a, \(\left\{{}\begin{matrix}\%V_{SO_2}=\dfrac{3}{3+2}.100\%=60\%\\\%V_{O_2}=40\%\end{matrix}\right.\)

\(\dfrac{V_{SO_2}}{V_{O_2}}=\dfrac{3}{2}=\dfrac{n_{SO_2}}{n_{O_2}}\) ⇒ n_SO2 = 3x → n_O2 = 2x

\(\Rightarrow\left\{{}\begin{matrix}\%m_{SO_2}=\dfrac{3x.64}{3x.64+2x.32}.100\%=75\%\\\%m_{O_2}=25\%\end{matrix}\right.\)

b, \(2SO_2+O_2\underrightarrow{^{t^o,V_2O_5}}2SO_3\)

Xét tỉ lệ: \(\dfrac{3x}{2}< \dfrac{2x}{1}\), ta được O₂ dư.

Pư: a____1/2a_____a (mol)

Sau: 3x-a___2x-1/2a___a (mol)

\(\Rightarrow\dfrac{\left(3x-a\right).64+\left(2x-\dfrac{1}{2}a\right).32+80a}{3x-a+2x-\dfrac{1}{2}a+a}=32.2\)

⇒ a = 2x

\(\Rightarrow H=\dfrac{2x}{3x}.100\%\approx66,67\%\)

a, K₂SO₄: potassium sulfate 
NH₄Cl: ammonium chloride 
Ca(H₂PO₄)₂: calcium dihydrogen phosphate 
KNO₃: potassium nitrate 
K₃PO₄: potassium phosphate 
NaCl: sodium chloride 
FeSO₄: iron (II) sulfate 

Gọi: \(\left\{{}\begin{matrix}n_{N_2O_5}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\)

⇒ 108x + 44y = 27,2 (1)

Mà: \(d_{A/H_2}=34\Rightarrow M_A=34.2=68\left(g/mol\right)\)

\(\Rightarrow n_A=\dfrac{27,2}{68}=0,4\left(mol\right)=x+y\left(2\right)\) 

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,25\left(mol\right)\end{matrix}\right.\)

BTNT O, có: n_{O (trong A)} = 5n_N2O5 + 2n_CO2 = 1,25 (mol)

Ta có: n_{O (trong Fe2(SO4)3)} = 12n_Fe2(SO4)3

⇒ 12n_Fe2(SO4)3 = 1,25

⇒ n_Fe2(SO4)3 = 5/48 (mol)

⇒ m_Fe2(SO4)3 = 5/48.400 = 125/3 (g)

\(a.n_{H_2}=\dfrac{14,874}{24,79}=0,6mol\\ \Rightarrow n_{H_2}=1,2mol\\ m_{HCl}=1,2.36,5=43,8g\\ b.m_{H_2}=0,6.2=1,2g\\ BTKL:m_X+m_{HCl}=m_{muối}+m_{H_2}\\ =>m_{muối}=m_X+m_{HCl}-m_{H_2}\\ =29,9+43,8-1,2\\ =72,5g\)

Gọi: n_Mg = x (mol), n_Zn = 2x (mol)

PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

Theo PT: \(n_{H_2}=n_{Mg}+n_{Zn}=x+2x=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)

⇒ x = 0,1 (mol)

⇒ n_Mg = 0,1 (mol), n_Zn = 0,2 (mol)

⇒ m_hh = 0,1.24 + 0,2.65 = 15,4 (g)

Theo PT: \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\)

\(\Rightarrow V_{HCl}=\dfrac{0,6}{2}=0,3\left(l\right)\)

\(n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\Rightarrow C_{M_{MgCl_2}}=\dfrac{0,1}{0,3}=\dfrac{1}{3}\left(M\right)\)

\(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)

Bàu 2

\(n_P=\dfrac{1,55}{31}=0,05mol\\ a)4P+5O_2\xrightarrow[]{t^0}2P_2O_5\)

0,05        0,0625       0,025

\(b)m_{P_2O_5}=0,025.142=3,55g\\ c)V_{O_2}=0,0625.24,79=1,549375l\)

Bài 3

\(a)n_{Fe}=\dfrac{11,2}{56}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)

0,2      0,4             0,2           0,2

\(V=V_{H_2}=0,2.24,79=4,958l\\ b)m_{FeCl_2}=0,2.127=25,4g\\ c)m_{ddHCl}=\dfrac{0,4.36,5}{20\%}\cdot100\%=73g\\ d)m_{dd}=11,2+73-0,2.2=83,8g\\ C_{\%FeCl_2}=\dfrac{25,4}{83,8}\cdot100\%=30,31\%\)