Đốt cháy hoàn toàn 24(g) Cacbon trong khí oxi thì thu được bao nhiêu gam Cacbonic nếu hiệu suất bằng 90%. Tính khối lượng oxi thực tế đã phản ứng
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\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:2Mg+O_2\underrightarrow{t^o}2MgO\)
0,2 0,1 0,2
\(V_{O_2}=0,1.22,4=2,24L\\
m_{MgO}=0,2.40=8g\)
\(n_C=\dfrac{3}{12}=0,25\left(mol\right)\)
\(pthh:C+O_2\underrightarrow{t^o}CO_2\)
\(LTL:0,25>0,1\)
=> C không cháy hết
a, nO2 = 5,6/22,4 = 0,25 (mol)
PTHH: C + O2 -> (t°) CO3
Mol: 0,25 <--- 0,25 ---> 0,25
b, mCO2 = 0,25 . 44 = 11 (g)
c, LTL: 0,2 < 0,25 => O2 dư
a)
\(n_{P_2O_5} = \dfrac{42,6}{142} = 0,3(mol)\\ \)
4P + 5O2 \(\xrightarrow{t^o}\) 2P2O5
0,6.............0,75.................0,3..........(mol)
mP = 0,6.31 = 18,6(gam)
b)
2KClO3 \(\xrightarrow{t^o}\) 2KCl + 3O2
0,5....................................0,75.....(mol)
\(m_{KClO_3} = 0,5.122,5 = 61,25(gam)\)
c)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)
\(n_{Fe} = \dfrac{16,8}{56} = 0,3(mol)\\ \dfrac{n_{Fe}}{3} = 0,1 < \dfrac{n_{O_2}}{2} = 0,375\)
nên hiệu suất tính theo số mol Fe.
\(n_{Fe\ pư} = 0,3.90\% = 0,27(mol)\\ n_{Fe_3O_4} =\dfrac{1}{3}n_{Fe\ pư} = 0,09(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,09.232 = 20,88(gam)\)
PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,3}{3}< \dfrac{0,3}{2}\) , ta được O2 dư.
Mà: H% = 80% \(\Rightarrow n_{Fe\left(pư\right)}=0,3.80\%=0,24\left(mol\right)\)
\(\Rightarrow n_{Fe\left(dư\right)}=0,3.0,24=0,06\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\)
Chất rắn thu được gồm Fe dư và Fe3O4.
⇒ mcr = mFe (dư) + mFe3O4 = 0,06.56 + 0,1.232 = 26,56 (g)
Bạn tham khảo nhé!
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
→ Oxi dư, vậy bài toán tính theo số mol của P
Do H = 80% nên khối lượng chất rắn thu được sau phản ứng là:
\(C\left(1,8\right)+O_2\left(1,8\right)\rightarrow CO_2\left(1,8\right)\)
\(n_{C\left(pứ\right)}=\frac{24}{12}.90\%=1,8\left(mol\right)\)
\(\Rightarrow m_{CO_2}=1,8.44=79,2\left(g\right)\)
\(\Rightarrow m_{O_2}=1,8.32=57,6\left(g\right)\)
PTHH: \(C+O_2\underrightarrow{t^o}CO_2\)
\(n_{C\left(lt\right)}=\dfrac{24}{12}=2\left(mol\right)\)
\(n_{C\left(pứ\right)}=\dfrac{2.90}{100}=1,8\left(mol\right)\)
\(n_{CO_2}=n_{O_2}=n_C=1,8\left(mol\right)\)
\(m_{CO_2}=1,8.44=79,2\left(g\right)\)
\(m_{O_2}=1,8.32=57,6\left(g\right)\)