>x=2,4
-> mC=2,4(g)
mS=5,6-2,4=3,2(g)
c)%mC=2,4/5,6.100%= 42,857%
%mS=100%-42,857%=57,143%
d)%nCO2=0,2/0,3.100%=66,7%
%nSO2=100%-66,7%=33,3%
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
\(n_{H_2SO_4}=5a\left(mol\right),n_{HCl}=3a\left(mol\right)\)
\(m=98\cdot5a+36.5\cdot3a=5.995\left(g\right)\)
\(\Rightarrow a=0.01\)
\(n_{H_2SO_4}=0.05\left(mol\right),n_{HCl}=0.03\left(mol\right)\)
\(b.\)
\(n_{H_2SO_4}=0.025\left(mol\right),n_{HCl}=0.015\left(mol\right)\)
\(n_{CO}=x\left(mol\right),n_{CO_2}=y\left(mol\right)\)
\(n_B=x+y=0.025+0.015=0.04\left(mol\right)\left(1\right)\)
\(m_B=28x+44y=2.16\left(g\right)\left(2\right)\)
\(\left(1\right),\left(2\right):\) Không biết sao tới chổ này số mol âm mất em ơii
Coi \(m_{CH_4} = m_{C_2H_4} = 224(gam)\\ \Rightarrow n_{CH_4} = \dfrac{224}{16} = 14(mol)\\ \Rightarrow n_{C_2H_4} = \dfrac{224}{28} = 8(mol)\)
Vậy :
\(\%n_{CH_4} = \dfrac{14}{14+8}.100\% = 63,64\%\\ \%n_{C_2H_4} = 100\% - 63,64\% = 36,36\%\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(n_{CH_4}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(TC:\)
\(16a=28b\left(2\right)\)
\(\left(1\right),\left(2\right):a=\dfrac{7}{11},b=\dfrac{4}{11}\)
\(\%n_{CH_4}=\dfrac{7}{11}\cdot100\%=63.64\%\)
\(\%n_{C_2H_4}=36.36\%\)
Em xem thử cách làm này nhé !!