Cần cho thêm bao nhiêu ml dung dịch CuCl2 1,2M vào 220 ml dung dịch CuCl2 4M để thu được dung dịch CuCl2 2M?
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A: MgO, CuO
B: MgCl2, CuCl2
C: Mg(OH)2, Cu(OH)2
PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{FeO}=\dfrac{2,16}{72}=0,03\left(mol\right)\\ n_{HCl}=0,2.0,4=0,08\left(mol\right)\\ a,PTHH:FeO+2HCl\rightarrow FeCl_2+H_2O\\ Vì:\dfrac{0,03}{1}< \dfrac{0,08}{2}\Rightarrow HCldư\\ n_{FeCl_2}=n_{FeO}=0,03\left(mol\right)\\ m_{FeCl_2}=127.0,03=3,81\left(g\right)\\ n_{HCl\left(Dư\right)}=0,08-2.0,03=0,02\left(mol\right)\\ V_{ddsau}=V_{ddHCl}=0,4\left(l\right)\\ C_{MddHCl\left(dư\right)}=\dfrac{0,02}{0,4}=0,05\left(M\right);C_{MddFeCl_2}=\dfrac{0,03}{0,4}=0,075\left(M\right)\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(a)7437ml=7,437l\\ n_{N_2}=\dfrac{7,437}{24,79}=0,3mol\\ m_{N_2}=0,3.28=8,4g\\ b)n_{Cl_2}=\dfrac{2,479}{24,79}=0,1mol\\ m_{Cl_2}=0,1.71=7,1g\)
Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
Theo ĐLBT KL: mZn + mH2SO4 = mZnSO4 + mH2
⇒ mH2SO4 = 9 + 0,1.2 - 6,5 = 2,7 (g)
\(a.Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ b.n_{H_2SO_4}=0,22.1,25=0,275mol\\ n_{Fe_2O_3}=a;n_{CuO}=b\\ \Rightarrow\left\{{}\begin{matrix}3a+b=0,275\\160a+80b=16\end{matrix}\right.\\ \Rightarrow a=0,075;b=0,05\\ \%m_{Fe_2O_3}=\dfrac{0,075.160}{16}\cdot100=75\%\\ \%m_{CuO}=100-75=25\%\)
Ta có: nCuCl2 (4M) = 0,22.4 = 0,88 (mol)
Gọi: VCuCl2 (1,2M) = a (l)
⇒ nCuCl2 (1,2M) = 1,2a (mol)
\(\Rightarrow\dfrac{0,88+1,2a}{0,22+a}=2\)
⇒ a = 0,55 (l) = 550 (ml)