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a)PTHH: \(Ba\left(OH\right)+Na_2CO_3\rightarrow2NaOH+BaCO_3\downarrow\)
\(BaCO_3\underrightarrow{t^o}BaO+CO_2\uparrow\)
Ta có: \(n_{Ba\left(OH\right)_2}=0,4\cdot0,2=0,08\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,16mol\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,16}{0,4}=0,4\left(M\right)\) (Coi Vdd thay đổi không đáng kể)
b) Theo PTHH: \(n_{BaCO_3}=n_{Ba\left(OH\right)_2}=n_{BaO}=0,08mol\) \(\Rightarrow m_{BaO}=0,08\cdot153=12,24\left(g\right)\)
a. Ba(OH)2 +Na2CO3 ➝ BaCO3 + 2NaOH
BaCO3 ➝ BaO + CO2
nBa(OH)2 = 0,08 mol
=> nNaOH = 2nBa(OH)2 = 0,16 mol
=> CM = 0,4 M
b) Bảo toàn Ba: nBaO = nBa(OH)2 = 0,08 mol
=> m = 12,24 g
\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,095 0,19 0,095 0,095
\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)
0,095 0,095
\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)
\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)
PTHH :
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
0,2 0,4 0,2 0,2
\(m_{NaOH}=0,4.40=16\left(g\right)\)
\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)
\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)
\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)
\(d,PTHH:\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
0,2 0,2
\(m_{CuO}=0,2.80=16\left(g\right)\)
a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)
\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)
c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)
d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)
\(a,PTHH:CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\\ Cu\left(OH\right)_2\rightarrow^{t^0}CuO+H_2O\\ b,n_{CuCl_2}=n_{Cu\left(OH\right)_2}=n_{CuO}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\\ c,n_{NaCl}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{23,4}{200}\cdot100\%=11,7\%\)
\(n_{AgNO_3}=0,1.0,2=0,02\left(mol\right)\\ n_{HCl}=0,3.0,2=0,06\left(mol\right)\\ AgNO_3+HCl\rightarrow AgCl\downarrow\left(trắng\right)+HNO_3\\ a,Vì:\dfrac{0,02}{1}< \dfrac{0,06}{1}\Rightarrow HCldư\\ \Rightarrow n_{AgCl}=n_{HNO_3}=n_{AgNO_3}=0,02\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{AgCl}=143,5.0,02=2,87\left(g\right)\\ b,dd.sau.p.ứ:HNO_3,HCl\left(dư\right)\\ n_{HCl\left(dư\right)}=0,06-0,02=0,04\left(mol\right)\\V_{ddsau}=V_{ddAgNO_3}+V_{ddHCl}=0,2+0,2=0,4\left(l\right)\\ \Rightarrow C_{MddHCl\left(dư\right)}=\dfrac{0,04}{0,4}=0,1\left(M\right)\\ C_{MddHNO_3}=\dfrac{0,02}{0,4}=0,05\left(M\right)\)
AgCl kết tủa thì không có phải dung dịch nên không tính nồng độ mol đâu bạn
\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)
\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)
chỉ mình câu b,c nữa ạ