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\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)
\(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)
b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)
\(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)
c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)
nZnCl2 =40,8/136=0,3mol
nNaOH= 0,1.0,5=0,05mol
a)
pt : ZnCl2 + 2NaOH ------> Zn(OH)2\(\downarrow\) + 2NaCl
ncó: 0,3 0,05
n pứ: 0,025<------0,05-------->0,025-------->0,05
n dư: 0,275 0
b)
mZnCl2 dư = 0,275.136=37,4g
mNaCl=0,05.58,5=2,925g
c)
pt : Zn(OH)2 ---to--> ZnO + H2O
n pứ : 0,025------------>0,025
mZnO=0,025.81=2,025g
d)
vdd sau pứ =Vdd NaOH =0,1l
CM(ZnCl2 dư )=0,025/0,1=0,25M
CM(NaOH)=0,05/0,1= 0,5M
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
FeCl2+ 2NaOH --> Fe(OH)2 + 2NaCl (1)
4Fe(OH)2 +O2 --to-> 2Fe2O3 + 4H2O (2)
nFeCl2=0,2(mol)
nNaOH=0,5(mol)
Lập tỉ lệ :
\(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)
=> FeCl2 hết ,NaOH dư
Theo (1,2) : nFe2O3=1/2nFeCl2=0,1(mol)
=> x=16(g)
b) VNaOH=\(\dfrac{m}{D}=\dfrac{200}{1,12}\approx178,6\left(ml\right)\)\(\approx\)0,1786(l)
Theo (1) : nNaOH(PƯ)=2nFeCl2=0,4(mol)
=>nNaOH dư=0,1(mol)
nNaCl=2nFeCl2=0,4(mol)
=> CM dd NaCl\(\approx\)2,24(M)
CM dd NaOH dư\(\approx\)0,6(M)