Cho 1,02 g Al2O3 tác dụng với 100ml dung dịch HCl 1m. Tính tính nồng độ mol dung dịch sau phản ứng
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\(n_{HCl}=0,1.1=0,1\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,1.1=0,1\left(mol\right)\)
PTHH :
\(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)
trc p/u : 0,1 0,1
p/u : 0,1 0,05 0,05 0,1
sau p/u : 0 0,05 0,05 0,1
\(C_{M_{BaCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(C_{M_{Ba\left(OH\right)_2dư}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(m_{BaCl_2}=0,05.208=10,4\left(g\right)\)
a) nNaOH= 0,15(mol) ; nH3PO4= 0,1(mol)
Ta có: 1< 0,15/0,1 <2
=> Sản phẩm thu được là hỗn hợp 2 muối: NaH2PO4 và Na2HPO4
a) PTHH: NaOH + H3PO4 -> NaH2PO4 + H2O
x____________x__________x(mol)
2 NaOH + H3PO4 -> Na2HPO4 + 2 H2O
y_______0,5y_________0,5y(mol)
b) Ta có hpt:
\(\left\{{}\begin{matrix}x+y=0,15\\x+0,5y=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,05\\y=0,1\end{matrix}\right.\)
=> m(muối)=mNaH2PO4 + mNa2HPO4= 120.0,05+142.0,1.0,5=13,1(g)
c) Vddmuoi= VddNaOH+ VddH3PO4= 0,1+0,1=0,2(l)
=> CMddNaH2PO4= 0,05/0,2=0,25(M)
CMddNa2HPO4=(0,1.0,5)/0,2=0,25(M)
Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)
\(n_{HCl}=4.100:1000=0,4\left(mol\right)\)
a. PTHH: MgO + 2HCl ---> MgCl2 + H2O
Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)
Vậy HCl dư.
=> \(n_{dư}=\dfrac{0,1.2}{0,4}=0,5\left(mol\right)\)
=> \(m_{dư}=0,5.36,5=18,2\left(g\right)\)
b. Ta có: \(V_{dd_{MgCl_2}}=V_{HCl}=\dfrac{100}{1000}=0,1\left(lít\right)\)
Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)
=> \(C_{M_{MgCl_2}}=\dfrac{0,1}{0,1}=1M\)
Bài 9 :
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05--->0,1-------->0,05
a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)
b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)
c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)
Câu 10 :
\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
0,05-->0,1------->0,05
\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)
\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)
\(a,Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right);n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{ZnCl_2}=136.0,2=27,2\left(g\right);C_{MddHCl}=\dfrac{0,4}{0,1}=4\left(M\right)\\ b,Zn+CuSO_4\rightarrow ZnSO_4+Cu\\ n_{CuSO_4}=\dfrac{20.10\%}{160}=0,0125\left(mol\right);n_{Zn}=0,2\left(mol\right)\\ Vì:\dfrac{0,0125}{1}< \dfrac{0,2}{1}\Rightarrow Zn.dư\\ n_{Zn\left(p.ứ\right)}=n_{ZnSO_4}=n_{CuSO_4}=0,0125\left(mol\right)\\m_{Zn\left(p.ứ\right)}=0,0125.65=0,8125\left(g\right)\\ m_{ddsau}=m_{Zn\left(p.ứ\right)}+m_{ddCuSO_4}=0,8125+20=20,8125\left(g\right)\\ C\%_{ddZnSO_4}=\dfrac{0,0125.161}{20,8125}.100\approx9,67\%\)
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(n_{KOH}=0,2\cdot0,5=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}=n_{K_2SO_4}=0,05\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\\C_{M_{K_2SO_4}}=\dfrac{0,05}{0,2+0,1}\approx0,17\left(M\right)\end{matrix}\right.\)
Bài 1 :
200ml = 0,2l
100ml = 0,1l
\(n_{KOH}=0,5.0,2=0,1\left(mol\right)\)
a) Pt : \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O|\)
2 1 1 2
0,1 0,05 0,05
b) \(n_{H2SO4}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(C_{M_{ddH2SO4}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
c) \(n_{K2SO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{ddspu}=0,2+0,1=0,3\left(l\right)\)
\(C_{M_{K2SO4}}=\dfrac{0,05}{0,3}=\dfrac{1}{6}\left(M\right)\)
Chúc bạn học tốt
\(Na_2SO_3+2HCl->2NaCl+SO_2+H_2O\\ n_{Na_2SO_3}=0,1mol\\ n_{HCl}=0,3mol\\ \Rightarrow HCl:dư\\ C_{M\left(HCl\right)}=\dfrac{0,1}{0,2}=0,5M\\ C_{M\left(NaCl\right)}=\dfrac{0,2}{0,2}=1M\)
\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)
\(0.1.............0.05...............0.05...........0.05\)
\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)
\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)
$n_{Al_2O_3} = \dfrac{1,02}{102} = 0,01(mol) ; n_{HCl} = 0,1(mol)$
Al2O3 + 6HCl → 2AlCl3 + 3H2O
0,01.........0,06.........0,02..........................(mol)
Suy ra :
$C_{M_{AlCl_3}} = \dfrac{0,02}{0,1} = 0,2M$
$C_{M_{HCl\ dư}} = \dfrac{0,1 - 0,06}{0,1} = 0,4M$