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\(m_{CaCO_3}=400\cdot90\%=360\left(g\right)\)
\(m_{trơ}=400-360=40\left(g\right)\)
\(n_{CaCO_3}=\dfrac{360}{100}=3.6\left(mol\right)\)
\(a.\)
\(n_{CaCO_3\left(pư\right)}=3.6\cdot75\%=2.7\left(mol\right)\)
\(CaCO_3\underrightarrow{^{^{t^0}}}CaO+CO_2\)
\(2.7........2.7...........2.7\)
\(m_X=m_{CaO}+m_{CaCO_3\left(dư\right)}+m_{trơ}=2.7\cdot56+\left(3.6-2.7\right)\cdot100+40=281.2\left(g\right)\)
\(b.\)
\(\%CaO=\dfrac{2.7\cdot56}{281.2}\cdot100\%=53.77\%\)
\(V_{CO_2}=2.7\cdot22.4=60.48\left(l\right)\)
\(m_{CaCO_3}=90\%.400=360\left(g\right)\\ \rightarrow n_{CaCO_3}=\dfrac{360}{100}=3,6\left(mol\right)\)
PTHH: CaCO3 --to--> CaO + CO2
3,6 ----------> 3,6 -----> 3,6
\(\rightarrow n_{CaO}=3,6.75\%=2,7\left(mol\right)\\ \rightarrow n_{CaCO_3\left(chưa.pư\right)}=3,6-2,7=0,9\left(mol\right)\)
\(\rightarrow m_X=0,9.100+2,7.56=241,2\left(g\right)\\ \%m_{CaO}=\dfrac{0,9.100}{241,2}=37,31\%\)
\(V_Y=V_{CO_2}=3,6.75\%.22,4=60,48\left(l\right)\)
\(m_{CaCO_3}=\dfrac{400\cdot90\%}{100\%}=360g\Rightarrow n_{CaCO_3}=\dfrac{360}{100}=3,6mol\)
\(CaCO_3\underrightarrow{t^o}CaO+CO_2\)
3,6 3,6 3,6
Thực tế: \(n_{CaO}=3,6\cdot75\%=2,7mol\)
\(\Rightarrow m_{CaO}=2,7\cdot56=151,2g\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,4 0,8 0,4 0,4
a) \(n_{H2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,4.22,4=8,96\left(l\right)\)
b) \(n_{HCl}=\dfrac{0,4.2}{1}=0,8\left(mol\right)\)
⇒ \(m_{HCl}=0,8.36,5=29,2\left(g\right)\)
\(m_{ddHCl}=\dfrac{29,2.100}{14,6}=200\left(g\right)\)
c) \(n_{ZnCl2}=\dfrac{0,4.1}{1}=0,4\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,4.136=54,4\left(g\right)\)
\(m_{ddspu}=26+200-\left(0,4.2\right)=225,2\left(g\right)\)
\(C_{ZnCl2}=\dfrac{54,4.100}{225,2}=24,16\)0/0
Chúc bạn học tốt
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{CuO\left(p.ứ\right)}=a\left(mol\right)\\ \Rightarrow n_{Cu}=a\left(mol\right);m_{CuO\left(dư\right)}=24-80a\left(g\right)\\ \Rightarrow m_{rắn}=m_{CuO\left(dư\right)}+m_{Cu}=\left(24-80a\right)+64a=21,6\\ \Leftrightarrow-16a=-2,4\\ \Leftrightarrow a=0,15\\ Vậy:H=\dfrac{0,15.80}{24}.100\%=50\%\\ b,n_{H_2}=n_{Cu}=a=0,15\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\)
\(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a) Chất tan : FeSO4
Chất khí : H2
\(m_{FeSO_4}=0.05\cdot152=7.6\left(g\right)\)
\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
a) $Fe + 2HCl \to FeCl_2 + H_2$
b)
n Fe = 8,4/56 = 0,15(mol) ; n HCl = 0,15.2,4 = 0,36(mol)
Ta thấy :
n Fe / 1 < n HCl /2 nên HCl dư
Theo PTHH : n H2 = n Fe = 0,15 mol
=> V = 0,15.22,4 = 3,36 lít
c) Dung dịch chứa HCl,FeCl2
m dd HCl = D.V = 0,8.150 = 120(gam)
Sau phản ứng :
n HCl dư = 0,36 - 0,15.2 = 0,06(mol)
n FeCl2 = n Fe = 0,15(mol)
m dd = 8,4 + 120 -0,15.2 = 128,1(gam)
C% HCl = 0,06.36,5/128,1 .100% = 1,71%
C% FeCl2 = 0,15.127/128,1 .100% = 14,87%