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\(n_{Na_2CO_3}=0,1.1=0,1\left(mol\right)\)
a. \(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
0,1 0,1 0,1 0,2
b. \(m_{kt}=m_{BaCO_3}=0,1.197=19,7\left(g\right)\)
c. \(C\%_{Ba\left(OH\right)_2}=\dfrac{0,1.171.100}{200}=8,55\%\)
d. \(BaCO_3+2HCl\rightarrow BaCl_2+H_2O+CO_2\)
0,1 0,2
=> \(a=m_{dd.HCl}=\dfrac{0,2.36,5.100}{30}=\dfrac{73}{3}\left(g\right)\)
a.
\(Na_2CO_3+Ba\left(OH\right)_2\rightarrow BaCO_3+2NaOH\)
b.
\(n_{BaCO_3}=n_{Na_2CO_3}=0,2.1=0,2\left(mol\right)\\ m_{kt}=197.0,2=39,4\left(g\right)\)
c.
\(n_{Ba\left(OH\right)_2}=n_{Na_2CO_3}=0,2\left(mol\right)\\ C\%_{Ba\left(OH\right)_2}=\dfrac{0,2.171.100\%}{200}=17,1\%\)
\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)
\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(a)Ba\left(OH\right)_2+Na_2CO_3\rightarrow2NaOH+BaCO_3\\ n_{Ba\left(OH\right)_2}=0,2.2=0,4mol\\ n_{BaCO_3}=n_{Na_2CO_3}=n_{Ba\left(OH\right)_2}=0,4mol\\ m_{BaCO_3}=0,4.171=68,4g\\ b)V_{Na_2CO_3}=\dfrac{0,4}{1}=0,4l\\ c)n_{NaOH}=2n_{Ba\left(OH\right)_2}=0,8mol\\ C_{M\left(NaOH\right)}=\dfrac{0,8}{0,2+0,4}=\dfrac{4}{3}M\)
Fe2(SO4)3+3Ba(OH)2\(\rightarrow\)2Fe(OH)3+3BaSO4
2Fe(OH)3\(\rightarrow\)Fe2O3+3H2O
Ba(OH)2+H2SO4\(\rightarrow\)BaSO4+2H2O
Ta có
ddB+H2SO4 tạo kết tủa \(\rightarrow\)dd B là Ba(OH)2 dư
Kết tủa A gồm Fe(OH)3 và BaSO4
Chất rắn D gồm Fe2O3 và BaSO4
nBaSO4=\(\frac{0,932}{233}\)=0,004 mol
\(\rightarrow\)nBa(OH)2 dư=0,04 mol
Gọi a là số mol Fe2(SO4)3\(\rightarrow\)nBa(OH)2 tham gia=3a mol
nBaSO4=3a mol
nFe2O3=a mol
Ta có
160a+699a=4,295 \(\rightarrow\)a=0,005 mol
\(\rightarrow\) nFe2(SO4)3=0,005 mol
nBa(OH)2=0,005.3+0,004=0,019 mol
CMFe2(SO4)3=\(\frac{0,005}{0,1}\)=0,05 M
CMBa(OH)2=\(\frac{0,019}{0,1}\)=0,19 M
a) PTHH Phản ứng Na2CO3 + Ba(OH)2 -----> 2NaOH + BaCO3
b) \(n_{Na_2CO_3}=C_M.V=1.0,1=0,1\left(mol\right)\)
=> \(n_{BaCO_3}=0,2\left(mol\right)\Rightarrow m_{BaCO_3}=n.M=0,2.197=39,4\left(g\right)\)
c) \(m_{Ba\left(OH\right)_2}=n.M=0,1.171=17,1\left(g\right)\)
=> \(C\%_{Ba\left(OH\right)_2}=\frac{m_{Ba\left(OH\right)_2}}{m_{dd}}.100\%=\frac{17,1}{200}.100\%=8,55\%\)
a) Na2CO3+Ba(OH)2--->BaCO3+2NaOH
b) n Na2CO3=0,1.1=0,1(mol)
Theo pthh
n BaCO3=n Na2CO3=0,1(mol)
m BaCO3=0,1.179=17,9(g)
c) Theo pthh
n Ba(OH)2=n Na2CO3=0,1(mol)
C%=\(\frac{0,1.171}{200}.100\%=8,55\%\)
C) BaCO3+2HCl---->BaCl2+H2O+CO2
Theo pthh
n HCl=2n BaCO3=0,2(mol)
m HCl=0,2.36,5=7,3(g)
a=m dd HCl=\(\frac{7,3.100}{30}=24,33\left(g\right)\)