cho 200g dd Al2(SO4)3 10% tac dụng với 500g NaOH 20%. tính nồng độ % dd sau PƯ
K
Khách
Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Những câu hỏi liên quan
16 tháng 12 2021
Sửa: \(14,7\%\)
\(n_{H_2SO_4}=\dfrac{200.14,7\%}{100\%.98}=0,3(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{200+5,4-0,3.2}.100\%=16,7\%\\ c,m_{Al_2(SO_4)_3}=0,1.342=34,2(g)\)
LN
1
6 tháng 10 2018
\(n_{Al_2\left(SO_4\right)_3}=0,3.0,2=0,06\left(mol\right)\)
\(n_{Al\left(OH\right)_3}=\dfrac{1,56}{78}=0,02\left(mol\right)\)
TH1: NaOH vừa đủ:
\(\dfrac{NaOH}{0,02\left(mol\right)}+\dfrac{Al_2\left(SO_4\right)_3}{0,02\left(mol\right)}\rightarrow\dfrac{Al\left(OH\right)_3\downarrow}{0,02\left(mol\right)}+Na_2SO_4\)
\(\Rightarrow C_{M\left(NaOH\right)}=\dfrac{0,02}{0,5}=0,1\left(M\right)\)
TH2: NaOH dư.
\(\dfrac{NaOH}{0,06\left(mol\right)}+\dfrac{Al_2\left(SO_4\right)_3}{0,06\left(mol\right)}\rightarrow\dfrac{Al\left(OH\right)_3\downarrow}{0,06\left(mol\right)}+Na_2SO_4\)(1)
\(\dfrac{NaOH}{0,02\left(mol\right)}+\dfrac{Al\left(OH\right)_3}{0,02\left(mol\right)}\rightarrow NaAlO_2+2H_2O\)(2)
Từ (1) (2), Suy ra: \(n_{NaOH}=0,06+0,02=0,08\left(mol\right)\)
\(C_{M\left(NaOH\right)}=\dfrac{0,08}{0,5}=0,16\left(M\right)\)
\(n_{Al_2\left(SO_4\right)_3}=\dfrac{200\cdot10\%}{342}=\dfrac{10}{171}\left(mol\right)\)
\(n_{NaOH}=\dfrac{500\cdot20\%}{40}=2.5\left(mol\right)\)
\(6NaOH+Al_2\left(SO_4\right)_3\rightarrow3Na_2SO_4+2Al\left(OH\right)_3\)
\(6..................1\)
\(2.5..................\dfrac{10}{171}\)
\(LTL:\dfrac{2.5}{6}>\dfrac{10}{171}\Rightarrow NaOHdư\)
\(n_{NaOH\left(dư\right)}=2.5-\dfrac{10}{171}\cdot6=2.15\left(mol\right)\)
\(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+H_2O\)
\(\dfrac{20}{171}........\dfrac{20}{171}.........\dfrac{20}{171}\)
\(n_{NaOH\left(cl\right)}=2.15-\dfrac{20}{171}\approx2\left(mol\right)\)
\(m_{\text{dung dịch sau phản ứng}}=200+500=700\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{\dfrac{10}{57}\cdot142}{700}\cdot100\%=3.55\%\)
\(C\%_{NaAlO_2}=\dfrac{\dfrac{20}{171}\cdot82}{700}\cdot100\%=1.37\%\)
$n_{Al_2(SO_4)_3} = \dfrac{200.10\%}{342} = \dfrac{10}{171}(mol)$
$n_{NaOH} = \dfrac{500.20\%}{40} = 2,5(mol)$
$Al_2(SO_4)_3 + 6NaOH \to 2Al(OH)_3 + 3Na_2SO_4$
Ta thấy :
\(\dfrac{n_{Al_2(SO_4)_3}}{1} > \dfrac{n_{NaOH}}{6}\) nên NaOH dư
Theo PTHH :
n NaOH pư = 6n Al2(SO4)3 = 20/57(mol)
n Na2SO4 = 3n Al2(SO4)3 = 10/57(mol)
n Al(OH)3 = 2n Al2(SO4)3 = 20/171(mol)
Sau pư :
m dd = 200 + 500 - 78.20/171 = 709,122(gam)
\(C\%_{NaOH} = \dfrac{(2,5 - \dfrac{20}{57})40}{709,122}.100\% = 12,12\%\\ C\%_{Na_2SO_4} = \dfrac{\dfrac{10}{57}.142}{709,122}.100\% = 3,51\%\)