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Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{m_{H_2SO_4}}{200}.100\%=14,7\%\)
=> \(m_{H_2SO_4}=29,4\left(g\right)\)
=> \(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
a. PTHH: 2KOH + H2SO4 ---> K2SO4 + 2H2O
Theo PT: \(n_{KOH}=2.n_{H_2SO_4}=2.0,3=0,6\left(mol\right)\)
=> \(m_{KOH}=0,6.56=33,6\left(g\right)\)
Ta có: \(C_{\%_{KOH}}=\dfrac{33,6}{m_{dd_{KOH}}}.100\%=5,6\%\)
=> \(m_{dd_{KOH}}=600\left(g\right)\)
Theo đề, ta có:
\(D=\dfrac{600}{V_{dd_{KOH}}}=10,45\)(g/ml)
=> \(V_{dd_{KOH}}=57,42\left(ml\right)\)
b. Ta có: \(m_{dd_{K_2SO_4}}=200+33,6=233,6\left(g\right)\)
Theo PT: \(n_{K_2SO_4}=n_{H_2SO_4}=0,3\left(mol\right)\)
=> \(m_{K_2SO_4}=0,3.174=52,2\left(g\right)\)
=> \(C_{\%_{K_2SO_4}}=\dfrac{52,2}{233,6}.100\%=22,35\%\)
Câu 16:
PTHH: \(KOH+HCl\rightarrow KCl+H_2O\)
Ta có: \(n_{HCl}=0,25\cdot1,5=0,375\left(mol\right)=n_{KOH}=n_{KCl}\)
\(\Rightarrow\left\{{}\begin{matrix}V_{KOH}=\dfrac{0,375}{2}=0,1875\left(l\right)\\C_{M_{KCl}}=\dfrac{0,375}{0,1875+0,25}\approx0,86\left(M\right)\end{matrix}\right.\)
Câu 18:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
a) Ta có: \(n_{H_2SO_4}=\dfrac{200\cdot14,7\%}{98}=0,3\left(mol\right)\)
\(\Rightarrow n_{KOH}=0,6\left(mol\right)\) \(\Rightarrow m_{ddKOH}=\dfrac{0,6\cdot56}{5,6\%}=600\left(g\right)\) \(\Rightarrow V_{ddKOH}=\dfrac{600}{10,45}\approx57,42\left(ml\right)\)
b) Theo PTHH: \(n_{K_2SO_4}=0,3\left(mol\right)\) \(\Rightarrow C\%_{K_2SO_4}=\dfrac{0,3\cdot174}{600+200}\cdot100\%=6,525\%\)
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
\(n_{H_2SO_4}=0,1.0,75=0,075mol\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\)
0,075 0,15 0,075 0,15
\(a)m_{K_2SO_4}=0,075.175=13,05mol\)
\(b)H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\\ n_{NaOH}=0,075.2=0,15mol\\ m_{ddNaOH}=\dfrac{0,15.40}{15\%}\cdot100\%=40g\\ V_{ddNaOH}=\dfrac{40}{1,05}=38,1ml\)
a.250ml=0,25l ; nHCl=0,25.1,5=0,375mol
KOH+HCl->KCl+H2O
1mol 1mol 1mol
0,375 0,375 0,375
VKOh=0,375/2=0,1875l
b.CM KCL=0,375/0,25=1,5M
c.NaOH+HCL=NaCl+H2O
1mol 1mol
0,375 0,375
mdd NaOH=0,375.40.100/10=150g
