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\(n_{Ba^{2+}}=0.1\cdot0.05=0.005\left(mol\right)\)
\(n_{OH^-}=0.1\cdot0.05\cdot2+0.1\cdot0.3=0.04\left(mol\right)\)
\(n_{Fe^{2+}}=0.1\cdot0.2=0.02\left(mol\right)\)
\(n_{SO_4^{2-}}=0.1\cdot0.1=0.01\left(mol\right)\)
\(n_{H^+}=0.1\cdot0.1\cdot2=0.02\left(mol\right)\)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
\(0.005....0.005..........0.005\)
\(\Rightarrow SO_4^{2-}dư\)
\(OH^-+H^+\rightarrow H_2O\)
\(0.02.......0.02\)
\(Fe^{2+}+2OH^-\rightarrow Fe\left(OH\right)_2\)
\(0.01....0.04-0.02....0.01\)
\(\Rightarrow Fe^{2+}dư\)
\(m\downarrow=0.005\cdot197+0.01\cdot90=2.065\left(g\right)\)
nNaOH = 0,1.0,2 = 0,02 mol => nOH- = 0,02 mol
nCa(OH)2 = 0,1.0,2 = 0,02 mol => nOH- = 0,02.2 = 0,04 mol
=> Sau khi trộn nOH- = 0,02 + 0,04 = 0,06 mol
Thể tích dung dịch sau khi trộn = 100 + 200 = 300ml = 0,3 lít
=> [OH-] = \(\dfrac{0,06}{0,3}\)= 0,2 M
\(n_{Ca^{2+}}=0.1\cdot0.4=0.04\left(mol\right),n_{Ba^{2+}}=0.1\cdot0.2=0.02\left(mol\right)\)
\(n_{CO_3^{2-}}=0.2\cdot0.3+0.2\cdot0.1=0.08\left(mol\right)\)
\(Ca^{2+}+CO_3^{2-}\rightarrow CaCO_3\)
\(0.04.......0.04.......0.04\)
\(Ba^{2+}+CO_3^{2-}\rightarrow BaCO_3\)
\(0.02.......0.02.......0.02\)
\(m_{\downarrow}=0.04\cdot100+0.02\cdot197=7.94\left(g\right)\)
Đáp án C
nH+ = 0,02 mol; nOH-= 0,04 mol
H+ + OH- → H2O
0,02 0,04
nOH- dư = 0,02 mol; [OH-] dư = 0,02/0,2 = 0,1M suy ra [H+] = 10-13 M suy ra pH = 13
\(n_{CaCO_3}=\dfrac{25}{100}=0.25\left(mol\right)\)
\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
\(0.25...........0.25...........0.25\)
\(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0.25}{0.1}=2.5\left(M\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(0.25..............0.25\)
\(V_{CH_4}=0.25\cdot22.4=5.6\left(l\right)\)
a) nCaCO3=0,25(mol)
CH4 + 2 O2 -to-> CO2 + 2 H2O
0,25<------------------0,25(mol)
CO2 + Ca(OH)2 -> CaCO3 + H2O
0,25<------0,25-----------0,25(mol)
b) CMddCa(OH)2= 0,25/0,1= 2,5(M)
b) V(CH4,đktc)=0,25.22,4=5,6(l)
Ta có: \(\Sigma n_{H^+}=0,1.0,1.2+0,1.0,2=0,04\left(mol\right)\)
\(\Sigma n_{OH^-}=0,1.0,2+0,1.0,1.2=0,04\left(mol\right)\)
PT ion: \(H^++OH^-\rightarrow H_2O\)
_____0,04____0,04_________ (mol)
⇒ H+ pư vừa đủ với OH-
⇒ a = pH = 7
Ta có: \(n_{SO_4^{2-}}=0,1.0,1=0,01\left(mol\right)\)
\(n_{Ba^{2+}}=0,1.0,1=0,01\left(mol\right)\)
PT ion: \(SO_4^{2-}+Ba^{2+}\rightarrow BaSO_{4\downarrow}\)
_______0,01___0,01______0,01___ (mol)
\(\Rightarrow m=m_{BaSO_4}=0,01.233=2,33\left(g\right)\)
Bạn tham khảo nhé!
