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a) H2SO4 + 2NaOH --> Na2SO4 + 2H2O
b) \(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\)
PTHH: H2SO4 + 2NaOH --> Na2SO4 + 2H2O
0,2---->0,4
=> mNaOH = 0,4.40 = 16 (g)
=> \(m_{dd.NaOH}=\dfrac{16.100}{20}=80\left(g\right)\)
c)
PTHH: H2SO4 + 2KOH --> K2SO4 + 2H2O
0,2---->0,4
=> mKOH = 0,4.56 = 22,4 (g)
=> \(m_{dd.KOH}=\dfrac{22,4.100}{5,6}=400\left(g\right)\)
=> \(V_{dd.KOH}=\dfrac{400}{1,045}=382,775\left(ml\right)\)
\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ pthh:H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2 0,4
\(m_{\text{ }NaOH}=0,4.40=16g\\ m_{\text{dd}NaOH}=\dfrac{16.100}{20}=80g\)
\(pthh:H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,2 0,4
\(m_{KOH}=0,4.56=22,4g\\
m_{\text{dd}KOH}=\dfrac{22,4.100}{5,6}=400g\\
V_{\text{dd}}=\dfrac{400}{1,045}=382,7ml\)
\(V_{dd}=\dfrac{22,4}{1,045}=21,4354ml\)
a) nH2SO4 = 0,2 . 1 = 0,2 mol
H2SO4 + 2NaOH -> Na2SO4 + 2H2O
0,2 0,4
mNaOH = 0,4 . 40 = 16g
mddNaOH = \(\frac{16.100\%}{20\%}=80g\)
b) 2KOH + H2SO4 -> K2SO4 + 2H2O
0,4 <---------- 0,2
=> mKOH = 0,4 . 56 = 22,4 g
mddKOH = \(\frac{22,4.100\%}{5,6\%}=400g\)
VddKOH = \(\frac{400}{1,045}=383ml\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{200}.100\%=14,7\%\)
=> \(m_{H_2SO_4}=29,4\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
a. PTHH: 2KOH + H2SO4 ---> K2SO4 + 2H2O
Theo PT: \(n_{KOH}=2.n_{H_2SO_4}=2.0,3=0,6\left(mol\right)\)
=> \(m_{KOH}=0,6.56=33,6\left(g\right)\)
Ta có: \(C_{\%_{KOH}}=\dfrac{33,6}{m_{dd_{KOH}}}.100\%=5,6\%\)
=> \(m_{dd_{KOH}}=600\left(g\right)\)
Theo đề, ta có:
\(D=\dfrac{600}{V_{dd_{KOH}}}=10,45\)(g/ml)
=> \(V_{dd_{KOH}}=57,42\left(ml\right)\)
b. Ta có: \(m_{dd_{K_2SO_4}}=200+33,6=233,6\left(g\right)\)
Theo PT: \(n_{K_2SO_4}=n_{H_2SO_4}=0,3\left(mol\right)\)
=> \(m_{K_2SO_4}=0,3.174=52,2\left(g\right)\)
=> \(C_{\%_{K_2SO_4}}=\dfrac{52,2}{233,6}.100\%=22,35\%\)
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
a) $2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
b)
n H2SO4 = 0,03.1 = 0,03(mol)
n NaOH = 2n H2SO4 = 0,06(mol)
=> CM NaOH = 0,06/0,05 = 1,2M
c) $H_2SO_4 + 2KOH \to K_2SO_4 + 2H_2O$
n KOH = 2n H2SO4 = 0,06(mol)
=> m KOH = 0,06.56 = 3,36 gam
=> m dd KOH = 3,36/5,6% = 60(gam)
=> V dd KOH = m/D = 60/1,045 = 57,42(ml)
a.250ml=0,25l ; nHCl=0,25.1,5=0,375mol
KOH+HCl->KCl+H2O
1mol 1mol 1mol
0,375 0,375 0,375
VKOh=0,375/2=0,1875l
b.CM KCL=0,375/0,25=1,5M
c.NaOH+HCL=NaCl+H2O
1mol 1mol
0,375 0,375
mdd NaOH=0,375.40.100/10=150g
\(n_{H_2SO_4}=0,2.0,25=0,05
mol
\)
a) \(H_2SO_4+2KOH
\rightarrow
K_2SO_4+2H_2O\)
Theo PTHH ta có: \(n_{KOH}=2n_{H_2SO_4}=0,05.2=0,1
mol\)
\(\rightarrow V_{dd
KOH}=\frac{n}{C_M}=\frac{0,1}{0,5}=0,2
\left(l\right)=200\left(ml\right)\)
\(n_{K_2SO_4}=n_{H_2SO_4}=0,05\left(mol\right)\)
\(m_{dd
sau}=250+200=450=0,45\left(l\right)\)
\(\rightarrow C_{M
K_2SO_4}=\frac{0,05}{0,45}=\frac{1}{9}M\)
b)\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(n_{NaOH}=2.n_{H_2SO_4}=0,1\left(mol\right)\rightarrow m_{NaOH}=0,1.40=4\left(g\right)\)
\(m_{dd
NaOH}=\frac{4.100}{20}=20\left(g\right)\)
\(n_{Na_2SO_4}=0,05\left(mol\right)\rightarrow m_{Na_2SO_4}=0,05.142=7,1\left(g\right)\)
Do D=1ml/g -> mdd H2SO4=250(g)
\(C\%_{Na_2SO_4}=\frac{7,1}{250+20}.100=2,63\%\)
