Tính nồng độ mol?
a) 200 ml dung dịch C chứa 7,5 gam CuSO4.5H2O.
b) dd Ba(OH) 20,684 % ( d = 1,25 g/ml )
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\(\text{a) 2HNO3+Ba(OH)2->Ba(NO3)2+2H2O}\)
\(\text{nBa(OH)2=100x25,65%/171=0,15(mol)}\)
V dd Ba(OH)2=100/1,25=80(ml)
\(\Rightarrow\text{CMBa(OH)2=0,15/0,08=1,875(M)}\)
\(\text{b) nHNO3=0,2.1,6=0,32(mol)}\)
=>nHNO3 dư=0,02(mol)
mdd spu=200x1,2+100=340(g)
\(\left\{{}\begin{matrix}\text{C%HNO3 dư=0,02x63/340x100=0,37%}\\\text{C%Ba(NO3)2=0,15x261/340=11,51% }\end{matrix}\right.\)
Ta có: \(n_{HCl}=0,1.2=0,2\left(mol\right)\)
\(n_{H_2SO_4}=0,1.1=0,1\left(mol\right)\)
PT: \(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
_____0,2_____0,1 (mol)
\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_{4\downarrow}+2H_2O\)
0,1________0,1 (mol)
⇒ nBa(OH)2 = 0,1 + 0,1 = 0,2 (mol)
\(\Rightarrow V_{Ba\left(OH\right)_2}=\dfrac{0,2}{2}=0,1\left(l\right)=100\left(ml\right)\)
⇒ Đáp án: D
Bạn tham khảo nhé!
Ta có
\(\text{nHCl=0,2.0,1=0,02(mol)}\)
\(\text{nH2SO4=0,2.0,05=0,01(mol)}\)
2HCl+Ba(OH)2\(\rightarrow\)BaCl2+2H2O
H2SO4+Ba(OH)2\(\rightarrow\)BaSO4+2H2O
Ta có pH=13\(\rightarrow\)Ba(OH)2 dư
pH=13\(\rightarrow\)pOH=1\(\Rightarrow\)CM[OH-]=0,1(M)
\(\rightarrow\)CMBa(OH)2 dư=0,05(M)
\(\text{nBa(OH)2 dư=0,05.0,5=0,025(mol)}\)
\(\text{m=0,01.233=2,33(g)}\)
nBa(OH)2=0,025+0,02/2+0,01=0,045(mol)
\(\rightarrow\)a=\(\frac{0,045}{0,3}\)=0,15(M)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
\(n_{OH^-}=0,5.0,2+0,2.2.0,3=0,22\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,22}{0,5}=0,44M\)
\(n_{Na^+}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,1}{0,5}=0,2M\)
\(n_{Ba^{2+}}=0,2.0,3=0,06\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,06}{0,5}=0,12M\)
Gọi \(\left\{{}\begin{matrix}C_{M\left(A\right)}=aM\\C_{M\left(B\right)}=bM\end{matrix}\right.\)
Giả sử trộn 50ml dd A với 50ml dd B để thu được 100ml dd C
=> \(\left\{{}\begin{matrix}n_{NaOH}=0,05a\left(mol\right)\\n_{Ba\left(OH\right)_2}=0,05b\left(mol\right)\end{matrix}\right.\)
\(n_{BaSO_4}=\dfrac{9,32}{233}=0,04\left(mol\right)\)
nH2SO4 = 0,035.2 = 0,07 (mol)
PTHH: Ba(OH)2 + H2SO4 --> BaSO4 + 2H2O
0,04<----0,04<-------0,04
2NaOH + H2SO4 --> Na2SO4 + 2H2O
0,06<----0,03
=> \(\left\{{}\begin{matrix}0,05a=0,06\\0,05b=0,04\end{matrix}\right.\)
=> a = 1,2; b = 0,8
20 ml dd A chứa nNaOH = 0,02.1,2 = 0,024 (mol)
\(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)
PTHH: 2NaOH + Al2O3 --> 2NaAlO2 + H2O
0,024-->0,012
Ba(OH)2 + Al2O3 --> Ba(AlO2)2 + H2O
0,188<---0,188
=> \(V_{dd.B}=\dfrac{0,188}{0,8}=0,235\left(l\right)=235\left(ml\right)\)
\(a.n_{CuSO_4}=\dfrac{7,5}{250}=0,03\left(mol\right)\\ C_{MddCuSO_4}=\dfrac{0,03}{0,2}=0,15\left(M\right)\\ b.C_{MddBa\left(OH\right)_2}=\dfrac{C\%_{ddBa\left(OH\right)_2}.10.D_{ddBa\left(OH\right)_2}}{M_{Ba\left(OH\right)_2}}\\ =\dfrac{20,684.10.1,25}{171}\approx1,512\left(M\right)\)