3. a. Tính hóa trị Mn trong M*n_{2} * O_{7} , Fe trong F*e_{2} * O_{3} , b. Lập CTHH : AL & 0 ; S(VI) & O; H & Br
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a. \(PTHH:3H_2+Fe_2O_3\rightarrow2Fe+3H_2O\)
b. \(n_{Fe_2O_3}=\dfrac{m_{Fe_2O_3}}{M_{Fe_2O_3}}=\dfrac{40}{160}=0,25\left(mol\right)\)
- Mol theo PTHH : \(3:1:2:3\)
- Mol theo phản ứng : \(0,75\leftarrow0,25\rightarrow0,5\rightarrow0,75\)
\(\Rightarrow n_{Fe}=0,5\left(mol\right)\)
\(\Rightarrow m_{Fe}=n_{Fe}.M_{Fe}=0,5.56=28\left(g\right)\)
c. Ta có : \(n_{Fe_2O_3}=0,25\left(mol\right);n_{H_2}=0,3\left(mol\right)\)
Do \(0,25< 0,3\) ⇒ H2 dư.
a
\(2Fe+6H_2SO_{4.đặc}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
b
\(2Na+2HCl\rightarrow2NaCl+H_2\)
c
\(8Al+30HNO_3\rightarrow8Al\left(NO_3\right)_3+3NH_4NO_3+9H_2O\)
d
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(Ba\left(OH\right)_2+\left(NH_4\right)_2SO_4\rightarrow BaSO_4+2NH_3+2H_2O\)
e
\(2AlCl_3+3Na_2CO_3+H_2O\rightarrow2Al\left(OH\right)_3+6NaCl+3CO_2\)
f
\(HCl+NaAlO_2+H_2O\rightarrow Al\left(OH\right)_3+NaCl\)
a: \(2Fe+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+3H_2O\)(H2SO4 đặc nóng)
b: \(2Na+2HCl\rightarrow2NaCl+H_2\uparrow\)
c: \(8Al+30HNO_3\rightarrow8Al\left(NO_3\right)_3+3NH_4NO_3+9H_2O\)
d; \(Ba+\left(NH_4\right)_2SO_4\rightarrow BaSO_4\downarrow+2NH_3+H_2O\)
e: \(2AlCl_3+3Na_2CO_3+3H_2O\rightarrow6NaCl+2Al\left(OH\right)_3\downarrow+3CO_2\uparrow\)
f: \(HCl+NaAlO_2+H_2O\rightarrow Al\left(OH\right)_3+NaCl\)
a.b.\(n_{Fe_2O_3}=\dfrac{m_{Fe_2O_3}}{M_{Fe_2O_3}}=\dfrac{16}{160}=0,1mol\)
\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{13,44}{22,4}=0,6mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,1 < 0,6 ( mol )
0,1 0,3 0,2 ( mol )
\(m_{Fe}=n_{Fe}.M_{Fe}=0,2.56=11,2g\)
c.\(n_{H_2}=0,6-0,3=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=n_{CuO}.M_{CuO}=0,3.80=24g\)
a) \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4(l) ---> FeSO4 + H2
0,1<-------------------------------0,1
\(m_{Fe}=0,1.56=5,6\left(g\right)\\ n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH:
2Fe + 6H2SO4(đ,n) ---> Fe2(SO4)3 + 3SO2 + 6H2O
0,1-------------------------------------------->0,15
2Ag + 2H2SO4(đ,n) ---> Ag2SO4 + SO2 + 2H2O
0,2<----------------------------------------0,1
=> mAg = 0,2.108 = 21,6 (g)
=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{5,6+21,6}.100\%=20,44\%\\\%m_{Ag}=100\%-20,44\%=79,56\%\end{matrix}\right.\)
b) nNaOH = 0,25.1,5 = 0,375 (mol)
\(T=\dfrac{0,375}{0,25}=1,5\) => Tạo cả 2 muối
PTHH:
2NaOH + SO2 ---> Na2SO3 + H2O
0,375--->0,1875--->0,1875
Na2SO3 + SO2 + H2O ---> 2NaHSO3
0,0625<---0,0625----------->0,125
=> \(\left\{{}\begin{matrix}C_{M\left(Na_2SO_3\right)}=\dfrac{0,1875-0,0625}{0,25}=0,48M\\C_{M\left(NaHSO_3\right)}=\dfrac{0,125}{0,25}=0,5M\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{RO}=2x\\n_{Fe_2O_3}=x\end{matrix}\right.\)
Theo đề:
\(R.2x+56.2x=31,56\)
\(\Rightarrow2x.R=31,56-112x\)
Mặt khác: \(2x.\left(R+16\right)+160x=36,36\)
\(\Leftrightarrow2xR+32x+160x=36,6\Leftrightarrow31,56-112x+32x+160x=36,36\)
=> x = 0,06
\(\Rightarrow R=\dfrac{31,56-112.0,06}{2.0,06}=207\)
Vậy kim loại R là Pb (chì).
3.a) mk ko hiểu đề
3.b) + Al2O3
+ SO2
+ BrH