1. Cho 11g hỗn hợp Fe và Al tác dụng vừa đủ 2 lít dd HCl bM thu được 8,96l khí xác định m hỗn hợp và b
2. Cho 11,2g Fe td vừa đủ với dd a lít HCl 2M thu được b lít khí tính a b
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a) 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
b) Gọi nAl = x, nFe = y
=> 27x + 56y = 11 (1)
Theo pt: \(\Sigma\)nH2 = 1,5x + y = \(\dfrac{8,96}{22,4}=0,4mol\)(2)
Từ 1 + 2 => x = 0,2 , y = 0,1
=> mAl = 0,2.27 = 5,4 => %mAl = \(\dfrac{5,4}{11}.100\%\approx49,09\%\)
%mFe = 100 - 49,09 = 50,91%
c) Theo pt: nHCl = 2nH2 = 0,8 mol
=> mHCl = 0,8 . 36,5 = 29,2g
=> \(m_{dd}\)HCl = 29,2 : 10% = 292g
d) mdd sau phản ứng = m A + mHCl = 11 + 292 = 303g
Theo pt: nAlCl3 = nAl = 0,2 mol => m AlCl3 = 26,7g
=> C%AlCl3 = \(\dfrac{26,7}{303}.100\%\) = 8,81%
tương tự nFeCl2 = 0,1 mol => C%FeCl2 = 4,19%
\(a,Fe+2HCl\rightarrow FeCl_2+H_2\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\Rightarrow n_{Fe}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\%\approx41,176\%\\ \Rightarrow\%m_{CuO}\approx58,824\%\\ b,n_{CuO}=\dfrac{13,6-0,1.56}{80}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.\left(n_{Fe}+n_{CuO}\right)=2.\left(0,1+0,1\right)=0,4\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
a) Sửa đề: dd H2SO4 9,8%
Ta có: \(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\) \(\Rightarrow m_{H_2}=0,35\cdot2=0,7\left(g\right)\)
Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{H_2}=0,35\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,35\cdot98}{9,8\%}=350\left(g\right)\)
\(\Rightarrow m_{dd}=m_{KL}+m_{H_2SO_4}-m_{H_2}=361,6\left(g\right)\)
b) Tương tự câu a
Trong \(20,4g\) hỗn hợp có: \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow65a+56b+27c=20,4\left(1\right)\)
\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)
\(BTe:2n_{Zn}+2n_{Fe}+3n_{Al}=2n_{H_2}\)
\(\Rightarrow2a+2b+3c=2\cdot0,45\left(2\right)\)
Trong \(0,2mol\) hhX có \(\left\{{}\begin{matrix}Zn:ka\left(mol\right)\\Fe:kb\left(mol\right)\\Al:kc\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow ka+kb+kc=0,2\)
\(n_{Cl_2}=\dfrac{6,16}{22,4}=0,275mol\)
\(BTe:2n_{Zn}+3n_{Fe}+3n_{Al}=2n_{Cl_2}\)
\(\Rightarrow2ka+3kb+3kc=2\cdot0,275\)
Xét thương:
\(\dfrac{ka+kb+kc}{2ka+3kb+3kc}=\dfrac{0,2}{2\cdot0,275}\Rightarrow\dfrac{a+b+c}{2a+3b+3c}=\dfrac{4}{11}\)
\(\Rightarrow3a-b-c=0\left(3\right)\)
Từ (1), (2), (3)\(\Rightarrow\left\{{}\begin{matrix}a=0,1mol\\b=0,2mol\\c=0,1mol\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Zn}=6,5g\\m_{Fe}=11,2g\\m_{Al}=2,7g\end{matrix}\right.\)
\(\text{Đ}\text{ặt}:n_{Mg}=a\left(mol\right);n_{Al}=1,5a\left(mol\right)\\ \Rightarrow24a+27.1,5a=12,9\\ \Leftrightarrow a=0,2\left(mol\right)\\\Rightarrow n_{Mg}=0,2\left(mol\right);n_{Al}=0,3\left(mol\right)\\ 2Al+3Cl_2\rightarrow\left(t^o\right)2AlCl_3\\ Mg+Cl_2\rightarrow\left(t^o\right)MgCl_2\\ n_{AlCl_3}=n_{Al}=0,3\left(mol\right);n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ m_{mu\text{ố}i}=m_{MgCl_2}+m_{AlCl_3}=95.0,2+0,3.133,5=59,05\left(g\right)\)
Đây là bài 1
B2:
\(n_{H_2}=0,4\left(mol\right)\\ n_{Cl_2}=0,45\left(mol\right)\\ \text{Đ}\text{ặt}:n_{Al}=x\left(mol\right);n_{Fe}=y\left(mol\right)\left(x,y>0\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ 2Al+3Cl_2\rightarrow\left(t^o\right)2AlCl_3\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ \Rightarrow\left\{{}\begin{matrix}1,5x+y=0,4\\1,5x+1,5y=0,45\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\\ \Rightarrow m=m_{Al}+m_{Fe}=27x+56y=27.0,2+56.0,1=11\left(g\right)\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+3H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ a,n_{HCl}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,8}{8}=0,1\left(l\right)\\ b,FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_2+2AgCl\downarrow\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\\ n_{AgCl}=n_{AgNO_3}=3.n_{AlCl_3}+2.n_{FeCl_2}=3.a+2.b=3.0,2+2.0,1=0,8\left(mol\right)\\ \Rightarrow a=\dfrac{170.0,8}{250}.100=54,4\%\\ b=m_{\downarrow}=m_{AgCl}=0,8.143,5=114,8\left(g\right)\)
a, Ta có: 24nMg + 56nFe = 12,8 (1)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,3\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,3.24=7,2\left(g\right)\\m_{Fe}=0,1.56=5,6\left(g\right)\end{matrix}\right.\)
b, \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{0,8}{2}=0,4\left(l\right)\)
c, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
Theo PT: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,3.58+0,1.90=26,4\left(g\right)\)
a. Số gam mỗi kim loại trong hỗn hợp ban đầu:
Mg: 9,6 gamFe: 22,4 gamb. Thể tích dung dịch HCl 2M đã phản ứng: 0,2 lít
c. Khối lượng kết tủa thu được khi dd A tác dụng với dung dịch NaOH dư là 0,4 gam.
------------------------------------đấy
a)
\(n_{H_2\left(1\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2 (1)
0,6<----------------------0,3
=> mNa = 0,6.23 = 13,8 (g)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,1<-0,2
=> mFe = 0,1.56 = 5,6 (g)
mCu = 10 (g)
\(\left\{{}\begin{matrix}\%Na=\dfrac{13,8}{13,8+5,6+10}.100\%=46,94\%\\\%Fe=\dfrac{5,6}{13,8+5,6+10}.100\%=19,05\%\\\%Cu=\dfrac{10}{13,8+5,6+10}.100\%=34,01\%\end{matrix}\right.\)
b)
PTHH: FexOy + yH2 --to--> xFe + yH2O
\(\dfrac{0,3}{y}\)<--0,3
=> \(M_{Fe_xO_y}=\dfrac{17,4}{\dfrac{0,3}{y}}=58y\left(g/mol\right)\)
=> 56x = 42y
=> \(\dfrac{x}{y}=\dfrac{3}{4}\) => CTHH: Fe3O4