Dẫn 8,96 l hỗn hợp X gồm metan và etilen vào 200ml dd Br2. Sau pư hoàn toàn thấy thoát ra 2,24l khí
a, Tính %V mỗi khí trong hỗn hợp X
b,Tính Cm dd Br2 pư và cho biết sau khi pư kết thúc khối lượng bình Br2 tăng hay giảm bao nhiêu gam ?
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\(a,Gọi\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\\n_{C_2H_2}=c\left(mol\right)\end{matrix}\right.\\ n_{hhkhí}=0,4\left(mol\right)\\ n_{CO_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ n_{Br_2}=\dfrac{64}{160}=0,4\left(mol\right)\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ Mol:a\rightarrow2a\rightarrow a\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:b\rightarrow3b\rightarrow2b\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:c\rightarrow2,5c\rightarrow2c\\ Hệ.pt\left\{{}\begin{matrix}a+b+c=0,4\\b+2c=0,4\\a+2b+2c=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\\c=0,1\left(mol\right)\end{matrix}\right.\)
\(\%V_{CH_4}=\%V_{C_2H_2}=\dfrac{0,1}{0,4}=25\%\\ \%V_{C_2H_4}=\dfrac{0,2}{0,4}=50\%\)
\(m_{CH_4}=0,1.16=1,6\left(g\right)\\ m_{C_2H_4}=28.0,2=5,6\left(g\right)\\ m_{C_2H_2}=0,1.26=2,6\left(g\right)\\ \%m_{CH_4}=\dfrac{1,6}{1,6+5,6+2,6}=16,32\%\\ \%m_{C_2H_4}=\dfrac{5,6}{1,6+5,6+2,6}=57,14\%\\ \%m_{C_2H_2}=100\%-16,32\%-57,14\%=26,54\%\)
\(b,PTHH:C_2H_5OH\rightarrow C_2H_4+H_2O\\ Mol:0,2\leftarrow0,2\\ m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
Dài quá!!!
\(a,n_{hhkhí\left(C_2H_4,C_2H_2\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Br_2}=\dfrac{80}{160}=0,5\left(mol\right)\\ Gọi\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ Hệ.pt\left\{{}\begin{matrix}a+b=0,3\\a+2b=0,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\\ \%V_{C_2H_4}=\dfrac{0,1}{0,3}=33,33\%\\ \%V_{C_2H_2}=100\%-33,335=66,67\%\)
\(b,PTHH:\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:0,1\rightarrow0,3\rightarrow0,2\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:0,2\rightarrow0,25\rightarrow0,4\\ n_{CO_2}=0,2+0,4=0,6\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ Mol:0,6\rightarrow0,6\rightarrow0,6\\ m_{CaCO_3}=0,6.100=60\left(g\right)\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Al}=0,2.27=5,4\left(g\right)\)
⇒ mFeO = 12,6 - 5,4 = 7,2 (g)
c, Phần này đề cho dd NaOH dư hay vừa đủ bạn nhỉ?
d, Cho hh vào dd H2SO4 đặc nguội thì có khí thoát ra.
PT: \(2FeO+4H_2SO_{4\left(đ\right)}\rightarrow Fe_2\left(SO_4\right)_3+SO_2+4H_2O\)
Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
Theo PT: \(n_{SO_2}=\dfrac{1}{2}n_{FeO}=0,05\left(mol\right)\)
\(\Rightarrow V_{SO_2}=0,05.22,4=1,12\left(l\right)\)
\(37) n_{C_2H_4} = a(mol) ; n_{C_2H_2} = b(mol)\\ \Rightarrow a + b = \dfrac{6,72}{22,4} = 0,3(1)\\ m_{tăng} = m_{C_2H_4} + m_{C_2H_2} = 28a + 26b = 8(2)\\ (1)(2)\Rightarrow a = 0,1 ; b = 0,2\\ \%V_{C_2H_4} = \dfrac{0,1}{0,3}.100\% = 33,33\%\\ \%V_{C_2H_2} = 100\%-33,33\% = 66,67\%\)
\(38) n_{CO_2} = \dfrac{38,08}{22,4} = 1,7(mol) ; n_{H_2O} = \dfrac{19,8}{18} = 1,1(mol)\\ n_{CO_2} > n_{H_2O} \to CTTQ : C_nH_{2n-2}\\ n_C = n_{CO_2} = 1,7(mol)\\ n_H = 2n_{H_2} = 2,2(mol)\\ \Rightarrow \dfrac{n}{2n-2} = \dfrac{1,7}{2,2}\\ \Rightarrow n = 2,83\\ Vì : 2 < n = 2,83 < 3\ nên\ CTHH\ X\ và\ Y\ là: C_2H_2,C_3H_4\)
Coi : hỗn hợp gồm : ankan và anken
\(n_{O_2}=\dfrac{30.24}{22.4}=1.35\left(mol\right)\)
\(n_{Br_2}=n_{anken}=0.125\left(mol\right)\)
\(\Rightarrow n_{ankan}=0.35-0.125=0.225\left(mol\right)\)
\(Đặt:\)
\(n_{CO_2}=a\left(mol\right),n_{H_2O}=b\left(mol\right)\)
\(n_{H_2O}-n_{CO_2}=n_{ankan}\)
\(\Rightarrow b-a=0.225\left(1\right)\)
\(BTNTO:\)
\(n_{CO_2}+\dfrac{1}{2}n_{H_2O}=n_{O_2}\)
\(\Rightarrow a+0.5b=1.35\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.825,b=1.05\)
\(m_X=m_C+m_H=0.825\cdot12+1.05\cdot2=12\left(g\right)\)
a)
Gọi $n_{Mg} = a ; n_{Al} = b \Rightarrow 24a + 27b = 5,1(1)$
$Mg + 2HCl \to MgCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Ta có :
$n_{H_2} = a + 1,5b = \dfrac{5,6}{22,4} = 0,25(2)$
Từ (1)(2) suy ra a = b = 0,1
$\%m_{Mg} = \dfrac{0,1.24}{5,1}.100\% =47,06\%$
$\%m_{Al} = 52,94\%$
b)
$n_{HCl} = 2n_{H_2} = 0,5(mol)$
$m_{dd\ HCl} = \dfrac{0,5.36,5}{10\%} = 182,5(gam)$
c)
$MgCl_2 + 2NaOH \to Mg(OH)_2 + 2NaCl$
$AlCl_3 + 3NaOH \to Al(OH)_3 + 3NaCl$
$Al(OH)_3 + NaOH \to NaAlO_2 + 2H_2O$
$n_{Mg(OH)_2} = a = 0,1(mol)$
$\Rightarrow m_{kết\ tủa} = 0,1.58 = 5,8(gam)$
Ta có:
\(Mg+2HCl\rightarrow MgCl_2+H_2\) ; \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Đặt số mol Mg và Al lần lượt là a và b (a,b>0)
theo bài ra ta có hệ
\(\left\{{}\begin{matrix}24a+27b=5,1\\a+1,5b=\dfrac{5,6}{22,4}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\%Mg=\dfrac{0,1\times24}{5,1}=47,06\%\Rightarrow\%Al=100\%-47,06\%=52,94\%\)
Theo PT có \(n_{HCl}=2n_{Mg}+3n_{Al}=2\times0,1+3\times0,1=0,5\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,5\times36,5=18,25\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2\downarrow+2NaCl\)
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3\downarrow+3NaCl\)
+ Với NaOH vừa đủ
\(a=m_{Mg\left(OH\right)_2}+m_{Al\left(OH\right)_3}=0,1\times58+0,1\times78=13,6\left(g\right)\)
+ Với NaOH dư có thêm PT
\(Al\left(OH\right)_3+NaOH\rightarrow NaAlO_2+2H_2O\)
\(\Rightarrow a=m_{Mg\left(OH\right)_2}=0,1\times58=5,8\left(g\right)\)
a) 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
b) Gọi nAl = x, nFe = y
=> 27x + 56y = 11 (1)
Theo pt: \(\Sigma\)nH2 = 1,5x + y = \(\dfrac{8,96}{22,4}=0,4mol\)(2)
Từ 1 + 2 => x = 0,2 , y = 0,1
=> mAl = 0,2.27 = 5,4 => %mAl = \(\dfrac{5,4}{11}.100\%\approx49,09\%\)
%mFe = 100 - 49,09 = 50,91%
c) Theo pt: nHCl = 2nH2 = 0,8 mol
=> mHCl = 0,8 . 36,5 = 29,2g
=> \(m_{dd}\)HCl = 29,2 : 10% = 292g
d) mdd sau phản ứng = m A + mHCl = 11 + 292 = 303g
Theo pt: nAlCl3 = nAl = 0,2 mol => m AlCl3 = 26,7g
=> C%AlCl3 = \(\dfrac{26,7}{303}.100\%\) = 8,81%
tương tự nFeCl2 = 0,1 mol => C%FeCl2 = 4,19%
\(CH_2=CH_2+Br_2\rightarrow CH_2Br-CH_2Br\)
\(n_{hh}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(V_{CH_4}=2.24\left(l\right)\)
\(n_{CH_4}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(\Rightarrow n_{C_2H_4}=0.15-0.1=0.05\left(mol\right)\)
\(\%CH_4=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%C_2H_4=33.33\%\)
\(CH_4+2O_2\underrightarrow{^{t^0}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^0}}2CO_2+2H_2O\)
\(n_{O_2}=0.1\cdot2+0.05\cdot3=0.35\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.35\cdot22.4=39.2\left(l\right)\)
a)
$V_{CH_4} = V_{khí\ thoát\ ra} = 2,24(lít)$
$\%V_{CH_4} = \dfrac{2,24}{8,96}.100\% = 25\%$
$\%V_{C_2H_4} = 100\% -25\% = 75\%$
b)
$n_{Br_2} = n_{C_2H_4} = \dfrac{8,96.75\%}{22,4} = 0,3(mol)$
$C_{M_{Br_2}} = \dfrac{0,3}{0,2} = 1,5M$
$m_{tăng} = m_{C_2H_4} = 0,3.28 = 8,4(gam)$