Cho 2,7g Al tác dụng vừa đủ với A g dung dịch HCl 10%. Tính A.
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`n_[Al]=[2,7]/27=0,1(mol)`
`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`
`0,1` `0,3` `0,1` `0,15` `(mol)`
`a)V_[H_2]=0,15.22,4=3,36(l)`
`b)V_[dd HCl]=[0,3]/2=0,15(l)`
`=>C_[M_[AlCl_3]]=[0,1]/[0,15]~~0,67(M)`
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,3 0,1 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ V_{HCl}=\dfrac{0,3}{2}=0,15\left(l\right)\\ C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}M\)
\(m_{HCl}=\dfrac{219.10}{100}=21,9\left(g\right)\)
\(n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,2 0,6 0,3
\(b,m_{Al}=0,2.27=5,4\left(g\right)\)
\(c,V_{H_2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
\(a.2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ b.m_{HCl}=\dfrac{219.10\%}{100\%}=21,9\left(g\right)\\ n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{Al}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\\ m_{Al}=0,2.27=5,4\left(g\right)\\ n_{H_2}=\dfrac{0,6.3}{6}=0,3\left(mol\right)\\ V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\ a,m_{AlCl_3}=133,5.0,1=13,35\left(g\right)\\ n_{H_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,n_{HCl}=\dfrac{6}{2}.0,1=0,3\left(mol\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
a)
Gọi số mol Mg, Al là a, b (mol)
=> 24a + 27b = 26,25 (1)
\(n_{H_2}=\dfrac{30,8}{22,4}=1,375\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
a-->2a--------->a------>a
2Al + 6HCl --> 2AlCl3 + 3H2
b---->3b------->b------>1,5b
=> a + 1,5b = 1,375 (2)
(1)(2) => a = 0,25 (mol); b = 0,75 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,25.24}{26,25}.100\%=22,857\%\\\%m_{Al}=\dfrac{0,75.27}{26,25}.100\%=77,143\%\end{matrix}\right.\)
b)
nHCl = 2a + 3b = 2,75 (mol)
=> mHCl = 2,75.36,5 = 100,375 (g)
=> \(m_{dd.HCl}=\dfrac{100,375.100}{10}=1003,75\left(g\right)\)
c)
mdd sau pư = 1003,75 + 26,25 - 1,375.2 = 1027,25 (g)
\(\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,25.95}{1027,25}.100\%=2,312\%\\C\%_{AlCl_3}=\dfrac{0,75.133,5}{1027,25}.100\%=9,747\%\end{matrix}\right.\)
\(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
Pt : \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O|\)
1 6 2 3
0,1 0,6 0,1
a) \(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{10}=219\left(g\right)\)
b) \(n_{AlCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)
⇒ \(m_{AlCl3}=0,2.133,5=26,7\left(g\right)\)
c) \(m_{ddspu}=10,2+219=229,2\left(g\right)\)
\(C_{AlCl3}=\dfrac{26,7.100}{229,2}=11,65\)0/0
Chúc bạn học tốt
nAl2O3=10.2:102=0.1(mol)
PTHH:Al2O3+6HCl->2AlCl3+3H2O
theo pthh:nHCl:nAl2O3=6->nHCl=6*0.1=0.6(mol)
mHCl=0.6*36.5=21.9(g)
mdd HCl=21.9*100:14.6=150(g)
theo pthh:nAlCl3:nAl2O3=2->nAlCl3=0.1*2=0.2(mol)
mAlCl3=0.2*133.5=26.7(g)
mdd sau phản ứng:10.2+150=160.2
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: m dd tăng = mKL - mH2
⇒ mH2 = 16,6 - 15,6 = 1 (g) \(\Rightarrow n_{H_2}=\dfrac{1}{2}=0,5\left(mol\right)\)
Có: 27nAl + 56nFe = 16,6 (1)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=0,5\left(2\right)\)
Từ (1) và (2) ⇒ nAl = nFe = 0,2 (mol)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{H_2}=1\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{1.36,5}{40\%}=91,25\left(g\right)\)
⇒ m dd sau pư = 91,25 + 15,6 = 106,85 (g)
Theo PT: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,2.133,5}{106,85}.100\%\approx24,98\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{106,85}.100\%\approx23,77\%\end{matrix}\right.\)
\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{H_2}=\dfrac{16,6-15,6}{2}=0,5mol\\ n_{HCl}=1mol\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=16,6\\ 3a+2b=1\\ a=b=0,2\\ m_{Al}=0,2.27=5,4g\\ m_{Fe}=0,2.56=11,2g\\ m_{ddsau}=15,6+\dfrac{36,5}{0,4}=106,85g\\ C\%_{AlCl_3}=\dfrac{133,5.0,2}{106,85}.100\%=24,99\%\\ C\%_{FeCl_2}=\dfrac{127.0,2}{106,85}.100\%=23,77\%\)
PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(CuCl_2+2KOH\rightarrow2KCl+Cu\left(OH\right)_2\downarrow\)
a+b) Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,2\left(mol\right)=n_{KOH}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2\cdot36,5}{300}\cdot100\%\approx2,43\%\\C_{M_{KOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
c) PTHH: \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
Theo các PTHH: \(n_{CuO\left(lý.thuyết\right)}=n_{Cu\left(OH\right)_2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow n_{CuO}=0,1\cdot95\%=0,095\left(mol\right)\) \(\Rightarrow m_{CuO}=0,095\cdot80=7,6\left(g\right)\)
Ta có :
\(\frac{2,7}{m_{dd}}\times100=10\left(\%\right)\)
\(\Rightarrow m_{dd}=\frac{2,7\times100}{10}\)
\(\Rightarrow m_{dd}=27\left(g\right)\)
\(\Rightarrow A=m_{dd}-m_{Al}=27-2,7=24,3\left(g\right)\)
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