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Bài 1 :
Giả sử : hỗn hợp có 1 mol
\(n_{H_2}=a\left(mol\right),n_{O_2}=1-a\left(mol\right)\)
\(\overline{M_X}=0.3276\cdot29=9.5\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow m_X=2a+32\cdot\left(1-a\right)=9.5\left(g\right)\)
\(\Rightarrow a=0.75\)
Cách 1 :
\(\%H_2=\dfrac{0.75}{1}\cdot100\%=75\%\)
\(\%O_2=100-75=25\%\)
Cách 2 em tính theo thể tích nhé !
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=0,1(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,1.24}{6,4}.100\%=37,5\%\\ \Rightarrow \%_{MgO}=100\%-37,5\%=62,5\%\)
\(b,n_{MgO}=\dfrac{6,4-0,1.24}{40}=0,1(mol)\\ \Rightarrow n_{HCl}=2.0,1+2.0,1=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(l)\\ c,n_{MgCl_2}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{MgCl_2}}=\dfrac{0,2}{0,8}=0,25M\)
CH4+2O2-to>CO2+2H2O
x---------2x-------x---------2x
C2H4+3O2-to>2CO2+2H2O
y-------------3y------2y-------2y
=>\(\left\{{}\begin{matrix}16x+28y=1,36\\2x+3y=0,16\end{matrix}\right.\)
=>x=0,05 mol , y=0,02 mol
=>%m CH4=\(\dfrac{0,05.16}{1,36}100\)=58,82%
=>%m C2H4=41,17%
=>mH2O=(0,1+0,04).18=2,52g
Đáp án D
Áp dụng ĐLBTKL:
Ta có:
⇒ 28x - 44x = 11,2 - 16
⇒ x = 0,3
Vậy VCO = 0,3.22,4 = 6,72 lít
Đặt tỉ lệ
Rồi lập hệ pt
\(\text{a) }n_{H_2O}=\dfrac{m}{M}=\dfrac{0,9}{18}=0,05\left(mol\right)\)
\(pthh:CuO+H_2\overset{t^o}{\rightarrow}Cu+H_2O\left(1\right)\\ \text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }x\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }x\\ PbO+H_2\overset{t^o}{\rightarrow}Pb+H_2O\left(2\right)\\ \text{ }\text{ }\text{ }y\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }y\)
Từ (1) và (2), ta có hệ phương trình:
\(\left\{{}\begin{matrix}x+y=0,05\\80x+217y=8,59\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{113}{6850}\\y=\dfrac{459}{13700}\end{matrix}\right.\)
\(\Rightarrow m_{CuO}=n\cdot M=80\cdot x=80\cdot\dfrac{113}{6850}=1,32\left(g\right)\\ \Rightarrow m_{PbO}=n\cdot M=217\cdot\dfrac{459}{13700}=7,27\left(g\right)\)
\(\Rightarrow\%CuO=\dfrac{1,32\cdot100}{8,59}=15,37\%\\ \%PbO=\dfrac{7,27\cdot100}{8,59}=84,63\%\)
b) Theo \(pthh\left(1\right):n_{Cu}=n_{CuO}=\dfrac{113}{6850}\left(mol\right)\)
Theo \(pthh\left(2\right):n_{Pb}=n_{PbO}=\dfrac{459}{13700}\left(mol\right)\)
\(\Rightarrow m_{Cu}=n\cdot M=\dfrac{113}{6850}\cdot64=1,06\left(g\right)\\ m_{Pb}=n\cdot M=\dfrac{459}{13700}\cdot207=6,94\left(g\right)\\ \Rightarrow m_{h^2}=1,06+6,94=8\left(g\right)\)
\(\Rightarrow\%Cu=\dfrac{1,06\cdot100}{8}=13,25\%\\ \%Pb=\dfrac{6,94\cdot100}{8}=86,75\%\\ \)