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Gọi \(\left\{{}\begin{matrix}n_{N_2}=x\left(mol\right)\\n_{NO}=y\left(mol\right)\end{matrix}\right.\)
\(n_{hh}=\dfrac{12,395}{24,79}=0,5\left(mol\right)\) (chắc đkc nhỉ vì đktc số kì: )
=> x + y = 0,5 (1)
Tỉ khối của X so với khí `H_2` là 14,5 có:
\(M_X=14,5.2=29\left(g/mol\right)\\ \Leftrightarrow\dfrac{28x+30y}{x+y}=29\\ \Rightarrow x-y=0\left(2\right)\)
Từ (1), (2) có: \(\left\{{}\begin{matrix}x+y=0,5\\x-y=0\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,25\\y=0,25\end{matrix}\right.\) (bấm máy giải hệ)
a
Số mol mỗi khí trong hỗn hợp khí X: \(n_{N_2}=n_{NO}=0,25\left(mol\right)\)
b
\(\%_{m_{N_2}}=\dfrac{0,25.28.100\%}{0,25.28+0,25.30}=48,28\%\)
\(\%_{m_{NO}}=100\%-48,28\%=51,72\%\)
\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(\overline{M_x}=24.2=48\)
\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\) 48 = \(\dfrac{16}{16}=1\)
\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)
1. \(m_{hh}=0,3.64+0,3.32=28,8g\)
2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)
\(\Rightarrow\%V_{O_2}=50\%\)
3. \(m_{SO_2}=0,3.64=19,2g\)
\(m_{O_2}=0,3.32=9,6g\)
Ta có: \(n_X=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Gọi: \(\left\{{}\begin{matrix}n_{H_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\) ⇒ x + y = 0,4 (mol) (1)
\(d_{X/NO_2}=0,5\Rightarrow M_X=0,5.46=23\left(g/mol\right)\)
⇒ mX = 0,4.23 = 9,2 (g)
⇒ 2x + 44y = 9,2 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,2\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
a) Gọi nO2 =a (mol); nO3 = b(mol)
Có: \(\dfrac{32a+48b}{a+b}=20.2=40\)
=> 32a + 48b = 40a + 40b
=> 8a = 8b => a = b
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+a}.100\%=50\%\\\%V_{O_3}=100\%-50\%=50\%\end{matrix}\right.\)
b) Gọi nN2 =a (mol); nNO = b(mol)
Có: \(\dfrac{28a+30b}{a+b}=14,75.2=29,5\)
=> 28a + 30b = 29,5a + 29,5b
=> 1,5a = 0,5b
=> 3a = b
=> \(\left\{{}\begin{matrix}\%V_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{a}{a+3a}.100\%=25\%\\\%V_{NO}=100\%-25\%=75\%\end{matrix}\right.\)
\(C+H_2O-^{^{ }t^{^{ }0}}->CO+H_2\\ C+2H_2O-^{^{ }t^{^0}}>CO_2+2H_2\\ m_X=11,2:22,4.7,8.2=7,8g\\ n_{CO}=a;n_{CO_2}=b\Rightarrow n_{H_2}=a+2b\left(mol\right)\\ n_X=0,5=a+b+a+2b=2a+3b=0,5\left(I\right)\\ m_X=28a+44b+2a+4b=30a+48b=7,8\left(II\right)\\ \left(I\right)\left(II\right)\Rightarrow a=0,1=b\\ n_{CO}=n_{CO_2}=0,1mol\\ n_{H_2}=0,3mol\)
\(n_{hhA}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\Rightarrow m_{hhA}=0,2.30=6\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}x+y=0,2\\28x+32y=6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2-y\\28.\left(0,2-y\right)+32y=6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{N_2}=0,1.28=2,8\left(g\right)\\m_{O_2}=6-2,8=3,2\left(g\right)\end{matrix}\right.\)
a) \(\overline{M}_A=5,875.2=11,75\left(g/mol\right)\)
b) Gọi số mol N2, H2 là a, b (mol)
\(\overline{M}_A=\dfrac{28a+2b}{a+b}=11,75\left(g/mol\right)\)
=> 16,25a = 9,75b
=> a = 0,6b
\(\left\{{}\begin{matrix}\%n_{N_2}=\dfrac{a}{a+b}.100\%=\dfrac{0,6b}{0,6b+b}.100\%=37,5\%\\\%n_{H_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{0,6b+b}.100\%=62,5\%\end{matrix}\right.\)
c)
1 mol hỗn hợp A chứa \(\left\{{}\begin{matrix}n_{N_2}=\dfrac{1.37,5}{100}=0,375\left(mol\right)\\n_{H_2}=\dfrac{1.62,5}{100}=0,625\left(mol\right)\end{matrix}\right.\)
\(\overline{M}_B=\dfrac{0,375.28+0,625.2+17x}{1+x}=6,4.2=12,8\left(g/mol\right)\)
=> x = 0,25 (mol)
Giả sử có 1 mol khí Cl2, 2 mol khí O2
a) \(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{1}{1+2}.100\%=33,33\%\\\%V_{O_2}=\dfrac{2}{1+2}.100\%=66,67\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cl_2}=\dfrac{1.71}{1.71+2.32}.100\%=52,59\%\\\%m_{O_2}=\dfrac{2.32}{1.71+2.32}.100\%=47,41\%\end{matrix}\right.\)
b) \(\overline{M}=\dfrac{1.71+2.32}{1+2}=45\left(g/mol\right)\)
=> \(d_{A/H_2}=\dfrac{45}{2}=22,5\)
c) \(n_A=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
=> mA = 0,3.45 = 13,5 (g)
Ta có: \(n_{H_2}+n_{O_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\) (1)
- Tỉ khối của X so với H2 là 8,5.
\(\Rightarrow\dfrac{2n_{H_2}+32n_{O_2}}{n_{H_2}+n_{O_2}}=8,5.2\) \(\Rightarrow2n_{H_2}+32n_{O_2}=8,5.2.0,3\left(2\right)\)
Từ (1) và (2) ⇒ nH2 = nO2 = 0,15 (mol)