CHO 11,2g Fe tác dụng vừa đủ với m(g) dd H2SO4 tạo ra dd FeSO4 14,7%
a/ tính m
b/ tính C% của dd axit
giúp mk vs đg cần gấp
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a)
$Fe + CuSO_4 \to FeSO_4 + Cu$
Theo PTHH : $n_{Cu} = n_{CuSO_4} = 0,3.1 = 0,3(mol)$
$m_{Cu} = 0,3.64 = 19,2(gam)$
b) $n_{FeSO_4} = n_{CuSO_4} = 0,3(mol)$
$\Rightarrow m_{FeSO_4} = 0,3.152 = 45,6(gam)$
c) $FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4$
$n_{Fe(OH)_2} = n_{FeSO_4} = 0,3(mol)$
$m_{Fe(OH)_2} = 0,3.90 = 27(gam)$
Bài 1 :
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2........0.4....................0.2\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.5}=0.8\left(l\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
Bài 2 :
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.2..........0.3.............................0.3\)
\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{10}=294\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
a, Theo PT: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, \(n_{HCl}=2n_{Fe}=0,4\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)
c, \(n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\)
a) PTHH: Fe + H2SO4 \(\rightarrow\) FeSO4 + H2 \(\uparrow\)
nFe = \(\frac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: n\(H_2\) = n\(FeSO_4\) = nFe = 0,2 (mol)
=> m\(FeSO_4\) = 0,2.152 = 30,4 (g)
=> m\(H_2\) = 0,2.2 = 0,4(g)
mdd sau pứ = 11,2 + m - 0,4 =10,8 + m (g)
Áp dụng CT : C% FeSO4 = \(\frac{m_{FeSO_4}}{md_dsau}pứ\).100%
=> 14,7% = \(\frac{30,4}{10,8+m}\).100%
=> 0,147 ( 10,8+m ) = 30,4
=> 1,5876 + 0,147m = 30,4
=> 0,147m = 28,8124
=> m \(\approx\) 196 (g)
b) Theo PT: n\(H_2SO_4\) = nFe = 0,2 (mol)
=> m\(H_2SO_4\) = 0,2.98 = 19,6 (g)
Áp dụng CT: C% = \(\frac{m_{ct}}{md_d}\).100%
=> C%dd axit = \(\frac{19,6}{196}.100\%\) = 10%
nFe= 11.2/56=0.2 mol
Fe + H2SO4 --> FeSO4 + H2
0.2___0.2______0.2_____0.2
mH2SO4= 0.2*98=19.6g
mFeSO4= 0.2*152=30.4g
mH2= 0.2*2=0.4g
mdd sau phản ứng= mFe + mdd H2SO4 -mH2= 11.2+m-0.4=10.8+m (g)
C%FeSO4= 30.4/ (10.8+m) *100%= 14.7%
<=> 10.8+m= 206.8
<=> m= 196g
C%H2SO4= 19.6/196*100%= 10%
\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)
\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)
0,02 0,06
\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)
0,05 0,05
\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)
\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O|\)
2 3 1 3
0,8 1,2 0,4 1,2
a) \(n_{H2}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=1,2.22,4=26,88\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
⇒ \(m_{H2SO4}=1,2.98=117,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{117,6.100}{29,4}=400\left(g\right)\)
c) \(n_{Al2\left(SO4\right)3}=\dfrac{1,2.1}{3}=0,4\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,4.342=136,8\left(g\right)\)
\(m_{ddspu}=21,6+400-\left(1,2.2\right)=419,2\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{136,8.100}{419,2}=32,63\)0/0
Chúc bạn học tốt
a) Gọi \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
PTHH: Mg + H2SO4 --> MgSO4 + H2
a--->a---------->a-------->a
Fe + H2SO4 --> FeSO4 + H2
b--->b----------->b------>b
=> \(m_{H_2SO_4}=98a+98b\left(g\right)\)
=> \(m_{ddH_2SO_4}=\dfrac{\left(98a+98b\right).100}{19,6}=500a+500b\left(g\right)\)
mdd sau pư = 24a + 56b + 500a + 500b - 2a - 2b = 522a + 554b (g)
Có: \(C\%_{FeSO_4}=\dfrac{152b}{522a+554b}.100\%=7,17\%\)
=> a = 3b
\(C\%_{MgSO_4}=\dfrac{120a}{522a+554b}.100\%=16,98\%\)
b)
Có: \(\left\{{}\begin{matrix}a=3b\\24a+56b=1,92\end{matrix}\right.\)
=> a = 0,045; b = 0,015
\(n_{CuSO_4}=0,1.1=0,1\left(mol\right)\)
PTHH: Mg + CuSO4 --> MgSO4 + Cu
0,045->0,045----->0,045
Fe + CuSO4 --> FeSO4 + Cu
0,015-->0,015----->0,015
=> \(\left\{{}\begin{matrix}n_{CuSO_4\left(dư\right)}=0,04\left(mol\right)\\n_{MgSO_4}=0,045\left(mol\right)\\n_{FeSO_4}=0,015\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(CuSO_4\left(dư\right)\right)}=\dfrac{0,04}{0,1}=0,4M\\C_{M\left(MgSO_4\right)}=\dfrac{0,045}{0,1}=0,45M\\C_{M\left(FeSO_4\right)}=\dfrac{0,015}{0,1}=0,15M\end{matrix}\right.\)