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\(n_{Al}=\frac{10,8}{27}=0,4\left(mol\right)\)
\(2Al+6HCl->2AlCl_3+3H_2\) (1)
theo (1) \(n_{H_2}=\frac{3}{2}n_{Al}=0,6\left(mol\right)\)
=> \(V_{H_2}=0,6.22,4=13,44\left(l\right)\)
Cho 10,08 g nhom tac dung vua du voi dung dich axit HCl.2M
a) viet phuong trinh phan ung va tinh the tich H2(dktc)
b) tinh the tich dung dich axit HCl.2M da dung
a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
Số mol Al tham gia pứ: 2,4.1022:6.1023=0,04mol
nO2=3/4.nAl=3/4.0,04=0,03mol
VO2=0,03.22,4=0,672l
-Thể ticsk kk tham gia : 0,672.5=3,36l
b)nAl2O3=2/4.nAl=2/4.0,04=0,02mol
mAl2O3=0,02.102=2,04g
Đặng Khánh Duy ai đùa làm gì? tính m dung dịch sai thì sai cả C% rồi còn đâu
Câu 1:
\(n_{Al}=\dfrac{m}{M}=\dfrac{8,1}{27}=0,3mol\)
\(n_{H_2SO_4}=\dfrac{200.14,7}{98.100}=0,3mol\)
2Al+3H2SO4\(\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
-Tỉ lệ: \(\dfrac{0,3}{2}>\dfrac{0,3}{3}\rightarrow\)Al dư, H2SO4 hết
\(n_{Al\left(pu\right)}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{2}{3}.0,3=0,2mol\)
\(n_{Al\left(dư\right)}=0,3-0,2=0,1mol\)
\(n_{H_2}=n_{H_2SO_4}=0,3mol\)
\(V_{H_2}=0,3.22,4=6,72l\)
\(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}=\dfrac{1}{3}.0,3=0,1mol\)
\(m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2gam\)
\(m_{dd}=8,1+200-0,1.27-0,3.2=204,8gam\)
C%Al2(SO4)3=\(\dfrac{34,2}{204,8}.100\approx16,7\%\)
Câu 2:
\(n_{MgO}=\dfrac{4}{40}=0,1mol\)
\(n_{H_2SO_4}=\dfrac{200.19,6}{98.100}=0,4mol\)
MgO+H2SO4\(\rightarrow\)MgSO4+H2O
-Tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{1}\rightarrow\)H2SO4 dư
\(n_{H_2SO_4\left(pu\right)}=n_{MgO}=0,1mol\)\(\rightarrow\)\(n_{H_2SO_4\left(dư\right)}=0,4-0,1=0,3mol\)
\(m_{H_2SO_4}=0,1.98=9,8gam\)
\(n_{MgSO_4}=n_{MgO}=0,1mol\)
\(m_{dd}=4+200=204gam\)
C%H2SO4(dư)=\(\dfrac{0,3.98}{204}.100\approx14,4\%\)
C%MgSO4=\(\dfrac{0,1.120}{204}.100\approx5,9\%\)
Pt: Ba+2H2O -> Ba(OH)2+H2 (1)
Ba(OH)2+CuSO4 ->Cu(OH)2 \(\downarrow\) +BaSO4 \(\downarrow\)(2)
Ba(OH)2+(NH4)2SO4 ->BaSO4 \(\downarrow\)+2NH3+2H2O (3)
Cu(OH)2\(\underrightarrow{t^0}\)CuO+H2O (4)
BaSO4 \(\underrightarrow{t^0}\) ko xảy ra phản ứng
Theo (1) ta có \(n_{H_2}=n_{Ba\left(OH\right)_2}=n_{Ba}=\frac{27,4}{137}=0,2\left(mol\right)\)
\(n_{\left(NH_4\right)_2SO_4}=\frac{1,32\cdot500}{132\cdot100}=0,05\left(mol\right)\)
\(n_{CuSO_4}=\frac{2\cdot500}{100\cdot160}=0,0625\left(mol\right)\)
Ta thấy: \(n_{Ba\left(OH\right)_2}>n_{\left(NH_4\right)_2SO_4}+n_{CuSO4\:}\) nên Ba(OH)2 dư và 2 muối đều phản ứng hết
Theo (2) ta có: \(n_{Ba\left(OH\right)_2}=n_{Cu\left(OH\right)_2}=n_{BaSO_4}=n_{CuSO_4}=0,0625\left(mol\right)\)
Theo (3) ta có: \(n_{Ba\left(OH\right)_2}=n_{BaSO_4}=n_{\left(NH_4\right)_2SO_4}=0,05\left(mol\right)\)
và \(n_{NH_3}=2n_{\left(NH_4\right)_2SO_4}=0,05\cdot2=0,1\left(mol\right)\)
\(\Rightarrow n_{Ba\left(OH_2\right)}\text{dư}=0,2-\left(0,05+0,0625\right)=0,0875\left(mol\right)\)
a)\(V_{A\left(ĐKTC\right)}=V_{H_2}+V_{NH_3}=\left(0,2+0,1\right)\cdot22,4=6,72\left(l\right)\)
b)Theo (4) ta có: \(n_{CuO}=n_{Cu\left(OH\right)_2}=0,0625\left(mol\right)\)
\(m_{\text{chất rắn}}=m_{BaSO_4}+m_{CuO}=\left(0,0625+0,05\right)\cdot233+0,0625\cdot80=31,2125\left(g\right)\)
CaCO3 + 2HCl -> CaCl2 + CO2 + H2O (1)
2NaOH + CO2 -> Na2CO3 + H2O (2)
nCaCO3=0,15(mol)
nHCl=0,2(mol)
Vì \(\dfrac{0,2}{2}< 0,15\) nên CaCO3 dư
Theo PTHH 1 ta có:
nCO2=\(\dfrac{1}{2}\)nHCl=0,1(mol)
Theo PTHH 2 ta có:
nCO2=nNa2CO3=0,1(mol)
mNa2CO3=106.0,1=10,6(g)
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