đốt sắt trong khí O2 thú được Fe3O4.muốn điếu chế 23,2 gam Fe3O4 thì khối lượng Fe cần dùng là bao nhiêu gam ?biết hiệu xuất phản ứng đạt 80 %.
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PTHH:3Fe+2O2----->Fe3O4
a.nFe3O4=mFe3O4MFe3O4=46,4232=0,2(mol)nFe3O4=mFe3O4MFe3O4=46,4232=0,2(mol)
Theo PTHH:nO2=2nFe3O4=2.0,2=0,4(mol)nO2=2nFe3O4=2.0,2=0,4(mol)
VO2=nO2.22,4=0,4.22,4=8,96(l)VO2=nO2.22,4=0,4.22,4=8,96(l)
b.Theo PTHH:nFe=3nFe3O4=3.0,2=0,6(mol)nFe=3nFe3O4=3.0,2=0,6(mol)
mFe=nFe.MFe=0,6.56=33,6(g)mFe=nFe.MFe=0,6.56=33,6(g)
c.PTHH:4Al+3O2----->2Al2O3
Theo PTHH:nAl=43nO2=43.0,4=815(mol)nAl=43nO2=43.0,4=815(mol)
mAl=nAl.MAl=815.27=14,4(g)
a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
\(a,PTHH:3Fe+2O_2\xrightarrow{t^o}Fe_3O_4\\ b,BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{O_2}=23,2-16,8=6,4(g)\)
a) \(n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
0,6--->0,4------->0,2 (mol)
=> \(m_{Fe_3O_4}=0,2.232=46,4\left(g\right)\)
b) \(V_{O_2\left(\text{đ}kc\right)}=0,4.24,79=9,916\left(l\right)\)
c) PTHH: \(2KClO_3\xrightarrow[]{t^o}2KCl+3O_2\)
\(\dfrac{4}{15}\)<-------------------0,4 (mol)
=> \(m_{KClO_3}=\dfrac{4}{15}.122,5=\dfrac{98}{3}\left(g\right)\)
Câu 8:
\(d_{\dfrac{A}{KK}}>1\\ \Leftrightarrow M_A>M_{KK}\\ \Leftrightarrow M_A>29\\ Vậy:Chọn.A\)
(Vì 44>29>28>2)
\(Câu.7:C\\ Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\\ Câu.6:A\)
a)
\(n_{P_2O_5} = \dfrac{42,6}{142} = 0,3(mol)\\ \)
4P + 5O2 \(\xrightarrow{t^o}\) 2P2O5
0,6.............0,75.................0,3..........(mol)
mP = 0,6.31 = 18,6(gam)
b)
2KClO3 \(\xrightarrow{t^o}\) 2KCl + 3O2
0,5....................................0,75.....(mol)
\(m_{KClO_3} = 0,5.122,5 = 61,25(gam)\)
c)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ \dfrac{n_{Fe}}{3} = 0,1 < \dfrac{n_{O_2}}{2} = 0,375\)
nên hiệu suất tính theo số mol Fe.
\(n_{Fe\ pư} = 0,3.90\% = 0,27(mol)\\ n_{Fe_3O_4} =\dfrac{1}{3}n_{Fe\ pư} = 0,09(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,09.232 = 20,88(gam)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
BTKL: \(m_{O_2}+m_{Fe}=m_{Fe_3O_4}\)
\(\Rightarrow m_{O_2}=23,2-16,8=6,4(g)\)
Ta co pthh
3Fe + 2O2 \(\rightarrow\)Fe3O4
Theo de bai ta co
nFe3O4 =\(\dfrac{23,2}{232}=0,1mol\)
Theo pthh
nFe=3nFe3O4=3.0,1=0,3 mol
\(\Rightarrow\)mFe=0,3 .56=16,8 g
Vi hieu suat phan ung la 80% nen khoi luong cua Fe la
mFe=\(\dfrac{16,8.100}{80}=21g\)
Sao lại chia cho 232 ạ??