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\(n_{Fe_3O_4}=\dfrac{m_{Fe_3O_4}}{M_{Fe_3O_4}}=\dfrac{23,2}{232}=0,1mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,3 0,2 0,1 ( mol )
\(m_{Fe}=n_{Fe}.M_{Fe}=0,3.56=16,8g\)
\(V_{O_2}=n_{O_2}.22,4=0,2.22,4=4,48l\)
\(V_{kk}=\dfrac{4,48.100}{20}=22,4l\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,4 0,2 ( mol )
\(n_{KMnO_4}=\dfrac{0,4}{85\%}=\dfrac{8}{17}mol\)
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=\dfrac{8}{17}.158=74,3529g\)
a)
\(b)n_{Fe_3O_4} = \dfrac{6,96}{232} = 0,03(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o}Fe_3O_4\\ n_{Fe} = 3n_{Fe_3O_4} = 0,09(mol)\\ m_{Fe} = 0,09.56 = 5,04(gam)\\ c) n_{O_2} = 2n_{Fe_3O_4} = 0,06(mol)\\ V_{O_2} = 0,06.22,4 = 1,344(lít)\\ d) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,12(mol)\\ m_{KMnO_4} = 0,12.158 = 18,96(gam)\)
\(n_{Fe_3O_4}=\dfrac{6.96}{232}=0.03\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_2O_3\)
\(0.09.....0.06.......0.03\)
\(m_{Fe}=0.09\cdot56=5.04\left(g\right)\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...............................................0.06\)
\(m_{KMnO_4}=0.12\cdot158=18.96\left(g\right)\)
n Fe3O4=\(\dfrac{13,92}{232}\)=0,06 mol
3Fe + 2O2 -to--> Fe3O4
0,18------0,12-------0,06
=>m Fe=0,18.56=10,08g
=>VO2=0,12.22,4=2,688l
2KMnO4-to>K2MnO4+MnO2+O2
0,24-------------------------------------0,12
=>m KMnO4=0,24.158=37,92g
nFe3O4 = 13,92 : 160= 0,087 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,087->0,058-->0,029 (mol)
=> mFe = 0,029 . 56 = 1,624 (g)
=> VO2 = 0,058 . 22,4 = 1,2992 (L)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,116<------------------------------0,058 (mol)
=> mKMnO4 = 0,116 . 158 = 18,328 (g)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,4}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{O_2\left(dư\right)}=0,4-\dfrac{2}{15}=\dfrac{4}{15}\left(mol\right)\)
+) Theo PTHH: \(\left\{{}\begin{matrix}n_{O_2}=\dfrac{2}{15}\left(mol\right)\\n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{2}{15}\cdot22,4\cdot5\approx14,93\left(l\right)\\m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\end{matrix}\right.\)
a.b.\(n_{Fe}=\dfrac{6,72}{56}=0,12mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,12 0,08 ( mol )
\(V_{O_2}=0,08.22,4=1,792l\)
c.\(2KClO_3\rightarrow\left(t^o,MnO_2\right)2KCl+3O_2\)
4/75 0,08 ( mol )
\(m_{KClO_3}=\dfrac{4}{75}.122,5=6,533g\)
nFe = 6,72 : 56 = 0,12 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,12 --> 0,08 (mol)
=> VO2 = 0,08 . 22,4 = 1,792 (L)
pthh: 2KClO3 -t--> 2KCl + 3O2
0,053<------------------ 0,08 (mol)
=> mKClO3 = 0,053 . 122,5 = 6,53 (G)
\(a/3Fe+2O_2\xrightarrow[]{t^0}Fe_3O_4\\ b/n_{Fe}=\dfrac{1,4}{56}=0,025mol\\ n_{O_2}=\dfrac{0,025.2}{3}=\dfrac{0,05}{3}mol\\ V_{O_2}=\dfrac{0,05}{3}\cdot22,4\approx0,37l\\ c/C_1\\ n_{Fe_3O_4}=\dfrac{0,025}{3}mol\\ m_{Fe_3O_4}=\dfrac{0,025}{3}\cdot232\approx1,93g\\ C_2\\ m_{O_2}=\dfrac{0,05}{3}\cdot32\approx0,53g\\ BTKL:m_{Fe}+m_{O_2}=m_{Fe_3O_4}\\ \Rightarrow m_{Fe_3O_4}=1,4+0,53=1,93g\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
PTHH: 3Fe + 2O2 =(nhiệt)=> Fe3O4
a) nFe = 5,6 / 56 = 0,1 (mol)
\(\Rightarrow n_{O2}=\frac{0,1.2}{3}=\frac{1}{15}\left(mol\right)\)
Thể tích oxi cần dùng ở điều kiện tiêu chuẩn là:
=> VO2(đktc) = \(\frac{1}{15}.22,4\approx1,5\left(lit\right)\)
b) nFe3O4 = \(\frac{0,1}{3}=\frac{1}{30}\left(mol\right)\)
=> mFe3O4 = \(\frac{1}{30}.232\approx7,73\left(gam\right)\)