hòa tan 28.4g hh na2so3 và k2so3 trong 200g dd hcl sau phản ứng thu đc 4,48l khí và dd a.
tính thành phần % về khối lượng của muối trong hh ban đầu .
tính c% dd hcl
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PTHH: \(K_2O+2HCl\rightarrow2KCl+H_2O\)
\(K_2SO_3+2HCl\rightarrow2KCl+SO_2\uparrow+H_2O\)
a) Ta có: \(\left\{{}\begin{matrix}n_{HCl}=\dfrac{200\cdot14,6\%}{36,5}=0,8\left(mol\right)\\n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_3}=0,3\left(mol\right)\\n_{K_2O}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{K_2O}=\dfrac{0,1\cdot94}{0,1\cdot94+0,3\cdot158}\cdot100\%\approx16,55\%\\\%m_{K_2SO_3}=83,45\%\end{matrix}\right.\)
b) Theo các PTHH: \(n_{KCl}=0,8\left(mol\right)\) \(\Rightarrow m_{KCl}=74,5\cdot0,8=59,6\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{hh}=56,8\left(g\right)\\m_{SO_2}=0,3\cdot64=19,2\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{SO_2}=237,6\left(g\right)\)
\(\Rightarrow C\%_{KCl}=\dfrac{59,6}{237,6}\cdot100\%\approx25,1\%\)
\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)
\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)
\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
Fe + 2HCl --> FeCl2 + H2
b) Gọi số mol Al, Fe lần lượt là a,b
=> 27a + 56b = 13,9
\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
2Al + 6HCl --> 2AlCl3 + 3H2
a----->3a--------->a------->1,5a______(mol)
Fe + 2HCl --> FeCl2 + H2
b------>2b-------->b----->b__________(mol)
=> 1,5a + b = 0,35
=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c) nHCl = 3a + 2b = 0,7 (mol)
=> mHCl = 0,7.36,5 = 25,55(g)
=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)
\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)
\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)
a)Gọi x,y lần lượt là số mol của Al, Fe trong hỗn hợp ban đầu (x,y>0)
Sau phản ứng hỗn hợp muối khan gồm: \(\left\{{}\begin{matrix}AlCl_3:x\left(mol\right)\\FeCl_2:y\left(mol\right)\end{matrix}\right.\)
Ta có hệ phương trình: \(\left\{{}\begin{matrix}27x+56y=13,9\\133,5x+127y=38\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x\approx0,0896\\y\approx0,205\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,0896\cdot27\cdot100\%}{13,9}\approx17,4\%\\\%m_{Fe}=\dfrac{0,205\cdot56\cdot100\%}{13,9}\approx82,6\%\end{matrix}\right.\)
Theo Bảo toàn nguyên tố Cl, H ta có:\(n_{H_2}=\dfrac{n_{HCl}}{2}=\dfrac{3n_{AlCl_3}+2n_{FeCl_2}}{2}\\ =\dfrac{3\cdot0,0896+2\cdot0,205}{2}=0,3394mol\\ \Rightarrow V_{H_2}=0,3394\cdot22,4\approx7,6l\)
Gọi : \(\left\{{}\begin{matrix}n_{Al_2O_3}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)⇒ 102a + 65b = 2,505(1)
\(Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O\\ Zn + 2HCl \to ZnCl_2 + H_2\)
Muối gồm : \(\left\{{}\begin{matrix}AlCl_3:2a\left(mol\right)\\ZnCl_2:b\left(mol\right)\end{matrix}\right.\)⇒ 133,5.2a + 136b = 6,045(2)
Từ (1)(2) suy ra : a = 0,015 ; b = 0,015
Vậy :
\(\%m_{Al_2O_3} = \dfrac{0,015.102}{2,505}.100\% = 61,08\%\\ \%m_{Zn} = 100\% - 61,08\% = 38,92\%\)
Theo PTHH : \(n_{HCl} = 6a + 2b = 0,12(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,12.36,5}{200}.100\% = 2,19\%\)
\(2NaBr+Cl_2\rightarrow2NaCl+Br_2\left(1\right)\\ m_{giảm}=m_{Br_2}-m_{Cl_2}\\ \Leftrightarrow n_{NaCl\left(1\right)}=n_{NaBr\left(1\right)}=\dfrac{13,35}{160-71}=0,15\left(mol\right)\\ \Rightarrow\%m_{NaBr}=\dfrac{103.0,15}{42,6}.100\approx36,268\%\\ \Rightarrow\%m_{NaCl}\approx63,732\%\)
Bổ sung:
\(C\%_{ddNaBr\left(trongA\right)}=\dfrac{0,15.103}{200}.100=7,725\%\\ C\%_{ddNaCl\left(trongA\right)}=\dfrac{42,6-0,15.103}{200}.100=13,575\%\)
a) \(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
Gọi x,y lần lượt là số mol Fe(OH)3 và Cu(OH)2
=> \(\left\{{}\begin{matrix}107x+98y=20,5\\160.\dfrac{x}{2}+80y=16\end{matrix}\right.\)
=> x= 0,1 ; y=0,1
=> \(\%m_{Fe\left(OH\right)_3}=\dfrac{0,1.107}{20,5}.100=52,2\%\)
\(\%m_{Cu\left(OH\right)_2}=47,8\%\)
b) \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
\(Cu\left(OH\right)_2+H_2SO_4\rightarrow CuSO_4+2H_2O\)
\(n_{H_2SO_4}=0,1.\dfrac{3}{2}+0,1=0,25\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
\(m_{ddsaupu}=20,5+122,5=143\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,05.400}{143}.100=13,97\%\)
\(C\%_{CuSO_4}=\dfrac{0,1.160}{143}.100=11,19\%\)
c) \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{Fe_2O_3}=0,05\left(mol\right);n_{CuO}=0,1\left(mol\right)\)
=> \(n_{H_2SO_4}=0,05.3+0,1=0,25\left(mol\right)\)
\(m_{ddH_2SO_4\left(pứ\right)}=\dfrac{0,25.98}{20\%}=122,5\left(g\right)\)
=> \(m_{ddH_2SO_4\left(bđ\right)}=122,5.110\%=134,75\left(g\right)\)
\(PTHH:Na_2SO_3+2HCl\rightarrow2NaCl+H_2O+SO_2\uparrow\\ K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\\ n_{SO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}+n_{K_2SO_3}=0,2\\126n_{Na_2SO_3}+158n_{K_2SO_3}=28,4\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%_{m_{Na_2SO_3}}=\dfrac{0,1\cdot126}{28,4}\cdot100\%\approx44\%\\ \Rightarrow\%_{m_{K_2SO_3}}=100\%-44\%=56\%\)
\(n_{HCl}=0,1\cdot2+0,1\cdot2=0,4\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,4\cdot36,5=14,6\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{14,6}{200}\cdot100\%=7,3\%CC\)