Cho 200g dd MgSO4 2,4% tác dụng hoàn toàn với 300g dd NaOH 8%. Tính khối lượng Mg(OH)2 tạo thành
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\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\
V_{H_2}=0,1.22,4=2,24l\\
m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{HCl}=0,4.36,5=14,6g\\
V_{H_2}=0,2.22,4=4,48l\\
m\text{dd}=4,8+200-0,4=204,4g\\
C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)
a)
$Fe + CuSO_4 \to FeSO_4 + Cu$
Theo PTHH : $n_{Cu} = n_{CuSO_4} = 0,3.1 = 0,3(mol)$
$m_{Cu} = 0,3.64 = 19,2(gam)$
b) $n_{FeSO_4} = n_{CuSO_4} = 0,3(mol)$
$\Rightarrow m_{FeSO_4} = 0,3.152 = 45,6(gam)$
c) $FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4$
$n_{Fe(OH)_2} = n_{FeSO_4} = 0,3(mol)$
$m_{Fe(OH)_2} = 0,3.90 = 27(gam)$
\(n_{CO_2}=0,2\left(mol\right);n_{NaOH}=0,3\left(mol\right)\)
Lập T=\(\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,3}{0,2}=1,5\) => Tạo 2 muối
Gọi x, y lần lượt là số mol NaHCO3 và Na2CO3
Bảo toàn nguyên tố C => x+y=0,2
Bảo toàn nguyên tố Na => x+2y=0,3
=> x=0,1 ; y=0,1
=>\(m_{muối}=m_{NaHCO_3}+m_{Na_2CO_3}=0,1.84+0,1.106=19\left(g\right)\)
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(m_{NaOH}=\dfrac{20.60}{100}=12\left(g\right)\Rightarrow n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)
PTHH:CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,3 0,15
Ta có tỉ lệ:\(\dfrac{0,2}{1}>\dfrac{0,3}{2}\)⇒ NaOH pứ hết,CO2 dư
⇒\(m_{Na_2CO_3}=0,15.106=15,9\left(g\right)\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,1 0,1 0,1
\(m_{MgSO_4}=120.0,1=12\left(g\right)\\
n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(LTL:\dfrac{0,6}{1}>\dfrac{0,1}{1}\)
=> CuO dư
\(n_{CuO\left(P\text{Ư}\right)}=n_{H_2}=0,1\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,6-0,1\right).80=40\left(g\right)\)
nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2
0,1 0,1 0,1
mMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2OmMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2O
\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)
\(NaOH+HCl\rightarrow NaCl+H_2O\)
0,4 0,4 0,4 0,4
a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)
b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)
\(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)
\(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)
\(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)
c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)
0,4 0,3 0,3 0,3
\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)
a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,2\cdot95=19\left(g\right)\\C\%_{HCl}=\dfrac{0,4\cdot36,5}{200}\cdot100\%=7,3\%\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{MgO}+m_{ddHCl}=208\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{19}{208}\cdot100\%\approx9,13\%\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{NaOH}=\dfrac{200\cdot4\%}{40}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,2}{2}\) \(\Rightarrow\) NaOH p/ứ hết, MgCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,2\left(mol\right)\\n_{Mg\left(OH\right)_2}=0,1\left(mol\right)=n_{MgCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,2\cdot58,5=11,7\left(g\right)\\m_{MgCl_2\left(dư\right)}=9,5\left(g\right)\\m_{Mg\left(OH\right)_2}=0,1\cdot58=5,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{ddA}+m_{ddNaOH}-m_{Mg\left(OH\right)_2}=402,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{11,7}{402,2}\cdot100\%\approx2,91\%\\C\%_{MgCl_2\left(dư\right)}=\dfrac{9,5}{402,2}\cdot100\%\approx2,36\%\end{matrix}\right.\)
Theo gt ta có: $n_{MgO}=0,2(mol)$
a, $MgO+2HCl\rightarrow MgCl_2+H_2O$
b, Ta có: $n_{HCl}=0,4(mol)\Rightarrow x=7,3$
Bảo toàn khối lượng ta có: $m_{ddA}=208(g)$
$\Rightarrow \%C_{MgCl_2}=9,13\%$
c, Ta có: $n_{NaOH}=0,2(mol)$
$\Rightarrow n_{Mg(OH)_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{ddB}=208+200-0,1.58=402,2(g)$
$\Rightarrow \%C_{MgCl_2}=2,36\%$
\(n_{NaOH}=\dfrac{200.5\%}{100\%.40}=0,25(mol)\\ n_{HCl}=\dfrac{36,5.20\%}{100\%.36,5}=0,2(mol)\\ a,NaOH+HCl\to NaCl+H_2O\)
Vì \(\dfrac{n_{NaOH}}{1}>\dfrac{n_{HCl}}{1}\) nên \(NaOH\) dư
\(b,n_{NaOH(dư)}=0,25-0,2=0,05(mol);n_{NaCl}=0,2(mol)\\ \Rightarrow m_{\text{dd sau p/ứ}}=0,2.58,5+0,05.40=13,7(g)\\ c,m_{NaCl}=0,2.58,5=11,7(g)\\ d,n_{H_2}=0,2(mol)\\ \Rightarrow \begin{cases} C\%_{NaOH}=\dfrac{0,05.40}{36,5+200-0,2.2}.100\%=0,85\%\\ C\%_{NaCl}=\dfrac{11,7}{36,5+200-0,2.2}.100\%=4,96\% \end{cases}\)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,5 0,5
\(m_{CaCl_2}=0.5\cdot111=55.5\left(g\right)\)
m MgSO4=4,8g=>nMgSO4=4,8\120=0,04 mol
mNaOh=24g =>nNaOh=24\40=0,6 mol
2NaOH+MgSO4->Mg(OH)2+Na2SO4
=> lập tỉ lệ :NaOH dư
=>mMg(OH)2=0,04.58=2,32g