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a.b.c.\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,1 0,15 ( mol )
\(V_{H_2}=0,15.22,4=3,36l\)
\(m_{AlCl_3}=0,1.133,5=13,35g\)
d.\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,15 0,1 ( mol )
\(m_{Fe}=0,1.56=5,6g\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
\(n_{HCl}=\dfrac{14,6}{36,5}=0,4mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 < 0,4 ( mol )
0,1 0,2 0,1 0,1 ( mol )
Chất dư là HCl
\(m_{HCl\left(dư\right)}=\left(0,4-0,2\right).36,5=7,3g\)
\(V_{H_2}=0,1.22,4=2,24l\)
\(m_{FeCl_2}=0,1.127=12,7g\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,1}{1}< \dfrac{0,4}{1}\)
=> H2SO4 d
\(n_{H_2SO_4\left(pu\right)}=n_{Fe}=0,1\left(mol\right)\\
m_{H_2SO_4\left(d\right)}=\left(0,4-0,1\right).98=29,4g\)
\(n_{H_2}=n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\)
\(V_{H_2}=0,1.22,4=2,24l\\
m_{FeSO_4}=0,1.152=15,2g\)
Ta có: \(n_{Fe_2O_3}=\dfrac{48}{160}=0,3\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
_____0,3_____0,9___0,6____0,9 (mol)
a, \(m_{Fe}=0,6.56=33,6\left(g\right)\)
b, \(V_{H_2}=0,9.22,4=20,16\left(l\right)\)
c, PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2O}=0,9\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,9.22,4=20,16\left(l\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\n_{H_2SO_4}=\dfrac{294\cdot10\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,3}{3}\) \(\Rightarrow\) Axit còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,075\left(mol\right)=n_{H_2SO_4\left(dư\right)}\\n_{H_2}=0,225\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,225\cdot22,4=5,04\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,075\cdot342=25,65\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,075\cdot98=7,35\left(g\right)\\m_{H_2}=0,225\cdot2=0,45\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=297,6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{25,65}{297,6}\cdot100\%\approx8,62\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{7,35}{297,6}\cdot100\%\approx4,47\%\end{matrix}\right.\)
\(a,n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,01--->0,02---->0,01---->0,01
\(V_{H_2}=0,01.22,4=0,224\left(l\right)\\ b,m_{ZnCl_2}=0,01.136=1,36\left(g\right)\\ V_{ddHCl}=\dfrac{0,02}{2}=0,01\left(l\right)\)
a,\(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right);n_{H_2SO_4}=1,5.0,2=0,3\left(mol\right)\)
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,3 0,3 0,3
Ta có: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\) ⇒ Mg dư, H2SO4 pứ hết
\(m_{MgSO_4}=0,3.120=36\left(g\right)\)
b,\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
c, \(n_{Fe_2O_3}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PTHH: 3H2 + Fe2O3 → 2Fe + 3H2O
Mol: 0,04 0,08
Ta có: \(\dfrac{0,3}{3}>\dfrac{0,04}{1}\) ⇒ H2 dư, Fe2O3 pứ hết
\(\Rightarrow m_{Fe}=0,08.56=4,48\left(g\right)\)
a) nFe=0,1(mol); nHCl=0,4(mol)
PTHH: Fe + 2 HCl -> FeCl2 + H2
Ta có: 0,1/1 < 0,4/2
=> Fe hết, HCl dư, tish theo nFe.
b) nH2=nFeCl2=Fe=0,1(mol)
=> V(H2,đktc)=0,1.22,4=2,24(l)
c) mFeCl2=127.0,1=12,7(g)
a) nFe=0,1(mol); nHCl=0,4(mol) PTHH: Fe + 2 HCl -> FeCl2 + H2 Ta có: 0,1/1 < 0,4/2 => Fe hết, HCl dư, tish theo nFe. b) nH2=nFeCl2=Fe=0,1(mol) => V(H2,đktc)=0,1.22,4=2,24(l) c) mFeCl2=127.0,1=12,7(g)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\
pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,15
\(V_{H_2}=0,15.22,4=3,36l\\
pthh:2H_2O+O_2\underrightarrow{t^o}2H_2O\)
0,15 0,075
\(V_{KK}=\left(0,075.22,4\right).5=8,4l\)
\(n_{Fe_2O_3}=\dfrac{4}{160}=0,025\left(mol\right)\\
pthh:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(LTL:\dfrac{0,025}{1}< \dfrac{0,15}{3}\)
=> H2 dư
\(n_{Fe}=2n_{Fe_2O_3}=0,05\left(mol\right)\\
m_{Fe}=0,05.56=2,8g\)
a) nAl=2,7/27=0,1(mol)
nHCl=14,6/36,5= 0,4(mol)
PTHH: 2Al +6 HCl -> 2 AlCl3 +3 H2
Ta có: 0,1/2 < 0,6/4
=> HCl dư, Al hết, tính theo nAl
=> nAlCl3=nAl=0,1(mol)
=> mAlCl3=0,1.133,5=13,35(g)
b) nH2= 3/2. nAl=3/2. 0,1=0,15(mol)
=>V(H2,đktc)=0,15.22,4=3,36(l)
c) mFe2O3(nguyên chất)= 80%. 38,4=30,72(g)
=>nFe2O3= 30,72/160=0,192(mol)
PTHH: Fe2O3 + 3 H2 -to->2 Fe +3 H2O
Ta có: 0,192/1 > 0,15/3
=> H2 hết, Fe2O3 dư, tính theo nH2
=> nFe= 2/3. nH2= 2/3. 0,15=0,1(mol)
=>mFe=0,1.56=5,6(g)
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right);n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,1 0,1 0,15
Tỉ lệ:\(\dfrac{0,1}{2}< \dfrac{0,4}{6}\) ⇒ Al pứ hết,HCl dư
\(\Rightarrow m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
b,\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c,\(m_{Fe_2O_3\left(tinhkhiét\right)}=38,4.\left(100\%-20\%\right)=30,72\left(g\right)\)
⇒\(n_{Fe_2O_3}=\dfrac{30,72}{160}=0,192\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol : 0,15 0,1
Tỉ lệ:\(\dfrac{0,192}{1}>\dfrac{0,15}{3}\)⇒ Fe2O3 dư,H2 hết
=> mFe = 0,1.56 =5,6 (g)